Search Documents

By Ferri P. Hassani, Riadh Bouzaïene

"Selected methods of pressure loss predictions in horizontal slurry flow in pipelines are presented. For a given combination of flow velocity, solids concentration and particle size, the slurry and its flow conditions are described, and an appropriate method of pressure loss prediction is outlined. The wide range of conditions treated in this paper may be found in practice in areas varying from the hydraulic transport of low concentration slurries to dense-phase conveying of paste backfill in underground mines.IntroductionThe hydraulic conveying of solid particles in pipelines is a major component of the mining and mineral processing industry. Whether the objective is to transport ore to the processing plant or to make use of mill tailing as backfill material; the need for well designed, economical hydraulic conveying systems is recognized.The contribution of this paper is part of an on-going research program at McGill University involved in optimizing and developing techniques for total mine waste disposal. One of the main concerns in the conveying of solid-liquid mixtures is the prior knowledge of the pumping power input required. This energy requirement is directly proportional to the pressure losses incurred in the pipeline system. Understanding the sources of such pressure losses and predicting their magnitudes should enable the system designer to make informed decisions regarding the optimum mode of hydraulic transportation commensurate with the over-all requirements of the operation.This paper is an attempt to classify pressure loss prediction methods encountered in the literature for solid-liquid mixtures. In spite of the large number of publications spanning thirty years of research in the field of slurry transportation, it is sometimes difficult to correctly identify the appropriate methods applicable to a given situation. This is partly due to the inherent complexity of the mechanics of slurry flow and the ensuing uncertainty about the nature of the flow regime under investigation.Our approach is to use three fundamental parameters, namely: flow velocity, solids concentration and particle size (for solid particles with a given density) to characterize the slurry and the flow conditions, and to match them with an adequate pressure loss prediction method. For each combination of flow velocity, solids concentration and particle size, a description of the most likely prevalent flow conditions and some known methods of dealing with them will be presented. Qualitative definitions of ""high"" and ""low"" magnitudes of the aforementioned parameters will be given as a general guide to the classification scheme presented in this paper."

Jan 1, 1992

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By Kevin Ross

Feasibility Study Team Processing / Engineering?Hatch, Vancouver Mining / Reserves?Australian Mine Consultants, Brisbane Geology / Resources?Roscoe Postle Associates, Vancouver Environmental / Permitting?Rescan, Vancouver Tailings BGC, Kamloops Probable Mine Components Mining tending towards caving methods Underground mine accessed by shaft /conveyor & decline Processing plant producing copper concentrate containing gold Concentrate trucked to rail head for export Non saturated tailings disposal

May 1, 2006

By Keith C. Hendrick

"Metal prices are frequently the most critical and least predictable element in determining the profitability of mining operations. Short -term fluctuations can be offset in varying degrees by hedging or other market actions. Such solutions are not practical for the longer term, The paper investigates the nature and extent of metal price risks and evaluates methods to reduce them.IntroductionIt is management's responsibility to improve the odds by managing the-risks by identifying them clearly, assessing them accurately, minimizing them where possible-and, then, timing decision s success fully.In determining the profitability of current operations, preparing forward plan s or developing feasibility studies for new projects or expansions, pr ices are usually the most critical input. Being market determined rather than cost based, they can also be the most unpredictable As a result, commodity prices are frequently the greatest of all risk factors.Nature of Commodity PricesThe cyclical nature of commodity prices is well known. They are stable only when supply is in balance with demand and forecast to remain that way. An imbalance on either side of the equation can lead to a price reaction completely out of proportion to the actual or perceived surplus or shortage.This exaggeration arises through the cumulative effect of market forces. When the market senses an uptrend, consumers buy for the expected increase in activity. They also seek additional quantities for inventory before price s rise. Merchants defer spot sales anticipating higher price s, speculators go along for the same reason, and producers raise prices in response to demand. Events tend to confirm the expectation of each party and strengthen their reaction causing prices to move higher."

Jan 1, 1983

By Francis Dakubo, Courtney Young, Avimanyu Das

"Hydrometallurgy of copper ores typically involve acid leaching followed by solvent extraction and electrowinning (SX/EW). EW is the final purification stage in which a voltage is applied across two electrodes causing the copper ions to reduce and deposit on the cathode. Applied voltages are near 2 volts with current densities around 300 amps/m2. In this study, research was undertaken to decrease the energy consumed in the EW process. To do this, various cell designs were constructed and tested in which a membrane was used to separate the cathode and anode compartments with concentrated solution from SX serving as catholyte and raffinate from SX serving as anolyte. Therefore, copper in the concentrated solution would be deposited on the cathode while ferrous in the raffinate would be oxidized to ferric at the anode. Because it is assumed that ferric acid leaching is used, resulting ferric would be recycled to the leaching process. A positive side effect of the envisioned process would be the elimination of oxygen evolution at the anode and thus the prevention of acid-misting. After a cell design was selected, it was used to test a number of variables: flowrate, concentration, temperature, ion-exchange membrane, and applied voltage. Following experiments in which variable ranges were determined, statistical modeling was conducted using STATEASE software. Optimal results indicate the voltage can be decreased to 1.5-1.7 volts with current densities of 300-400 amps/m2. Significant reduction in the energy consumption was accomplished by reducing the applied voltage. Furthermore, current efficiencies and copper production rates was increased by application of the membrane.INTRODUCTIONLeaching of copper ores is achieved using mostly sulfuric acid. The copper pregnant solution is contacted with an organic solvent or resin adsorbent which picks up copper ions as in Equation 1:"

Jan 1, 2016

By K. Sun, S. A. Argyropoulos

The assimilation and the exothermic behavior of Zn-Zr metallic powder compacts into molten aluminum was studied by measuring simultaneously the temperatures inside at the centerline of the compact, at its surface, and inside the molten aluminum bath, as well as the net downward force acting on the compact. In addition, the exothermic behavior of these compacts was also investigated in an argon protected atmosphere. The temperature rise inside the compact increases significantly with the mass ratio of zirconium in the compact and to a lesser degree with the aluminum bath temperature. Experimental results on the recovery of these compacts in molten aluminum will also be presented.

Jan 1, 2008

By David Meadows, Elmer Palmer, Steve Dixon

As part of the Goldcorp Inc growth plan Minera Peñasquito SA de CV has developed its polymetallic deposit with a large “state of the art” concentrator to process lead and zinc ores. The plant consists of two grinding lines including 38ft diameter SAG mills and 24ft diameter ball mills. During mid to late 2009 concentrator commissioning activities commenced. First concentrates were produced in October 2009 and now the plant is meeting its design basis of 65,000 mtpd per line. This paper describes the design and operational experience to date for its grinding circuit design, together with the recently commissioned HPGR crushing circuit.

Jan 1, 2012

By F. Parada

During copper smelting and converting processes, slag generated is pyrometallurgically cleaned and then disposed, containing around 1 % of this metal. However, important amount of molybdenum initially contained in concentrates also goes to the slag phase. Research on molybdenum recovery from water granulated slags using acid leaching at low temperatures was conducted to find an efficient way for molybdenum extraction with lower magnetite in the slag. However because of the high fayalite content high acid consumption was found. Molybdenum can be recovered from solution using ionic exchange resins, but high silica content interferes with extraction. Some studies addressed to minimize silica extraction as well as alternatives of selective silica precipitation in order to develop a technically feasible process.

Jan 1, 2007

"Line Creek Resources Ltd. produces three million clean tonnes per year of metallurgical and thermal coals for the international market. The mining operation, which is located in the mountains of southeastern British Columbia, produces coal from four pits by conventional truck and shovel methods.The South Pit, which has been in operation since J982, has a benched highwall 490 m in height. Shallow dipping coal seams at the base of the syncline formation will be exposed in the highwall over the next four years of pit life. The first of these seams, which will measure 500 m in final highwall length, was exposed in J994. An auger, powered by a 1250 hp engine capable of cutting 2.2 m diameter holes, was brought on site in J994 and has proven to be a successful means of recovering coal from the J3 m thick seam.This paper covers the background to the selection of an auger mining method to recover highwall reserves together with the geotechnical and methane considerations for this approach.IntroductionLine Creek Resources Ltd., a wholly owned subsidiary of Manalta Coal Ltd., owns and operates the Line Creek mine. The operation which consists of four active pits, a processing plant, and rail loadout is located in the southeastern coal fields of British Columbia. Figure 1 shows the general area.The coal bearing sequence at the mine is preserved on the east and west limbs of a major syncline. Up to twelve mineable coal seams, ranging in thickness from 2 m to 15 m are contained in the formation. Within the pits the seams are stratigraphically consistent and structurally undisturbed, except for small-scale thrust faults that create multiple repeats of the seams."

Jan 1, 1995

By Henry Smith, Stu Brown

"The Williams Mine is Canada's largest gold producer, with annual production of some 500 000 ounces of gold from two million tonnes of ore. Highly mechanized and automated underground mining practices are utilized at the property in order to help achieve high levels of productivity and the most cost-effective mining possible.Planning and design parameters for the underground ore handling system at the Williams Mine are described in this paper. Particular reference is made to the considerations that were built into the system to provide maximum operating flexibility through the use of multiple orepass systems, portable low profile jaw crushers, underground conveyors and automated hoisting equipment.IntroductionThe Williams Mine is situated in the Hernlo area of northwestern Ontario, approximately 40 Ian east of the town of Marathon (Fig. I). It is operated by the Williams Operating Corporation, which is owned equally by Teck Corporation and Corona Corporation, and is one of three adjacent properties forming the HernIo gold camp.The mine commenced operation in October 1985 at a nominal production rate of 3000 tpcd. Through an ongoing capital development program, winch was completed in late 1989, the production rate at the property was increased to its current level of 6000 tpcd. This paper describes the mine planning process and the evolution of current mining strategies with particular reference to the underground ore handling system .HistoryGold mineralization was discovered in 1944 in the Hemlo area of Northern Ontario, near the north shore of Lake Superior. A year later, 11 claims were staked over the showing and subsequently patented by the late Dr. Jack Kerr Williams.Over the next 35 years, other claims were subsequently staked, explored and abandoned in the immediate area of the 11 patented claims . In 1980 a predecessor of the Corona Corporation acquired claims adjoining the Williams property to the east. Drilling on this claim group started early in 1981 and intersected the Hemlo orebody in May of that year. In December 1981, Corona Corporation entered into an option agreement with Teck Corporation to explore and develop the property.A drilling program by LAC Minerals on the II patented claims discovered the Williams orebody in March 1982. The mine started production in 1985, pouring its first official bar of gold on December 6 of that year. Corona Corporation was awarded ownership of the Williams Mine conclusively by a decision of the Supreme Court of Canada on August 11, 1989. The court's ruling ended a legal dispute with LAC Minerals over the property initiated eight years earlier."

Jan 1, 1991

By T. Thriveni, Ji Whan Ahn

"The current advanced technologies for the manufacture of light weight metals processing significantly increasing and attributes to the safety, performance, recyclability and economy. Still lack of technologies developed for light weight metals processing waste utilization and application. Environmentally friendly methods need to develop for better understanding the processing waste utilization. Alumina and aluminium processing creates a wide range of waste products, the most significant being is red mud. Bauxite residue is a high volume hazardous waste and nearly 3 billion tons have been dumped worldwide. Approximately, 120 Million tons/yr of red mud being produced without any environmental sustainable solution. Currently the most significant technology is waste utilization. The bauxite residue is suitable for road base construction, golf bunker sand, back fill and, general fill. Sustainable recycling technologies are necessary for the bauxite residue utilization for the recovery of rare earth elements and cement materials. Carbonation or CO2 sequestration of carbon dioxide is a method pioneered for the bauxite residue is modified to reduce alkalinity. The carbonation of alkaline material is an inexpensive and safe process that leads to the formation of thermodynamically stable products. The use of the carbonation can be an advantageous solution for environmental climate change and sustainability problems in the new century.INTRODUCTIONIn 2014, bauxite consumption was estimated to be 9.6 million tons, nearly all of which was imported, worth an estimated 269 million dollars. More than 95% of the bauxite was converted to alumina, and the remaining 5% went to non-metallurgical products, such as abrasives, chemicals, proppants, and refractories. Global aluminum demand is growing steadily spurred by growth in India and China (RBCAluminum Market Outlook, 2013) (Figure 1). Aluminum consumption is expected to rise 5% annually through the end of the decade, reaching 67 million tons per year by 2020. Global bauxite production decreased by 17% from that of 2013, principally owing to lower production in Indonesia. In response to a Government ban on exporting bauxite and other unprocessed mineral ores that took effect on January 12, 2014, bauxite mines throughout Indonesia shut down and production decreased from 55.7 million tons in 2013 to an estimated 500,000 tons in 2014. The ban was part of a mining law that was instituted in 2009 to increase development of downstream processing facilities in Indonesia."

Jan 1, 2016

By Per-Lennart Nystedt

"The Boliden Lead Kaldo Plant for the treatment of lead bearing flue-dust from the Copper Smelter and the Slag Fuming Plant has been in operation at the Ronnskar Works of Boliden Metall since the middle of 1976. At the present stage, the plant can treat lead-bearing dust of different kinds and compositions. The process allows good separation of arsenic and halogens from lead.The flue dust from the Copper Smelter and the Slag Fuming Plant is very complex and, apart from lead, also contains zinc, copper, tin, bismuth, cadmium, antimony, arsenic, sulphur, silver, chlorine and fluorine. The metallurgical process has been developed by Boliden Metall and has been tested on a pilot scale at the Foundation for Metallurgical Research (MEFOS) in Lulea, Sweden.The pelletized dust is smelted in the converter, where the heat is generated by an oil oxygen burner. The second step consists of reduction with coke. A lead bullion and slag are obtained. The slag, transported in liquid form, is treated in the Slag Fuming Plant for the recovery of zinc. The third step is the elimination of arsenic from the bullion. This is achieved by treating the lead with iron (turnings or pellets). The result is a crude lead and speiss. The lead contains silver, tin, antimony and bismuth, and is suitable for the final refining stages in normal plant equipment for refined lead.For process control, we use the rapid analysis centre, which is pneumatically and electronically linked to 'all major plant sections and allows for a quick turn-around between delivery of the sample and feedback of results. All three steps in the process are performed in the same converter.Since the starting up of the plant, the original process has been subjected to some modifications. Initial problems related to equipment, maintenance and environment have been solved step by step. Examples are quoted. Recent operating particulars are presented."

Jan 1, 1980

By D. C. Martin, P. M. Hawley, C. P. Acott

"In bedded deposits such as coal or sedimentary iron, economic limits of mineable reserves are clearly defined by the footwall of the seams or ore-bearing units. Where open pits are developed in dipping strata, a long, high footwall slope may result. In many cases, unbenched slopes excavated along the base of the lowest mineable seam are operationally simple, economically desirable and geotechnicalty practical, although a variety of failure mechanisms may develop. This paper examines the engineering geology and rock mechanics parameters of importance in the design of footwall slopes. Possible failure mechanisms and stability analysis methods are described. Design considerations for benched and unbenched slopes are discussed with prime consideration given to development of long high stopes without benches or with a minimum number of benches. IntroductionIn bedded deposits, the ultimate depth and economic viability of an open pit in dipping strata may be controlled by the design of the footwall slope. The stability and, hence, design of footwall slopes is strongly influenced by the engineering geology and rock mechanics parameters of the slope forming materials. A clear understanding of the structural geology, engineering geology and tectonic history of the deposit is essential to assess the behaviour of the slope. This is particularly important for long high, unbenched footwall slopes such as shown in Photo I.A rational footwall slope design requires identification and assessment of all possible slope failure mechanisms with respect to the proposed slope geometry. Stability analyses of each potential failure mechanism are used to identify the main controls on slope stability and to develop appropriate slope design criteria. The optimum slope design is based on the most economic and geotechnically practical slope geometry with due consideration of operational constraints and of the possible advantages of specific remedial measures."

Jan 1, 1986

By Jean-Luc Collins

"This paper shows how simple reliability concepts such as mean time between failures and mean repair time can be used efficiently to help increase equipment availability and so reduce the economic losses associated with unreliability.More specifically, the paper shows how these simple concepts can be used in maintaining an appropriate balance between fleet failure and repair rates and how they can be used for setting up priority repair rules f or queuing equipment.IntroductionA profitable mining operation must handle large quantities of ore and waste at the lowest possible cost. To achieve this objective, the operation must optimize the productivity of its fleets of equipment by efficient management of the time element. Figure I shows some basic equipment activities in an open pit operation while Figure 2 shows a tree diagram describing some time elements of these activities.It should be noted that the only time a piece of equipment can generate a profit is when it can be found in the operating status. In order to maximize this time element, the sum of the other time elements must be minimized because the total time is always fixed.This paper shows the application of simple techniques capable of reducing the waiting time for repair (maintenance delay) by using simple reliability concepts."

Jan 1, 1988

By G. W. McDonald

"The mineralogical studies done on Hope Brook ore samples indicated that a heap leach gold recovery process may be possible. In the metallurgicalprogram that followed, column tests confirmed this interpretation. A 9300 tonne demonstration heap leach test, in the late fall of 1985, reaffirmed laboratory results while identifying operating conditions that will have to be addressed in a production heap leach plan. Operating plans, gold recoveries and cost areas will be presented.Another important factor in a successful operation is the environment approach.LocationThe Hope Brook gold deposit is located 5 km inland from Cinq Cerf Bay on the south coast of Newfoundland. Port au x Basques is 80 km west and Burgeo 40 km to the east of Hope Brook. As there are no roads in the area, access to the site is by sea or air (Fig. I). The Hope Brook orebody is near the saddle of three watersheds flowing to Cinq Cerf Brook, Boat Hole Brook and Betty's Pond. Acceptable solutions to several environmental concerns can be obtained by using the relative sensitivities of these watersheds.The terrain at the site is generally rolling to hummocky with numerous small ponds separated with rock outcrops and patches of peat covering. Tree vegetation is sparse except in the sheltered areas around Couteau Bay and Cinq Cerf Brook. GeologyThe Chetwynd deposit is hosted by the Lower to Middle Ordovician Georges Brook Formation of the La Poile Group, a thick sequence of volcanic and sedimentary rocks.The Hope Brook Zone contains the largest concentration of gold found to date at Chetwynd. The zone occurs as an intensely silicified lens 100 m to 550 m long (average 400 m) by up to 60 m in width and forms the eastern portion of a more extensive, 4 km long , alteration zone trending at 053 degrees Az and dipping 70 degrees southeast.The Hope Brook Zone contains massive finely granular quartz, scattered blue quartz eyes, 3070 to 8% pyrite, minor calcopyrite and trace molybdenite. Barren silicification envelopes the gold mineralization. The zone is flanked to the southeast by a 200 metre thick aluminosilicate alteration zone and to the northwest by a 10 metre barren pyritic siliceous fragmental rock . The original lithology may be either a thick felsic pyroclastic sequence or a quartz porphyry sill that has been altered by hydrothermal processes. Silica flooding of the permeable host was accompanied by gold deposition."

Jan 1, 1989

?NWCC has the highest number of Aboriginal students of any post secondary institution in BC and the region served includes 25 bands ? Chair of the Board of Governors is Irene Seguin (Hagwiloo K?am Saxwhl Giis) from Gitwinksihlkw ? FN council ? 39 First Nations Members * focus is to develop policy recommendations to increase student success rates

May 1, 2009

By M. R. Babcock

"The Rabbit Lake story began in the late sixties and will continue well into the twenty-first century. It is a story of success, of multiple ore body discoveries, of unique systems, and new methods made possible through innovative and state-of-the-art design. Two quite different geological systems host the five ore bodies mined, or slated to be mined. These two systems have yielded two distinct ore types, each with characteristic mineralogical properties and each requiring its own specific mill circuit.Emphasis on communications and our unique systems have led to a satisfactory and fulfilling work environment resulting in the historically low employee turnover which has contributed to the operation success.A comprehensive environmental study after twelve years of operation has given the Rabbit Lake Operation a completely clean bill of health. INTRODUCTIONRabbit Lake can be described as Saskatchewan's first highgrade uranium mining operation, which set the stage for the province's current role as the leader in uranium mining throughout the western world. The importance of the Rabbit Lake operations - past, present and future.LocationThe Rabbit Lake operation is located in northeastern Saskatchewan (Fig. 1)- 805 km north of Saskatoon, Saskatchewan, and 814 km northeast of Edmonton, Alberta. OwnershipGulf Minerals Canada Limited discovered the Rabbit Lake deposit in 1968. Mining operations began in 1975and were operated by Gulf until purchased by Eldorado Nuclear Limited in 1982. In 1988, Eldorado merged with Saskatchewan Mining Development Corporation (SMDC) to form Cameco-A Canadian Mining &. Energy Corporation. The new corporation is one of the world 's largest uranium companies.Cameco's $1.5 billion in assets include the Rabbit Lake uranium mine (Cameco 100010); the Key Lake uranium mine (Cameco 66.67%; Uranerz Exploration and Mining Limited 33.33%); the Cluff Lake uranium mine (Cameco 20%; Amok Ltd. 80%); the Fuel Services Division at Blind River and Port Hope, Ontario (Cameco 100%); and a 100%); and a 48.75% interest in the Cigar Lake uranium deposit which is now at the test mining stage (Cogema Canada Ltd . 32.625% ; Idemitsu Uranium Exploration Canada Limited 12.875%; Corono Grande 3.75%; Korea Electric Power Corporation 2%). In addition, Cameco is involved in a number of base and precious metal explor ation projects."

Jan 1, 1989

By D. G. Champion

"A comparison of diesel engine power ratings with in-service capability, and the selection of unit size and total number of units are discussed in the paper. Engine specific fuel consumption and its evaluation in relation to manufacturers' tolerances and equipment load factors is reviewed along with the suitable plant layout. The potential for heat recovery is discussed in connection with simple and operable recovery systems f or exhaust and cooling circuits. Maintenance standards as related to improved reliability and reduced fuel and operating costs are also outlined. IntroductionDiesel generators are used in Canadian mining operations to provide electrical power for "" base- load"" requirements in some instances and for ""stand-by"" or ""emergency"" power in almost every producing mine in the country . There are over 300 mines in Canada of which only a handful have to generate their own electricity. Only one or two mine s enjoy access to a hydroelectric site. Consequently, the diesel engine is the principal prime mover because of its high efficiency relative to other prime movers in the size range in question.The author has been associated with several “base-load” plants in addition to participation in numerous projects requiring emergency diesel generators. Records indicate that engine performance in term s of reliability and efficiency lags behind other industries where the diesel engine is used more extensively, such as the shipping industry which is able to make a more prudent selection of original equipment and enjoy easy access to highly skilled operating and maintenance personnel. It is hoped that the contents of this paper will be of value to Canadian operators of diesel generators, in the generation of prime power or applications for back-up power."

Jan 1, 1986

By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By G. Grant Smith

In situ bulk density of coal is a variable applied to various aspects of coal resource evaluation, such as compositing ply analyses of coal attributes that are expressed on a weight per cent basis, and determining tonnages from volume estimates. Its value is a function of composition and porosity of the in situ material. When densities of ash-free coal, ash and water are fixed, in situ bulk density of a coaly mix can be expressed as a function of proportionate weight of ash in the mix. Correlations between in situ bulk densities and weight per cent ash contents of coaly mixes have been estimated for four general rank classes of coal (low medium volatile bituminous, high volatile bituminous, subbituminous, and lignitic).

Jan 1, 1991