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By Willard L. Hunter

The Bureau of Mines studied the effect of temperature upon the reduction of chromite by carbon and the relative reducibility of chromites as a function of their composition. Ferric oxide was also studied to provide comparative data. Pellets weighing approximately 1 gram and containing 70 percent ferric oxide, chromic oxide, or chromite and 30 percent graphite were subjected to closely controlled temperatures under a flow of argon for 15 minutes. The amount of CO and CO2 evolved was measured, and the reduced sample was analyzed by X-ray diffraction techniques. The reduction of Fe2O3 was studied over a temperature range of 600° to 1,400° C, while the reduction of Cr2O5 and chromite was conducted from 9000 to 1,621° C. The temperature above which appreciable reduction of Cr203 by graphite took place was 1,125° C. The temperature at which significant reduction started for three of the four chromite samples was approximately the same, indicating that there was concurrent reduction of iron and chromium oxides in the chromite mineral rather than selective reduction of iron oxides followed by reduction of chromic oxide. Rhodesian chromite appeared to dissociate at a lower temperature with concurrent reduction of iron. Based on the temperature at Which chromite was 50 percent reduced in 15 minutes, Transvaal chromite reduced most easily, followed by Mouat, then by Kampersian, and finally by Rhodesian DFC material. Statistical analysis of test results indicated that the ferric iron content of chromites affects their reduction behavior more than any other constituent.

Jan 1, 1966

By W. A. Selvig

"The purpose of the investigation described herein was to determine how closely different laboratories can check one another in making determinations of fusibility of coal ash with the De Graaf electric coal-ash fusion furnace: how well duplicate determinations by the same laboratory will check, and how the results with the De Graaf furnace compare with those of the standard gas-furnace method of the American Society for Testing Materials.4Thanks are due the following laboratories who cooperated in this study by making fusibility tests with the Do Graaf electric coal-ash fusion apparatus: J. J. Brennan, testing engineer, Northern States Power Co.; R. E. Gilmore, superintendent, Fuel Research Laboratories, Canadian Department of Mines A. T. Leavitt, president, and W. Mueller, chief chemist, Hamilton By-product Coke Ovens. Ltd.; Edgar Stansfield, chief chemical engineer, Scientific and Industrial Research Council of Alberta. Canada; and H. S. Vassar, laboratory engineer, Public Service Electric and Gas Co.The ash-fusibility determinations by the standard gas-furnace method were made in the Coal Analysis Laboratory of the Bureau of Mines at Pittsburgh under the direction of H. M. Cooper, associate chemist. The investigation was made at the suggestion of A. C. Fieldner, chief engineer, Experiment Stations Division of the Bureau of Mines.Routine determinations of the fusibility of coal ash are made in the laboratories of the United States Bureau of Mines by the gas-furnace method. This method was standardized after considerable experimentation5 on the nature of the fusion of coal ash and the various factors which affect its determination. The method was subsequently adopted by the American Society for Testing Materials as one of its standard tests."

Jun 1, 1930

By S. C. Termes, P. E. Richardson, R. L. Wilfong

"The Bureau of Mines conducted research on the flocculation of various minerals with insoluble cross-linked starch xanthate (ISX) to determine its potential as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming. Covellite, chalcocite, pyrite, pyrrhotite, chalcopyrite, bornite, sphalerite, galena, and molybdenite fines flocculate with ISX. Floc formation, floc size, and settling rate are dependent on pH, with the pH dependence differing for each mineral. Quartz is not flocculated by ISX. Experiments to obtain selective flocculation of sulfides from quartz were attempted. Good selectivity was only obtained for the bornite-quartz system. Post flocculation separations resulted in flocculated bornite in grades as high as 92 pct. Evidence is presented that the flocculation of many of the sulfide minerals with ISX may involve covalent bonding of the xanthate group to lattice metal site(s). INTRODUCTIONBecause of the increasing interest in selective flocculation as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming, the Bureau of Mines has been investigating the flocculation behavior of several cross-linked starch derivatives containing chelating groups. This report dis cusses the flocculation of sulfide mineral fines by insoluble cross-linked starch xanthate (ISX).Polymeric materials such as ISX, which contain a chelating group of known re¬activity towards specific mineral surfaces, were first proposed by Slater, Clark, and Kitchener (1), 3 Kitchener (2), and Attia and Kitchener (3) as selective flocculants for mineral fines with particle aggregation possible through a bridging mechanism. ISX appeared to be attractive as a sulfide mineral flocculant because (1) alkyl xanthates are known to react selectively with sulfide minerals"

Jan 1, 1983

By F. A. Rutledge

The W. E. Dunkle mine, sometimes called the Costello Creek coal mine, is 8 miles N. 20° W. of Colorado Station on the Alaska Railroad. The presence of coal in this area has been known since the district was extensively prospected for gold between 1911 and 1915. At that time, coal from this deposit was used by miners for blacksmithing. The increased demand for coal resulting from government defense projects in Alaska led to exploitation of this deposit in 1941. The inability of Alaska coal mines to supply the quantity of coal required by public and private consumers and by the armed forces in Alaska was responsible for establishment by the Army of the Coal Procurement Section of its Alaska Department. It proposed to investigate the deposits and to expedite production from the Alaskan coal fields. The Bureau of Mines closely cooperated in this program. The quality of the Dunkle coal and the favorable location of the deposit caused it to be one of the properties chosen for investigation under a joint Army-Bureau of Mines-Geological Survey program.

Jan 1, 1948

By W. M. Dressel

The Federal Bureau of Mines has obtained data by differential thermal analysis of the various minerals that represent the nation's resources in manganese. These data are supported by X-ray diffraction analysis, chemical analysis, mineralography, and optical mineralogy, and provide fundamental information on the response of each mineral to thermal treatment in oxidizing, reducing, and neutral atmospheres. The information can be applied advantage¬ously in the identification of manganese minerals. Its greatest potential value, however, lies in the application of the quantitative data on the reaction temperatures, rates, and products to the more efficient extraction of manganese from U.S. ores. Thermal analysis curves are presented for certain manganese minerals, namely hausmannite, bixbyite, braunite, pyrolusite, lithiophorite, cryptomelane, hollandite, manganite, rhodochrosite, and rhodonite. The original minerals and the products of their thermal decomposition were identified by X-ray diffraction analysis, supplemented by chemical analysis and mineralogical identification.

Jan 1, 1961

By D. A. Reynolds, J. D. Davis

"This work was begun in l928, with the cooperation of the American, Gas Association, and the Association contributed financial aid for that year and for the 4 years following. In 1933 financial aid was discontinued, but the Advisory Committee, under the able, Chairmanship of J. S. Haug, has continued to function through the years to the present date. Mr. Haug's annual reports have been published in the Proceedings of the American Gas Association. The purpose of this paper is to bring the index of coals tested by the Bureau of Mines-American Gas Association (EM-AGA) method up to date, to discuss development of auxiliary tests, and to outiline the uses to which the methods have been put in promoting the war effort.COALS TESTEDThe test methods developed with the advice of the Advisory Committee had been applied to 66 coals up to 1942, and an index giving the serial number, origin, and analyses of these coals was published as Bureau of Mines Technical Paper 637. Since this paper was published, 20 additional coals have been tested; the source and analyses of these coals are given in table 1. The table also refers to publications that have been issued. Complete series of tests at high, medium, and low temperatures,have been made on most of these coals, and blending tests with 20 and 30 30 percent of low-volatile coals have also been made at 900°C.; however a few low- and medium-volatile coals (60, 70, 74, 79, and 80) were bested,at high temperatures only. Those coals were mined in eastern Oklahoma and western Arkansas. The test work included low- and high-temperature assay tests, petrorraphic analyses, and plasticity tests since its inception; and for the last 20 coals of the series, expansion and oxidation tests have been made where applicable."

Jun 1, 1944

By L. C. IlsLey

In January, 1922, a conference relative to trailing cables for use with permissible mining machines was held at the Pittsburgh Experiment Station of the U. S. Bureau of Mines. At this conference it was recommended that the bureau take steps to investigate the rubber-sheathed type of cables and to bring about the establishment of a list of approved cables. Effective until such time as a complete investigation could be made, the bureau asked the several manufacturers holding approvals for mining machines to recommend cables for use with their machines. In general the cables recommended were tentatively approved. Due to the lack of available personnel, no actual tests of cables were made until mid-1927. Meanwhile a field investigation of trailing cables was made at 20 mines of three coal companies in western Pennsylvania, and samples of cables were obtained from the manufacturers for laboratory tests. Twenty-five samples of the concentric-type cable, representing the product of five manufacturers, were obtained for the tests. These cables were of four sizes, as follows: 3 cables of No. 2 B & S gage, 17 cables of No. 3 B & S gage, 3 cables of No. 4 B & S gage, and 2 cables of No. 6 B & S gage.

Jan 1, 1929

By Steven R. Davis

Voyageurs National Park in northern Minnesota, and a 30-mile radius area of influence on the United States side of the International Border, was examined for hardrock (nonferrous metallic minerals and diamonds) mineral potential and environmental sensitivity by the U.S. Bureau of Mines. The investigation also included an analysis of current Metallic Minerals Leasing Rules of the State of Minnesota, and the probable effects of changes proposed to the current rules by the State of Minnesota in order to "encourage mineral exploration and development." The study has determined that the proposed changes to the Minnesota State Leasing rules will have minimal, if any, impact on the likely, foreseeable levels of mineral-related activities in the State as a whole, and particularly, in the area of influence to the Park. Voyageurs National Park management was advised on the extent and character of the proposed rules changes, and on those items of concern meriting a specific and timely response by the National Park Service.

Jan 1, 1994

By H. H. Schrenk

[There is a need for method of determining: benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the modification of the Elliott and Dalton6/ procedure. This depends on the nitration of the benzene to reduction to phenylenediamine with all excesses of standard titanous chloride; solution, and titration with e standard ferric ammonium sulphite solution. This method has the disadvantages of being what time consulting: and cumbersome it requires considerable apparatus, and a special modification is necessary in the presence of toluene.]

Jan 1, 1935

By H. H. Schrenk

There is a need for a method of determining benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the Smyth modification of the Elliott and Dalton procedure. This depends on the nitration of the benzene to m-dinitrobenzene, reduction to phenylenediamine with an excess of standard titanous chloride solution, and back titration with a standard ferric ammonium sulphate solution. This method has the disadvantages of being somewhat time-consuming and cumbersome; it requires considerable apparatus, and a special modification is necessary in the presence of toluene. Recently Cook and Ficklen have published a method based on the oxidation of benzene with hydrogen peroxide in the presence of iron salts. This method requires the use of solid carbon dioxide to freeze out the benzene. The reaction Which produces the color is complex; and only approximate quantitative estimations can be made, except in a very narrow range.

Jan 1, 1935

By Donald L. Siebert

This profile study of the commercial secondary aluminum industry examines not only the elements that form the industry but also the technological contributions of each toward industrial growth. Concise descriptions of processing methods trace aluminum scrap from generating sources to marketable industrial and consumer goods. Economic and marketing appraisals are used to illustrate the impact that recent technology has had upon the secondary aluminum industry. Price, supply, demand, competition, and substitutes are selected as components of an economic model of the secondary industry and are used to illustrate the aggregate effects of technological changes. The final section is a conceptual look at the future in which sensitive economic indicators (such as die casting in the automotive and appliance industries) are examined as well as the problems of conserving mineral resources by retrieving secondary aluminum from solid waste.

Jan 1, 1970

By W. A. Young

To initiate this project a critical evaluation of the pre-sent phosphate mining industry in the Western phosphate field was conducted. Mines were visited, mine operators were interviewed and pertinent literature studied. Three phosphate mining enterprises were reviewed and mining cost estimates prepared. The report discusses the present state of phosphate processing, rock alteration and location. New ideas and concepts are proposed to improve the recovery of phosphate rock from the Phosphoria formation. The report evaluates two variations to the present phosphate open pit mining methods, which were developed to improve the economics of mining phosphate and to better accomplish necessary reclamation and accelerate the time for environmental recovery. A material handling system using conveyor haulage will eliminate the need for trucks. Terrace haulback utilizes safety benches to haul and dispose of waste in the mined out pit. Ore will be removed from the pit via an inclined, cable-supported mobile conveyor.

Jan 1, 1980

By R. G. Nelson

This report covers investigations of the Bureau of Mines for the period of June 15, 1952, to June 15, 1953, on a research project for the Materials Laboratory, Wright Patterson Air Force Base, Dayton, Ohio. The primary purpose of this investigation was to make high-purity chromium-base alloys having room-temperature ductility and high-temperature strength. The Nonferrous Metals Branch of the Bureau of Mines, Albany, Oreg., has, during the past 7 years, developed on a laboratory scale a hydrogen treatment method for making high-purity chromium that can be fabricated into thin sheet and wire. This material can be bent at room temperature. The object of this investigation was to use this material to develop improved chromium-rich alloys for high-temperature uses.

Jan 1, 1955

By Stephen C. Tadolini

The U.S. Bureau of Mines conducted a laboratory investigation designed to evaluate the stress and deformation characteristics of fully grouted roof bolts subjected to various magnitudes of end loadings. The experiment and subsequent analysis were completed, utilizing axial deformation data obtained -ultrasonically from forty-one 4-ft, grade 40 roof bolts, with a total of 132 measurement locations along the lengths of the bolts. The ultrasonic measurement instrumentation used in this investigation allowed for elongation measurements without requiring extensive bolt modifications. The results indicate that approximately 39 pct o{ the applied end load dissipated within the first 3.4 in of the bolts. However, only 3 pct of the applied load was realized beyond 28 in of the grout column. Data are presented individually for every 6-in increment of bolt length, and analysis was performed using statistical, nonlinear equations developed for 5,000 and 8,000 lb loading conditions.

Jan 1, 1990

By David C. Chang

A survey of in-situ methods for determining bulk electric properties of coal is given. Largely because of the strong dependence of coals properties on operating frequency, different sensing methods have to be adopted for different applications. Evaluation of both established and feasible methods is made in this report from the viewpoint of physical set-up, probing depth, and the type of inversion involved.

Jan 1, 1977

Our mission is help ensure our country has an adequate, dependable supply of minerals and mate al to meet its national security and economic needs at acceptable social, environmental, and economi[c] costs. We do this by promoting and encouraging private enterprise in the development of viable and stable mineral industries through the transfer of innovative extraction, processing, recycling, an environmental technologies; our use of cooperative partnerships with industry, academia, an government; our timely, authoritative worldwide mineral intelligence; our advocacy of public policies based on good science and sound economics.

Jan 1, 1994

By Chas. F. Jackson

This paper is one of a series dealing with mining methods and costs, prepared and published under the sponsorship of the United States Bureau of Mines and made possible through the cooperation f many mining companies in the United States and foreign countries. The preparation of this paper follows a field study of top-slice mining during which the author visited and discussed with operating officials a large number of iron mines in the Lake Superior region. During this study special note was made of changes in top-slicing practice during the past decade, prior to which the author had acquired several years experience with the method through active connection with a number of mines employing top slicing.

Jan 1, 1931

By C. W. Davis

During the second year of its existence, the Ore-Testing Section has actively prosecuted work in the standardization of testing methods, in conducting routine tests and analyses for other Government agencies, and in the determination of recommended processes for the treatment of representative ores from mining districts. Close cooperation has been maintained between the members and units of this Section and those of other Sections, J. A. Woolf and J. B. Clemmer have continued to act in an advisory capacity and R. E. Head has contributed valuable assistance in the microscopic examination of ores and metallurgical products that did not respond readily to standard treatment methods.

Jan 1, 1938

By C. W. Davis

During the second year of its existence the Ore-Testing Section has actively prosecuted work in the standardization of testing methods, in conducting routine tests and analyses for other Government agencies, and in the determination of recommended processes for the treatment of representative ores from mining districts. Close cooperation has been maintained between the members and units of this Section and those of other Sections. J. A. Woolf and J, B. Clemmer have continued to act in an advisory capacity and. R. E. Head has contributed valuable assistance in the microscopic examination of ores and metallurgical products that did not respond readily to standard treatment methods.

Jan 1, 1938

By Robert R. Perron

The U.S. Bureau of Mines is engaged in many diverse programs for improving mine safety. Of particular interest to the Bureau are new and improved means for minimizing the hazard of fire which can be initiated by prolonged low energy electrical faults on trolley line systems. When a high energy fault occurs on a trolley line, wherein the current exceeds the magnitude normally drawn by legitimate loads, such as locomotives, then the circuit breakers at close-by power rectifier sets trip. Tripping of the breakers not only protects the equipment at the rectifier sets, but also disconnects the energy source from the fault and thereby minimizes the fire risk. However, the fault current is frequently of a level substantially below that required to trip the overload breakers. When the fault is a substantial percentage of the set level of the breakers, the energy dissipated by the fault is frequently sufficient to clear the system by rapidly burning itself clear. Such a fault is often short-lived and does not present as serious a fire risk hazard as a prolonged, much lower energy fault, wherein the energy level is too low to clear the system. The breakdown of a trolley line insulator, in which there was a 20 or 30 ampere leak, would represent such a fault or illegitimate load and a substantial fire risk.

Jan 1, 1974