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By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By W. McCombe, G. Remple, L. Zunti, M. Bernardin, L. Nightingale-Mercer

"The McClean Lake Mill is located approximately 700 kilometres north of Saskatoon, Saskatchewan, Canada and is operated by AREVA Resources Canada Inc. (AREVA). The mill was designed to process high grade uranium ores, and has been undergoing a multiyear expansion to increase its production capacity to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to processing high grade ores from the Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk from hydrogen gas. During 2013 Hatch and AREVA designed and engineered a number of novel upgrades for the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit can be safely operated with ores that can evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project.INTRODUCTION The McClean Lake mill was originally designed to process high grade uranium ores, however until 2014 the average ore grade processed was 1%. The facility has been undergoing a multiyear upgrade and expansion to increase its production capacity from 12 to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to new high grade ores, averaging 18% U, from the Cigar Lake Mine. During the last round of metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit had a higher propensity to generate hydrogen gas during acid leaching than previous test work had indicated. Hydrogen gas is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit."

Jan 1, 2017

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By B. J. Keating

"AT PRESENT, it is not certain that any of the sulphide de in the Province of Nova Scotia attain the lower grade limit of 60 per cent sulphides over the minimum area of 1,000 square feet suggested as cut-off specifications for inclusion in this Symposium. However, several of them do include massive sections of substantial size and others represent concentrations of sulphide material that are well above average. It is felt, therefore, that a tentative classification of the deposits and presentation of their geological settings are justified and may help round out the genetic aspects of this study. Accordingly, data considered to be the most pertinent are assembled here in the event that some may fit into larger-scale patterns of mineralization that may take shape as a result of this investigation.The three principal massive sulphide deposits in Nova Scotia are the Stirling, the Smithfield, and the Walton. The locations of these are shown on the accompanying key-map (Figure 1).Three other deposits, the locations of which are also indicated on the map, are the Meat Cove, Rocky Brook, and Gays River de¬posits. Although these fall far short of the minimum dimensions and grade specifications referred to above they are singled out because they have received more than passing attention and are illustrative of the mineralization types to which they belong."

Jan 1, 1960

By O. A. Ojo, E. Anisimov, A. K. Khan

Electro-spark deposition (ESD) has recently generated a great deal of interest in processing aerospace materials. This is due to its potential for joining and repairing difficult-to-weld precipitation strengthened nickel-based superalloys without having problems of welding cracking that often plaque these materials. The short duration of current pulses involved in the process combined with the intermittent contact results in extremely rapid thermal cycle that produces nearly no heat affected zone in the substrate material. The microstructure of electro-spark deposited superalloy was meticulously studied in this work by scanning electron microscopy (SEM) and analytical transmission electron microscopy (TEM). The results show that in contrast to general assumption, the extreme rapid cooling rates involved in the ESD process did not produce partition-less solidification that is devoid of second phase microconstituents in the material. The secondary microconstituents were found formed along the intercellular regions of the solidification microstructure. The nature of these particles and the possible implication of their formation on mechanical properties of ESD processed material are reported and discussed.

Jan 1, 2015

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By Roberto Pena, Cristhian Morales, Darwin Morales, Veronica Cambiaso

"This article makes evident the shortcomings of the current operation of oxygen pipes as well as the damages they cause and why they cause them. When focusing on the causes and effects of these drawbacks, it was possible to develop a new family of thermal lances that could pierce a taphole with the precision of a drill but with the capacity to complete the whole operation. Although efforts have been made to replace oxygen pipes since they are annoying, dangerous and inefficient, nobody had worked to improve the way the traditional oxygen pipe taps/perforates the furnaces and reactors tapholes. In fact, developments made in drills and robotic arms, have failed to replace the oxygen pipe, which despite their negative side effects have been used for more than a century. Observation and theory were key to radically transform this humble tool into a dependable and efficient support in the operation. A good news that it is worthwhile to share for the benefit of all of us, passionate about the world of pyro metallurgy.INTRODUCTION Normally, reports and papers prepared for conventions, symposia or other technical events related to metallurgy aim to relevant topics in the operational field, probably because in them lay the scale economies every company pursues. We intend to give relevance to a matter normally disregarded in operations, but that unmistakably vital: if the furnace or reactor cannot be bled, the pyrometallurgical process will not be completed. Besides, if the tapping task is difficult or is long delayed, the availability of the furnace will be reduced. Consequently, there will be a waste of energy and workers will be exposed to dangerous levels of radiation as well as to work overload and physical injuries Apart from these basic effects, in tapping operations where oxygen pipes are used, we can see serious damages in the smelting furnace, especially in the taphole components such as refractory bricks, taphole jackets and water cooled plates. This paper intends to show that taking care of the tapping task can significantly upgrade not only to the tapping operation itself, but also the whole plant productivity."

Jan 1, 2017

By T. G. Joseph, M. Bolster, M. Curley

"High tirerim loading on haul trucks operating on rough ground frequently manifests as mechanical separations and rim base cracking caused by cyclic fatigue. This paper provides an understanding of the impact of high loads on rim component life and tire footprint, bulge, and deformation behaviour; and develops a maintenance planning tool to predict strain implications of high g loading for a given rim location. Loading tests and analyses were conducted for a tirerim arrangement under increasing load and internal tire pressure. Graphical models were developed, allowing higher g load extrapolation predictions for specific rim components.KEYWORDS g load, Mining, Model, Prediction, Rim, Strain, Tire bulge, Tire footprint, Ultra-class vehicleRÉSUMÉ L’application d’un chargement élevé sur le système pneu/jante de camions de transport rou¬lant sur des terrains accidentés se manifeste fréquemment par des séparations mécaniques et une fissure à la base de la jante engendrée par une fatigue cyclique. Cet article nous permet de mieux comprendre l’incidence de l’application de charges élevées sur la durée de vie des composantes de la jante ainsi que sur l’empreinte, la hernie et le comportement de déformation des pneus. Il développe également un outil de planification de l’entretien visant à prévoir l’incidence des contraintes en cas d’application d’un chargement g élevé sur un endroit donné de la jante. Des essais et des analyses de la charge ont été effectués pour un agencement pneu/jante soumis à une charge et une pression interne du pneu croissantes. Des modèles graphiques ont été développés, ce qui a permis d’établir des prédictions sur la base d’une extrapolation du chargement g plus élevé appliqué à des composantes spécifiques de la jante.MOTS CLÉS charge g, contrainte, empreinte du pneu, exploitation minière, hernie du pneu, jante, modèle, prédiction, véhicule ultralourdINTRODUCTION The purpose of this paper is to report on a proposed and trialed tire performance test based on data obtained from controlled testing that is used to predict the impact of high g loading on hauler rims and tires with greater accuracy. For example, for many years oil sand mining operations have expressed qualitative beliefs that an impact load of the magnitude experienced by a rim and tire arrangement is not detrimental to a rim as a stiff component; however, mining equipment components are subjected to cyclic loading where failure can result from repeated load/unload activity, truncating the peak region of a stress–strain response and resulting in fatigue failure at a stress value that is less than the peak value. The outcome reported by oil sand haul truck maintenance groups indicates they have realized that most high g impacts—such as those experienced by hauler tires and rims operating on poor ground conditions—can result in failure due to cyclic loading, where higher loads require fewer cycles for failure. This high-level loading and the resulting strain transmitted to the rim is evident in the results of the laboratory testing presented in this paper."

Jan 1, 2019

By Gordon W. Parsons, Ross E. Sampson

"THIS PAPER will trace the work done in bringing the Munro underground ""A"" •Orebody into production to replace the open pit, which was scheduled to be completed early in 1959. Included will be an outline of the exploration work and early planning, and of the final decisions on mining methods. Some of the more detailed work will be described and reasons will be given for the decisions made regarding development work, mine ventilation, ground support, and equipment. Brief mention will be made of open pit operations, as these have had some influence on underground development. Also, some of the main geological features of the ore occurrence will be de-scri0bed, as these had to be taken into consideration when making decisions on ore development and mining methods.LOCATION AND HISTORYhe Munro mine of Canadian Johns-Manville is in Ontario, approximately 50 miles east of Timmins and 40 miles west of the Que-bec-Ontari-0 boundary. The producing orebody is in the southwestern part of Munro township. Property controlled by the Company extends nortl1westerly about 2¥2 miles into Beatty township, on which two other interesting asbestos-bearing zones have been partially expl-0red. Active exploration work on the property was started in March, 194.9, and continued until the summer of 1950."

Jan 1, 1960

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Previous testwork by the authors has indicated that both granular coconut shell based activated carbon and a new microporous carbonaceous bead, Lewatit® AF 5, are highly effective in improving the oxidation kinetics and decreasing the elemental sulphur yield when assisting the atmospheric oxidation of pyrite. While the two carbon catalysts show similar results and improvements to the pyrite oxidation, there are differences between them. For example, the activated carbon assisted oxidation showed faster kinetics than the AF 5 assisted oxidation, while elemental sulphur seemed to remain adhered to the surface of the AF 5 after oxidation when much of the elemental sulphur formed during the activated carbon assisted tests was found in the oxidation residue. The objective of this paper is to investigate the differences between the two catalysts through the use of scanning electron microscopy, photography, Raman spectroscopy, surface chemistry analysis, and Brunauer-Emmett-Teller (BET) surface area analysis. With this investigation the authors should be able to achieve a better understanding of the surface chemistry of the two carbon catalysts (i.e. functional groups, charges, acidity etc.) and help explain the strengths and/or the weaknesses of the catalysts when applied to the atmospheric oxidation of pyrite.INTRODUCTION Previous research conducted by the authors, indicated that both a granular coconut shell based activated carbon (activated carbon) and a microporous carbonaceous bead, Lewatit® AF 5 (AF 5), acting as a catalyst enhanced atmospheric pyrite oxidation in ferric sulphate media by approximately 40% when compared to unassisted oxidation and that elemental sulphur yields were increased from 23% to approximately 69 and 63% when assisted by AF 5 and activated carbon respectively (Cowan, Jahromi, & Ghahreman, 2017). The study indicated that although total pyrite oxidation assisted by the two catalysts was similar, differences were noticed in the impact that the two catalysts had on the outcome of the oxidation. Kinetic curves in the Cowan et al. study indicated that atmospheric oxidation of pyrite seemed to reach completion after 48 hours of oxidation when assisted by activated carbon. A similar trend was noticed in the kinetic curves for oxidation when assisted by AF 5, however the oxidation curve did not reach completion until approximately 96 hours (Cowan et al., 2017). This observation indicated that the kinetics of pyrite oxidation are enhanced by both catalysts, oxidation kinetics are much faster when assisted by activated carbon rather than AF 5."

Jan 1, 2017

By Zihe Ren, Edouard Asselin, Marcus Tomlinson, Tianbi Zhang, Jing Liu

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Preg-robbing may arise from natural carbonaceous materials in the ore. Several mechanisms have been proposed in the past decades including a physical sorption process by the carbonaceous matter, or via the reduction of aurocyanide at the mineral surface (Abotsi & Osseoasare, 1986; Afenya, Osseoasare, & Abotsi, 1983; Tan, Feng, Lukey, & Van Deventer, 2005). Nevertheless, the mechanisms of preg-robbing remain poorly understood. Understanding the nature of the preg-robber is of practical importance for the selection of a suitable treatment process. Fine carbon particles in the ore have been recognized as preg-robbers due to their similarity to the activated carbon used in the carbon in leach (CIL) or carbon in pulp (CIP) processes. Previous research has illustrated that the activated carbon (also referred to as amorphous carbon in some literature) has a much higher absorption ability than pure graphite with high crystallinity (Adams & Burger, 1998). Adams et al (Adams, Swaney, Friedl & Wagner 1996) concluded that carbonaceous matter is largely responsible for the overall preg-robbing capacity of a given ore. However, the mechanism of carbon preg-robbing was still not clear mostly due to the complexity of amorphous carbon and its behavior in different solution matrices, and at different pH and temperature (Adams, 1990, 1993)."

Jan 1, 2017

By R. Poulin, M. R. Samis

Real options valuation is an alternative net present value framework that is able to incorporate both management flexibility and dynamic project risks. In this paper, management is considering the development of a satellite low-grade zone while operations in a developed high-grade zone continue. If the lowgrade zone is developed prior to high-grade zone exhaustion, mine capacity must be expanded before additional production from the low-grade zone can be processed. This expansion can be avoided only if low-grade zone development is delayed until the high-grade zone is exhausted. The real option model presented here allows the development and capacity expansion decisions to be reconsidered on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably.

Jan 1, 2006

By P. E. Davidson

The management of solid waste is known to be a large and increasing problem in high-population areas throughout the world. It is not necessary here to add further definition to the nature and magnitude of the problem. Instead, it is the purpose of this paper to describe a new process, called the Andco-Torrax System, which will be of use in converting municipal solid waste into useful energy forms and a granulated slag by-product. The paper includes a description of the first commercial plant for the process.

Jan 1, 1977

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By R. H. Sheaphim

THE RECENT and continuing activity in the Boundary district, British Columbia, makes the publication of this paper timely. The following description and discussions are based on two years' experience in the district as Field Manager and Geologist for Attwood Copper Mines, Limited. The Attwood project was organized by Dr. D. F. Kidd to re-examine the Boundary mining camp. Thanks are due to Dr. Kidd, both for his intelligent guidance during the project and for his permission to publish this paper. Much of the data and many of the interpretations presented are credited to the work of, and to discussion with, Dr. W. H. White, Consultant Geologist, who worked for two field seasons on the project. However, the author assumes the responsibility for this presentation. Dr. C. D. A. Dahlstrom worked with the author during the latter stages of the project. His assistance and advice are gratefully acknowledged.

Jan 1, 1956

By M. L. Wacker

"Cigar Lake high-grade uranium mine in Saskatchewan is operating after 25 years of test mining, construction, and mine flood remediation. Factors include ground stability, groundwater control, radiation exposure, and ore handling. A 10 year test program resulted in validating “jet boring”, a non-entry mining method involving artificially freezing the orebody and surrounding rock; tunnelling to develop access crosscuts below the orebody; installing cased pilot holes through ore; extracting ore using rotating high-pressure water jets within pilot holes; and cavity concrete backfilling. Ore slurry is prepared underground, pumped to surface, and trucked to McClean Lake mill for processing to uranium concentrate.RÉSUMÉ Après 25 années d’essais sur les méthodes minières, de construction et d’assainissement suivant les inondations à la mine, l’exploitation de minerai à haute teneur en uranium Cigar Lake, localisée dans la province de la Saskatchewan, est opérationnelle. Les principales difficultés concernent la stabilité du terrain, le contrôle des eaux souterraines, l’exposition aux rayonnements et la manutention du minerai. Un programme d’essai de 10 ans a abouti à la validation du « forage à érosion », une méthode minière qui consiste à congeler artificiellement le corps minéralisé et les roches environnantes ; à creuser des tunnels pour développer des travers-bancs d’accès en dessous du corps minéralisé ; à installer des puits de fondation pilotes à travers le minerai ; à extraire le minerai à l’aide de jets d’eau à haute pression dans les puits pilotes ; et à remblayer les cavités avec du béton. La boue de minerai est préparée sous terre, pompée vers la surface puis transportée par camion jusqu’à l’usine de concentration de McClean Lake pour le traitement afin d’obtenir du concentré d’uranium.INTRODUCTIONThe Cigar Lake deposit is in northern Saskatchewan, 660 km north of Saskatoon, Saskatchewan, Canada, at the east edge of the Athabasca basin (Figure 1; Bishop, Mainville, & Yesnik, 2016). The operation is jointly owned by Cameco Corporation, AREVA Resources Canada Inc., Idemitsu Canada Resources Ltd., and TEPCO Resources Inc. Cameco has been the operator of Cigar Lake since January 2002. The discovery hole was drilled in 1981. Commercial production was declared in May 2015 and the Phase 1 operation will have a mine life of 15 years."

Jan 1, 2017

By M. Normandin

The performance of various polymers and other macromolecules used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocity and turbidity level, The Jar Test is widely used in the mineral industry to determine the efficiency of solid-liquid separation processes, particularly for gravity settler of the Bayer process. However, a high level of variability is found in the data obtained by this methodology, In this study, different parameters of the cylinder test procedure are evaluated to determine their role in the overall variability of the method, As demonstrated by laboratory testing, the overall variability can be considerably reduced by good laboratory practices.

Jan 1, 2005

By P. Müller, W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"Abstract -The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was Iow, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization .Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This mode] does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5% of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipitation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994

By E. C. Roper

THE Britannia Mining & Smelting Company, Limited, have been operating their property at Britannia Beach, B.C., continuously for nearly forty years and have mined over 33,000,000 tons of ore from orebodies within a belt of highly sheared rocks, five miles long by 2,000 feet wide. The property is in the Coast Range mountains, about twenty miles due north of Vancouver. The mountains rise abruptly from sea level to elevations of 4, 500 feet within a horizontal distance of 7,000 feet. The topography has enabled the orebodies to be developed by adit tunnels. The active mining levels are connected to the adits by incline and vertical service shafts. The main service adits are the 2200, 2700, and 4100 levels (see Figure 1). The mine surface shops, three bunk-houses, and over one hundred dwellings form the townsite camp at the portal of the 2200 level adit. A small camp of one bunk-house and a few dwellings is situated at the 2700 level portal. The beach surface shops and camp, adjacent to the 4100 level adit, service the mill, foundry, and other beach installations as well as the mining from the 4100 level. The ore mined from the various orebodies is delivered to the 4100 main haulage level through a system of rock raises and intermediate tramming levels and is hauled on the 4100 level to the mill.

Jan 1, 1945