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By Milton Orchin

There has been a good deal of speculation as to the function of a vehicle in the coal hydrogenation process. One of the most fruitful theories has been the suggestion that a vehicle such as tetralin functions by supplying hydrogen to the coal, and that the high-pressure hydrogen present in the system serves to regenerate the tetralin. In order to obtain experimental evidence bearing on this theory, a series of experiments was planned in which varying quantities of tetralin were used with coal in the presence of high-pressure hydrogen. This paper reports the results of these experiments.

Jan 1, 1949

By M. J. Ferrante

A process was investigated for preparing Specification-grade nickel (containing less than 1 percent cobalt) by stripping it electrolytically from a nickel sulfate-boric acid solution and using the stripped electrolyte for the preferential dissolution of nickel from basic carbonates of nickel and cobalt. The basic carbonates were produced at the plant at Nicaro, Cuba, owned by the U.S. Government. Determination of the optimum conditions for deposition of Specification-grade nickel indicated that the upper limit of cobalt concentration was 0.1 gram per liter. The pH, temperature, and concentrations of nickel and boric acid in the electrolyte were not critical. An aluminum cathode and two lead anodes were used at a cathode current density of 1.2 amperes per square decimeter.

Jan 1, 1959

By Paul Biggs

This Bureau of Mines report contains information on 63 water flood projects in Colorado. Water was injected in 10 formations located in 58 oilfields. Specific field data presented include location, discovery, development, water supply, fluid injection, oil and water production, oil reserves, and oil recoveries by primary and secondary methods. An estimated 3.5 billion barrels of water has been injected to recover approximately 533 million barrels of oil, a ratio of 6.57 to 1. Most of the injection water is from alluvial deposits, although produced water is used in many fields. Injection water treatment is not a major problem. Appraisal of project success or failure in this report is based on technical, rather than economic, information.

Jan 1, 1974

By J. T. Popp, C. M. McCulloch

This Bureau of Mines study reviews the geological factors that affect methane in the Beckley coalbed in southern West Virginia, including overburden, coalbed structure, type of and changes in lithology above and below the Beckley coalbed, and presence of fractures in the coal and rock adjacent to the Beckley. Depending on the depth, the Beckley coalbed emits from 216 to 520 ft3 of methane per ton of coal mined, and the Bureau estimates that methane emission in a deep, extensively developed mine in this area may exceed 3,000 ft3 per day per ton of coal mined. Average face cleat and butt cleat trends in the Beckley coalbed measured underground are N 33° W and N 53° E, respectively. Close cleat spacing con- tributes to the friable nature of the Beckley and provides easy movement for methane and water. Because rider coals, splits, and carbonaceous shales may contribute methane to mine emissions, predictions of methane emission based on gas content of the Beckley coalbed alone may be conservative. Beckley coalbed reserves in the study area are 234 million tons. The gas content of the Beckley coalbed averages 407 ft3/ton, and the coalbed gas reserves are 108 billion ft3.

Jan 1, 1976

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1330, however, was unusually dry and represents what may be termed "extreme low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscohonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.

Jan 1, 1931

By Raymond G. Travis

This report describes coal-mining methods, power requirements, coal production and distribution, and coal resources of the Bull Mountain coal field in Musselshell and Yellowstone Counties, south-central Montana Investigations in the field, were conducted by Bureau of Mines engineers The report contains a short summary of the geology and geography of the field and discusses the following information secured during the field study: Method of mining practiced at each mine, including a description of each phase of the mining cycle. Coal produced and its distribution at each mine. Power requirements and the consumption of electricity per ton of coal produced by mines. Number of non employed by mines, and the production per man per shift underground and the over-all production per man employed. Estimates of future production and power requirements for the field as a whole. This information should be of benefit to any company or individual planning the development of now coal mines in the area or the expansion of present operations.

Jan 1, 1950

By Roy H. Poston

This paper sets forth the mode of ore occurrence, characteristics of ore and country rocks, methods of exploration, development, and. ore extraction, and the costs of underground operation at No. 8 mine of the St. Louis Smelting and Refining Works of the National Lead Co. located near the southern extremity of the Southeast Missouri lead district. The author acknowledges the assistance of E. T. Campbell, geologist, in the preparation of the paragraphs on the geology of the ores. HISTORY The first record of mining in St. Francois County, Mo., concerns more or less shallow semisurface "diggings" which were worked about the year 174-2. In 1864, however, the discovery of the disseminated deposits, the present source of lead, was made on property near the town of Bone Terre. Winslow has estimated the lead-ore production in this county prior to 1869 to be 59,526 tons.3

Jan 1, 1929

By G. S. Scott

The investigation of the causes, behavior, and control of anthracite mine fires, which the Bureau of Mines has been carrying on has yielded several publications directly applicable to mine-fire problems. 3/, 4/, 5/, 6/, 7/, 8/ As a further step in elucidating the causes of heating in certain anthracites subjected to oxidation, reliable information vial needed relative to the actual amount of heat that is liberated when a unit volume of oxygen combines with anthracite at varying temperatures.

Jan 1, 1939

By Larry L. Anderson

Enormous quantities of organic wastes are produced each year in the United States. The total amount is in excess of 2 billion tons and at least 880 million tons of this is moisture- and ash-free organic material (dry organic solids), representing a potential energy source of significant magnitude that is not being utilized. Bureau of Mines scientists have developed methods for converting these wastes to convenient energy forms. This report itemizes and evaluates for the first time in detail the quantities and sources of moisture- and ash-free organic material contained in manure, urban refuse, industrial wastes, sewage solids, and agricultural wastes in the United States. Furthermore, estimates are presented for amounts of organic wastes collected or concentrated. The potential for fuel, either oil or gas, from both the total organic wastes generated and those collected or concentrated is also estimated.

Jan 1, 1972

By Suresh K. Bhatt

Although overall worker productivity for U.S. underground coal mines is available, productivity by mining method and seam thickness is not. Mining technology has gone through dramatic changes in the past decade, and the industry has experienced a lack of accurate productivity Figures addressing these changes. This information is of great interest in planning for future mining systems as thick and shallow coal seams currently being mined are depleted and exploitation of thinner, deeper, and better quality seams is considered to partially meet the requirements of the 1990 Clean Air Act Amendments. In a cooperative program, the U.S. Bureau of Mines obtained raw mine level production and related data from U.S. Energy Information Administration for 1989 and 1990 and performed the needed statistical analysis. Base criteria, parameters, and salient results of the mine productivity analysis are presented in this report.

Jan 1, 1994

By M. E. Hawkins

Mineral analyses and electrical resistivity measurements of 324 representative samples of oilfield brines from 24 oil-productive counties in Mississippi and Alabama are presented in tabular form. Results of the mineral analyses, which include calcium, magnesium, carbonates, bicarbonates, sulfates, chlorides, sodium, and barium (with strontium if present), are reported in milligrams per liter. Electrical resistivity measurements in ohm-meter2 per meter at 75° F are reported in ohm-meters in the tables. Chemical analyses of formation waters are helpful to operators having water problems associated with petroleum recovery; electrical resistivity values are helpful in making interpretations from electric logs.

Jan 1, 1963

By A. T. Harris

Ground quartzite, known in the industry as amorphous silica, is produced from a quartzite deposit near Honey Brook, Pa., by George F. Pettinos, Inc., of Bala-Cynwyd, Pa. The quartzite is mined by the open pit method and processed in a mill at the mine. The operation regularly produces five standard grades of sand and one grade of crushed stone; however, the company accepts special orders and will produce material to meet the customer's specifications. Beneficiation (chiefly crushing and screening) is controlled by laboratory screen tests on samples taken during preparation of the sand. The chief uses of the sand are for foundry operations, furnace lining, concrete aggregate, and other specialized uses. The quartzite in this deposit is of uniform composition and does not require control by chemical analysis. However, for special purposes, analysis will be furnished.

Jan 1, 1965

By A. T. Harris

Ground quartzite, known in the industry as amorphous silica, is produced from a quartzite deposit near Honey Brook, Pa., by George F. Pettinos, Inc., of Bala-Cynwyd, Pa. The quartzite is mined by the open pit method and processed in a mill at the mine. The operation regularly produces five standard grades of sand and one grade of crushed stone; however, the company accepts special orders and will produce material to meet the customer's specifications. Beneficiation (chiefly crushing and screening) is controlled by laboratory screen tests on samples taken during preparation of the sand. The chief uses of the sand are for foundry operations, furnace lining, concrete aggregate, and Other specialized uses. The quartzite in this deposit is of uniform composition and does not require control by chemical analysis. However, for special purposes, analysis will be furnished.

Jan 1, 1965

By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By Summer S. Smith

The year 1916 broke all previous records of mineral production in the Territory. As a consequence, there has been a noteworthy increase in the number of mines in active operation or under development, though the greater part of the increased output is the result of greater activity at mines already producing rather than of opening new mines. Owing to available funds not being sufficient to meet the cost of travel in the interior of the Territory during the winter months, the Federal mine inspector was unable during the spring to visit the placer mines of the interior as has been his custom in the past. However, by working in close cooperation with the Territorial in- spector, who left Juneau in June to take the first boat down the Yukon to Fairbanks after the spring break-up, it was possible to visit hurriedly all the larger mining centers of the Territory. The Territorial inspector covered the districts from Fairbanks to Nome and the Federal inspector covered those of southeastern and south- western Alaska. A number of applicants have begun mining coal on ground held under free-use 10-acre permits, and have furnished coal for local use. The larger leasing units in the Bering River and Matanuska coal fields have been advertised and applications for leases have been submitted. These applications came too late in the fall for active development to begin before the end of the year. The Government railroad has been built from Anchorage to the center of the Matanuska coal field, and private interests have under- taken the building of a standard-gage road from a point known as Goose City on Controller Bay to Canyon Creek, in the Bering River field. Capital has become interested in the oil fields on Controller Bay, and plans have been made for more active exploration and production. The work of the Federal mine inspector is still handicapped by the lack of funds for additional field assistants and of the office ac- commodations necessary for carrying on the work with the efficiency that its importance warrants.

Jan 1, 1917

By S. J. Pearce

There are a number of methods for determining relatively small quantities of sulfur dioxide in air. However, those methods require fairly elaborate apparatus and laboratory facilities. Frequently in industrial hygiene surveys it is desirable to have a simple arrangement to obtain "on the spot" determinations. This has been accomplished for concentrations of sulfur dioxide of hygienic significance by using the midget impinger and decolorizing a starch-iodine solution.

Jan 1, 1948

By T. R. Jolley

This publication describes the control of fires in inactive coal deposits in the Western United States, including Alaska by the Bureau of Mines. Material presented should contribute to a better understanding of the purpose, process, and benefits of the program. Forty fires were extinguished or controlled in the Western United States and Alaska from 1948 to 1958 under a national program directed by the Bureau's Health and Safety activity. Thirty-five fires were controlled by smothering; three were controlled by the isolation method; and two were extinguished by removing the burning coal, smothering it with incombustible material, and backfilling the fire zone. The fire-control projects were distributed as follows: Alaska 2, Arizona 1, Colorado 9, Montana 9, New Mexico 4, Utah 2, and Wyoming 13. The total cost of the 40 fires extinguished or controlled was $1,203,957. Of this cost, 12.8 percent was engineering and administrative and 87.2 percent was contractual services.

Jan 1, 1959

By Walter Kawa

In connection with its research in producing synthetic liquid fuels from coal, the Federal Bureau of Mines studied reactions of iron and iron compounds with hydrogen and hydrogen sulfide in batch autoclaves. The Bureau hoped to gain indirect evidence regarding the chemical changes that iron catalysts undergo when they are used in the hydrogenation of coal. The information obtained may be helpful in identifying the active form or forms of iron catalysts. At 450° C., with hydrogen at hundreds of atmospheres and hydrogen sulfide at 1 or 2 atmospheres, the thermodynamically stable form of iron is ferrous sulfide in the case of the metal, magnetite, ferric oxide, ferrous sulfate, ferrous oxalate, or the chlorides of iron. However, complete conversion to ferrous sulfide was not achieved at temperatures of 400° to 500° C. for kinetic reasons. Extensive sulfiding of iron, magnetite, ferric oxide, and ferrous oxalate occurred below 400° C., and some conversion of ferrous sulfate to ferrous sulfide occurred at 400° C. In the hydrogenation of coal, ferrous sulfide is the form of iron likely to be available for heterogeneous catalysis when starting with the metal, oxide, sulfate, or oxalate.

Jan 1, 1960

By M. P. Dalton

This paper which describes the milling practice at the Morning concentrator of the Federal Mining and Smelting Co., Mullan, Idaho, is one of a series being prepared by the Bureau of Mines. ACKNOWLEDGMENT The author wishes to acknowledge the assistance given by H. G. Washburn, general manager of the Federal Mining and Smelting Co., and by C. S. Price, assistant mill superintendent, in the preparation of this paper.

Jan 1, 1932

By J. H. Maysilles

The Bureau of Mines is conducting research on various technologies to recover alumina from domestic resources for feedstock to existing aluminum smelting capacity as a means to reduce dependence on imported bauxite, which represents 93 pct of U.S. aluminum requirements. One of the more promising technologies being investigated is the hydrochloric acid leaching of kaolinitic clay. In the hydrochloric acid leaching technology, alumina is recovered from iron-free aluminum chloride leach liquor and separated from impurity elements by sparging the liquor with HC1 gas to crystallize aluminum chloride hexahydrate (ACH). A large-scale crystallizer with a 336-gallon usable volume was constructed and operated to obtain engineering and design data for potential scale up and to demonstrate the ability of the technology to produce specification grade alumina. Test campaigns involving about 1,400 hours of operation were completed. ACH meeting all chemical purity requirements could not be produced by a single crystallization, but was produced by recrystallizing the product from the calcined kaolin clay leach liquor. Product crystals with a size distribution of more than 80 pct plus 100 mesh and 65 pct plus 65 mesh were made at a rate of 10 pounds of ACH/(hr)(ft3). The zirconium tube heat exchanger used to maintain constant process temperature operated with an over-all heat transfer coefficient of 420 to 500 BTU/(hr)(ft2)(°F).

Jan 1, 1981