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By T. G. Pedro, Q. Gonzalo, R. E. Roberto

Anionic surfactants, such as oleic acid and sodium oleate (OLE), and cationic surfactants, such as dodecyl amine-hydrochloride (DDA), are used as flotation collectors of spodumene. However, recovery is poor even if activating ions are used because gangue minerals are also activated. Some reports demonstrate that OLE/DDA mixtures act as a selective collector to enhance spodumene recovery. From mostly macroscopic tests, it has been argued that anionic OLE and cationic DDA form electroneutral complexes, which are adsorbed on the mineral surface through chemisorption; however, no molecular evidence has been presented. Therefore, the adsorption mechanisms of the collector mixtures remain mostly unknown. It seems necessary to first study the behaviour of these surfactants confined in salt solutions, to determine auto-associations when they are pure and cross-associations when mixed, the transition from monomers to micelles, and the structure of the micelles and the effects of pH, temperature and concentration. In this paper, ab initio calculations are first used to determine the surface charge distribution of OLE and DDA separately. Then molecular dynamics simulations are used to determine the conformation, aggregation, and diffusion of these pure and mixed surfactants in freshwater and saltwater with the ionic strength of seawater in a pH range. In particular, it is interesting to determine the various associations that result in mixtures of both surfactants and the impact of alkali and alkaline earth metal cations on the structures formedp. Cations influence the order of the structure and orientation of water dipoles, reducing the mobility of water, ions, and surfactant molecules. This knowledge is critical to improve the molecular understanding of the adsorption mechanisms on minerals. Keywords: Computer simulation, molecular dynamics, flotation, collectors, saltwater

Jan 1, 2020

By А. V. Aksenov, S. G. Rybkin, А. Y. Senchenko

Recovered activated carbon fines result from processing of ore and concentrates via cyanide leaching and sorption of valuable metals on carbon at gold-mining plants. This intermediate product is characterised by the particles sized smaller than 0.6 mm and gold grade up to 300-500 g/t. Processing of carbon fines with recovery of valuable metals is not available at many plants due to the lack of optimal technology. The paper describes the testwork and development of an efficient technology to process carbon fines with the recovery of valuable metals into the target gold alloy. This innovative technology involves pelletising of fine activated carbon particles using an organic binder, drying and further firing of pellets in a grate fired furnace at 800-900 °С. The produced ash is subject to sintering with sodium nitrate and hydroxide at 600-700°С. The sintered ash is then leached in water. The insoluble residue containing gold and silver is removed by filtration, dried and smelted to produce gold alloy. Water solution containing sulphur and arsenic is subject to detoxification. Processing of recovered carbon fines according to the developed technology implies the use of standard full-scale equipment. The offered method to treat gold-bearing carbon fines was patented by the Eurasian Patent Office. Key words: Fine activated carbon particles, valuable metals, pelletizing, firing, ash, sintering, leaching, smelting

Jan 1, 2020

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 25th August, 1971, at 4.15 p.m. Mr V. C. Robinson (President) was in the Chair. There were also present fifty one Fellows, twenty one Members, two Associates, two Students and fourteen Visitors, making a total of ninety one. The President declared the meeting open at 4.15 p.m. OBITUARIES The President: 'It is my sad duty to announce the death of the following members of the institute: H. J. G. C. Arndt, Life Member, joined 1933, passed away 11th May, 1971. J. H. A. Diering, Fellow, joined 1921, passed away 24th June, 1971. L. O. W. Leimer, Fellow, joined 1960, passed away 25th June, 1971. E. A. Meltzer, Fellow, joined 1941, passed away April, 1971. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I would ask you to rise and observe a few moments silence.' MINUTES The President: 'May we confirm the minutes of the General Meeting held on 17th March, 1971, as published in the July, 1971 issue of the Journal?' Agreed. WELCOME TO VISITORS The President: In welcoming you here, ladies and gentlemen, it gives me great pleasure to see so many of our office bearers-our important honorary office bearers-and particularly I would like to welcome our Honorary President, who is, as you know, the President of the Chamber of Mines, Mr John Shilling, and we are 'privileged also to have with us two of our Honorary Vice-Presidents. One in particular I am very pleased to welcome here, and that is Mr G. F. van L. Froneman, who is the Administrator of the Orange Free State, and we extend a very hearty welcome to him, because he is a long way from home. Then we have another Honorary Vice-President, Mr Tommy Gibbs, the Government Mining Engineer, and there are many distinguished guests, whose names I want to give you, so that you will know who they are. We are happy to have present: Mr R. C. J. Goode, Member of Council, I.M.M. London; Mr E. Boden, Manager, A.S. & T.S. of S.A.; Mr G. A. P. Louw, The President, The Associated Scientific and Technical Societies of S.A.; Mr I. R. G. Stephen, The President, The South African Institution of Electrical Engineers; Mr A. S. Robinson, The President, The South African Institution of Civil Engineers; Mr C. F. J. Schneider, The President, The Institute of Land Surveyors of the Transvaal; Mr R. J. Vermaak, The President, The South African Institute of Assayers & Analysts; Prof J. P. F. Sellschop, The President, Joint Council of S.A. Scientific Societies; Mr T. C. Watermeyer, The President, The Federation of Societies of Professional Engineers; Mr G. A. MacWhirther, The President, S.E.I.F.S.A.; Mr C. G. Hinds, The President, The Mine Managers Association; Mr J. F. Aldersley, The President, The South African Institute of Foundrymen; Dr H. O. Reisener, The President, The Institute of Welding; Dr F. P. A. Robinson, The President, S.A. Corrosion Council; Mr A. Bain, The Chairman, Witbank-Middelburg Branch; Prof D. J. Schoeman, The Chairman, The S.A. Institution of Chemical Engineers; Dr N. P. Finkelstein, The Chairman, The South African Chemical Institute (S.Tvl Section); Mr J. M. Meyer, Chairman, O.F.S. Branch. To all these guests and their ladies, I extend a most cordial welcome, and hope that you are going to enjoy the afternoon. MEMBERSHIP The President: 'I have pleasure in announcing that the names of the following candidates having been published in accordance with By-Law 5.2.2., Council has elected them to membership in the following grades: Fellows: Richard Lloyd Blandy, Byron J. Haley. Members: Brian Roger Borton, Frederick Brian Peacock, Peter John Stacey, Kenneth Niles Thanstrom. Students: Peter Boesley James, Kenneth Brian Perel. TRANSFERS From Member to Fellow: Cecil Eugene Fivaz, Peter Edwards. I wish to welcome the new members to the Institute and to congratulate those members who have been transferred to a higher grade. ANNUAL REPORT OF THE COUNCIL AND ACCOUNTS FOR THE YEAR ENDED 30TH JUNE 1971 THE PRESIDENT: We now come, ladies and gentlemen, to the annual report of the Council of the Institute-and our accounts for the year ended 30th June, 1971, and these documents are on your chairs; I know you probably haven't had time to study them yet, but I would like to highlight some of the things which I think are worth mentioning. I would ask you to take, first of all, ladies and gentlemen, the report of the Council as being read, and before moving adoption, however, there are certain salient points I wish to touch on, and I will leave the financial side of this entirely to our very competent and worthy, Honorary Treasurer, Mr Denis Maxwell.

By M. Getz, G. Asbjörnsson, M. Evertsson, E. Clausen

The mining and minerals processing industry is gradually being digitalised to improve efficiency and reduce waste. One aspect of this transition is to ensure that relevant process-data in sufficient quality and quantity is given to the operator in the right format and at the right time to improve decision-making. Augmented reality (AR) can serve as a potential ICT-based support tool for human operators to achieve this goal. With AR, virtual information is combined with the real world in real-time. Therefore, AR technology has the potential to fulfil the need for improved data visualisation in Industry 4.0. This article is the result of a collaborative effort of Chalmers University of Technology and RWTH Aachen University to identify selected state-of-the-art applications of AR that are currently being applied in the mining and minerals industry or selected related industries. This paper aims to show opportunities for the application of AR in the mining and mineral processing industry with selected conceptual applications. This paper concludes with several requirements identified as necessary to implement the conceptual applications of AR in the mining and minerals industry. Keywords: Augmented reality, mining, mineral processing

Jan 1, 2020

By D. D. Aksenova, V. A. Ignatkina, L. A. Samatova, A. V. Lygach, E. D. Shepeta

Calcium minerals such as scheelite, phosphate, apatite are valuable minerals, which have similar flotation properties to the calcium gangue minerals. An additional problem is the fine dispersion and close mineral association of valuable and other minerals. Low polar compounds (non-ionic surfactant), such as fatty iso alcohols, neonol and phosphol, and their combinations with sodium oleate have been studied using flotation of monominerals and ore flotation; ATR IR spectroscopy and TEM for study surface of minerals; UV spectroscopy for control solubility, aggregation and de-aggregation processes. Increase in solubility of fatty acid collectors was confirmed by low soluble (heteropolar) compounds. Oxyethylated esters of phosphoric acid are adsorbed on phosphorite by -O2PO2R2 and on other rock minerals by donation of OH bond. Same effect shows difference of adsorption of fatty iso alcohols on calcite and scheelite. The different forms of adsorption of ionic and nonionic compound on a sparingly-soluble mineral surface creates distinction of the flotation kinetics and technological balance of ore flotation. The results of the separation of flotation of scheelite from calcite depend on the order of pouring into pulp of fatty iso alcohols and oleate, and their ratio in the mixture. Increasing scheelite recovery into rougher scheelite concentrate by 3.6% for both the flotation and sludge classes was obtained. Calcite recovery varied slightly upwards or downwards by 0.8-2.4%. The use of the non-ionic surfactant phosphol in combination with a fatty acid soap allows for obtaining a phosphate concentrate with more than 28% P2O5 content and almost 80% recovery in flotation operation. It is not obtainable with other reagent regimes. Keywords: Flotation, calcium minerals, oleate, fatty isoalcols, neonol, oxyethylated esters, adsorption

Jan 1, 2020

By K. C. Corin, M. Tadie, N. Ndamase

Fresh water conservation efforts and strict environmental regulations have forced the mining industry to reduce freshwater consumption and effluent discharge. This is achieved by recycling process water back to mining processes. The performance of flotation circuits depends on the pulp chemistry. When process water is recycled to flotation cells, organic and inorganic species that have accumulated over time alter the pulp chemistry. The presence of accumulating ionic species such as SO4 2- and S2O3 2- has been found to hinder the adsorption of collector ions onto mineral surfaces. Sulphide minerals are semi-conductors; electrochemical reactions take place on their surfaces. The adsorption of collectors onto mineral surfaces takes place via electrochemical reactions. This study, therefore, aims to investigate how the presence of accumulating ionic species at varying ionic strengths affects the adsorption of sodium ethyl xanthate onto chalcopyrite from an electrochemical perspective. Synthetic plant water comprised of single salts with varying ionic strengths was used. Rest potential measurements were conducted to investigate collector-mineral interactions in the presence of these ionic species. Microflotation tests were performed to determine whether the presence of these ionic species affects mineral floatability. Higher chalcopyrite recoveries were achieved in the presence of SO4 2- than in the presence of S2O3 2-. Rest potential measurements were found to successfully predict microflotation performance in the presence of the ions of interest. Keywords: Flotation water quality, electrochemical adsorption; xanthate collectors

Jan 1, 2020

By C. C. Birch

Due to grade estimation uncertainty, two statistical errors can occur. The Type I error is where material is classified as ore and mined, despite the true value being below the break-even grade. This material is dilution. The Type II error is where the material is estimated to be below the cut-off grade and is classified as waste, although the true grade is actually above the break-even grade. This material is not mined and is lost. The uncertainty was assumed to follow a normal distribution in a previous study. For this study, estimated block values are compared to those determined after mining (the best estimate of the true grade). This actual data from four mines shows that the uncertainty follows a Laplace. There is no single solution regarding adjusting the cut-off grade away from the break-even grade, considering estimation uncertainty, that could be applied to all gold mines. However, adjusting the cut-off grade downwards (up to 22% for one mine) is noted when optimizing the profit considering grade uncertainties. This type of adjustment could open up significant mining areas and extend the life of the mine.

Jul 2, 2022

By P. Saari

The Talvivaara deposits are located in Eastern Finland, within the Kainuu Schist Belt. These polymetallic sulphide deposits are of relatively low grade, but bioheapleaching enables economically profitable nickel extraction from the ore. Zinc, cobalt, and copper are also produced. Talvivaara?s production process begins with large-scale open-pit mining and four crushing stages, followed by stacking of the ore in bioleaching heaps. The ore is first leached for 13?14 months on the primary leach pad, after which the leached ore is reclaimed, conveyed, and re-stacked on the secondary heap pad. After secondary leaching, the barren ore will remain on the secondary heaps permanently. In the metals recovery process, the metals are precipitated from the pregnant leaching solution. Construction of the process was begun in spring of 2007 and first metal sulphides were produced at the plant in October 2008. The development of the bioheapleaching process was begun in a 17 000t on-site pilot heap operated during 2005?2008 and has continued in the industrial heap. At industrial scale, the development measures have focused on improving the permeability and aeration of the heap. Challenges with crushing and aerations systems at the beginning of industrial-scale leaching delayed the increase in metal recovery, but after the first two operational years the leaching results have improved significantly and the process is performing as targeted.

Jan 1, 2012

At the Annual General Meeting of the Chamber of Mines of South Africa, held in Johannesburg on 29th June, 1982, the following leading members of the mining industry were elected to office for the 1982-1983 term: Mr W. W. Malan President Mr C. T. Fenton Vice-President Mr G. Y. Nisbet Vice President William Wouter Malan was born in Springs on 7th November, 1928, and was educated at the Springs High School and the University of the Witwatersrand, where he obtained a B.8c degree in mining engineering. Diamond Mines. Mr Nisbet became a consulting engineer of the Anglo American Corporation in 1972, and a deputy managing director of the Gold Division in 1974. George Young Kisbet was born in Benoni in 1923 and was educated at Pretoria Boys High and the University of the Witwatersrand. Mintek reports Report 2010D A process for the recovery of rare-earth oxides from monazite. (First published 16th March, 1979). Report 2073D A preliminary investigation of the concentration process at Ucar Minerals Corporation. (First published 19th September, 1980). Report 2092D The recovery of pyrite from gold ore by gravity separation. (First published 28th November, 1980). Report M13 Factors affecting the production of fines during the screening and handling of highcarbon ferromanganese.

Jan 1, 1982

By R. B. Khumalo, F. K. Mulenga

Sampling in a continuous flotation plant is always a challenge as these plants are meant for production and not research work. The continuous flotation operation used in this work produced three sets of data: the first was based on overall plant performance, done by sampling the feed, concentrate, and tails; the second was based on the roughers row cell-by-cell; the third set of results came from the cleaners/recleaners row cell-by-cell. The highest recovery results in all sets of data obtained lie in the particle size ranges of 40 μm and 100 μm, which is in agreement with results by other researchers in the same field. King’s theoretical (model) recovery proved to be able to fit the experimental data but there is still room for improvement as the sum of squared error ranged between 400– 1200. Data obtained in continuous flotation operation could be used with batch flotation test-work to characterize scale-up of flotation cells.

Jan 1, 2023

By C. van Buuren, R. F. Sandenbergh, P. J. Pieterse

Gold extraction from double refractory ores using conventional cyanidation has proved challenging due to the presence of carbon within the ore. Carbon particles may adsorb leached gold resulting in gold losses to tailings, i.e. preg-robbing the gold. Some of the preg-robbed gold may be recovered by the application of the HiTeCC process on CIL tailings. The process developed by Metso Outotec involves caustic conditioning of the tailings followed by high temperature desorption and simultaneous adsorption onto virgin activated carbon of the aurodicyanide. The aim of this paper was to develop a model for the HiTeCC process which could be used to support design and optimisation of the process, based on the adsorption characteristics of the preg-robbing and activated carbons. It was found that accurate experimental isotherms can be used to predict the behaviour of preg-robbing adsorbents. Comparing the sorption isotherms for preg-robbing ores and activated carbon indicated similar dependencies on temperature and ionic composition. Applying boundary layer diffusion models coupled with experimentally determined isotherms for preg-robbing ore and activated carbon, the HiTeCC process was successfully simulated at experimental and plant scale. Gold recovery of the HiTeCC process is most sensitive to the temperature of desorption and gold loading of the activated carbon, with increased temperature improving recovery. The gold loading of the activated carbon in the process should always be maintained lower than that of the normalised pregrobbing carbon gold loading to ensure favourable conditions for adsorption onto the activated carbon. Caustic conditioning stabilises adsorption and is therefore not necessary during the desorption stages of the process, but potentially improves recovery during adsorption. Keywords: Preg-robbing, refractory gold ores, HiTeCC, aurodicyanide

Jan 1, 2020

By I. Zh. Bunin, M. V. Ryazantseva, V. A. Chanturiya

The paper proposes a new method for selective calciferous separation. The effect was achieved through the application of the combination of high-power electromagnetic pulses (HPEMP) and a specific reagent regime of the flotation. The combined application of HPEMP with the special reagent regime allowed for the improvement of the scheelite floatability: the recovery of CaWO4 rises from 41.2 % (untreated sample) to 58.5 (sample treated at 103 pulses). In contrast, the floatability of calcite decreases significantly: the recovery of calcite drops from 74.7% (untreated sample) to 41.1 % (sample treated at 103 pulses). The conditions were found for the selective separation of the minerals with very close flotation properties. Keywords: Calcite, scheelite, flotation, high-power electromagnetic pulses, DRIFT, XPS

Jan 1, 2020

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

By L. Godfrey, Z. Nontso, F. Magweregwede, B. Maphalala, S. Khan

The aim of this paper was to establish if mineral resource scarcity is a driver for South Africa to transition to a circular economy. The project objectives were achieved by investigating economically viable, and critical or strategic minerals remaining in South Africa, as well as resource scarcity, as a driver for South Africa to transition to a circular economy. The study found that some minerals in South Africa, such as iron ore, lead, manganese, gold, and cobalt have less than 50 years of economically viable mining remaining. At least 18 minerals can be classified indicatively as critical or strategic: aggregates, bauxite, chromite, cobalt, copper, gold, graphite, iron, limestone, lithium, manganese, nickel, phosphorous, platinum group metals, rare earth elements, silver, titanium, and vanadium. The classification was based on the minerals’ economic importance, supply risk, and potential use in the development and manufacturing of emerging technologies. The findings suggest that the scarcity of mineral resources is a critical driver for the country to transition to a circular economy. Other identified drivers include socio-economic factors, climate change commitments, and business objectives. All minerals are non-renewable resources and at risk of depletion, therefore sustainable extraction and use are critical. Priority should be directed at investigating circular economy opportunities and substitutes for commodities at risk of being depleted within the next 50 years. There is an opportunity for South Africa to transition from a minerals export-based model to one that promotes local mineral beneficiation and manufacturing of end products.

Mar 5, 2025

By B. Emwanu, R. A. Raju

The implementation of new technology in mining can be likened to a paradoxical situation or dilemma, where, on one hand, major mining projects are not able to solicit investor funding unless it is proven that the business cases were developed using tried and tested mining methods. On the other hand, new and innovative mining technology and mining methods need first to demonstrate and prove themselves under real production conditions over a reasonable period before they can be considered bankable feasibility studies in the mining industry. This dilemma locks new mining technology investments in a continuous cycle of underinvestment. Technological innovations are particularly relevant to the mining industry, which deals with the challenges of depleting access to resources, requiring new solutions to remain sustainable and competitive. In the last decade, the mining industry has come to realise that technological innovations can directly contribute to its sustained competitive advantage (Sanchez, Hartlieb, 2020), helping to reduce costs, lessen environmental impact, increase production, and improve mineral recovery. While understanding barriers and drivers for technology adoption is important for the success of technology implementation efforts and the sustainability of the mining sector (Muduli et al., 2013), this paper suggests strategies to exit the dilemma, proposing a preliminary framework.

Oct 24, 2025

By H. Mulder, M. C. Bekker

The objective of this paper is to describe the research followed in creating a generalized, readiness assessment tool for mining projects. We start by highlighting the need for the assessment tool and then progress towards explaining the methodology followed during the study. The selection and finalization of the list of elements, sections, and categories that make up the unweighted values are described, followed by a summary of the weighting process applied. The outcome of this process is a weighted readiness assessment tool for mining project studies. The main benefits of the tool are that it will guide decision-makers and project managers through the definition phases of the project and improve the likelihood of project success.

Jul 2, 2022

By C. C. Pretorius, S. Ramjee, R. J. Mostert

The study investigates the effect of prior corrosive exposure on crack growth resistance behaviour of thin sheet (3 mm thick) aluminium alloy 2024-T3 at slow strain rates. Compact tension specimens were exposed to standard corrosive environments that simulate accelerated atmospheric corrosion attack. Two corrosive environments were considered – an exfoliation corrosion (EXCO) solution and a 3.5 wt% sodium chloride solution. The unloading compliance R-curves of the two-hour EXCO-exposed specimens revealed a significant degradation of approximately 11% in the crack growth resistance behaviour (Kc_e values) compared to the baseline (air-exposed) values. Furthermore, secondary intergranular crack formation was also revealed in the plastic zone ahead of, and adjacent to, the crack tip of these specimens; which formed during the crack growth resistance loading. It is postulated that the observed degradation of the Kc_e values of the EXCO-exposed material is due to hydrogen embrittlement since the exposure times for the EXCO evaluation were limited to ensure that uniform corrosion dominated; that is, significant penetration of corrosion damage and pitting due to localized corrosive attack did not occur. The sodium chloride-exposed specimens revealed a similar degradation (13%) after 24 hours exposure. However, slight intergranular corrosive attack and isolated pitting were observed on the exposed surfaces prior to crack growth resistance loading, resulting in notch effects that could assist in crack growth. Pitting and intergranular corrosion were, however, not observed at the pre-crack tip. The relative contributions of the notch effects and the hydrogen embrittlement during the degradation of the KR performance are, therefore, unclear.

Apr 1, 2021

By J. Petersen, K. Shaik1, H. Kolev, Z. Cherkezova-Zheleva

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.

Mar 6, 2026

By W. F. McKechnie

"Southern Africa is generally thought to be well explored, with only limited potential for major new diamond discoveries. However, Chiadzwa in Zimbabwe and reports of a significant new kimberlite find in Angola are testimony to the dangers attached to an attitude that ‘there is nothing left to find’.Since the major discoveries in the central interior of South Africa in the 1870s, diamond exploration in the region has been led by market and political factors that influence the key exploration drivers of opportunity and value proposition. Unexpected new discoveries by new players always impact on existing producers and, from time to time, denial of opportunity through political or protectionist policies has inhibited investment in exploration.Entrepreneurial exploration appetite in southern Africa will be tempered by the potential value equation and security of investment. Overlaid on this, developments in diamond recovery technologies provide opportunity to reinvigorate current mines and old prospects previously considered too difficult or costly to exploit. Position on the cost curve will remain a key factor for survival in an increasingly competitive environment. IntroductionThe diamond industry in southern Africa boasts a history of 150 years of discovery and mining, forming the cornerstone of development of the core, modern economies at the southern tip of Africa.Since the discovery, in the 1860s and 1870s, of the secondary diamond placers and primary diamond-bearing kimberlite deposits in the central interior of the then Cape Colony and Orange Free State, southern Africa has endured as the pre-eminent diamondproducing region in the world. Notwithstanding periodic competition from significant new discoveries in other parts of the globe and the paucity of recent, new discoveries in the region, its ranking is unlikely to change in the short to medium term.In a geological context the region contains the Kaapvaal-Zimbabwe and Angola-Kasai cratons, identified in terms of Clifford’s rule as areas inherently prospective for diamonds, being underlain by portions of the Earth’s crust that are tectonically stable and older than 1.5 billion years (Clifford, 1992). Although the Democratic Republic of Congo (DRC) would, in a geographic context, be considered to be part of Central Africa, for the purposes of this review it is included in southern Africa since northeast Angola and the adjacent parts of the DRC form part of the same geological terrane and diamond production from both countries needs to be considered together. Historical and current diamond production from the northeastern parts of the DRC around Kisangani is not considered to be significant and its inclusion in the overall numbers for the DRC does not materially affect the overall picture presented here."

Feb 1, 2019

By T. Mahlangu Mahlangu, T. Fungene, K. C. Sole

"Although oxygen is widely employed as the oxidant of choice in gold leaching by cyanide, its low aqueous solubility presents some drawbacks in practical application; hydrogen peroxide has therefore been considered as a possible alternative. The aim of this investigation was to study the catalytic decomposition of hydrogen peroxide, which generates an oxidizing intermediate species, and to understand its effect on cyanide destruction. Operating conditions that facilitated the effective decomposition of hydrogen peroxide were established by varying the pH and catalyst type and concentration. The oxidizing intermediate, detected using an indirect technique, was found to be the hydroxyl radical (OH?). OH? is commonly generated in acidic solutions, but this work demonstrated that it is also produced at the alkaline pH values necessary for cyanide gold leaching. The effects of free and complexed iron and copper catalysts on the oxidation and consumption of hydrogen peroxide and cyanide were also investigated. It was shown that the cyano complexes of Fe(II) and Cu(I) are also effective as decomposition catalysts. Hydrogen peroxide concentrations above 0.01 M decreased the free cyanide concentration, which was attributed to the probable formation of the cyanate anion (CNO-). Although cyanide consumption increased due to its oxidation in the presence of OH?, excessive cyanide consumption in the presence of copper was attributed primarily to its complexation by the unstable copper(I) cyanide species. Rate constants for the decompositions of H2O2 and cyanide by ferrocyanide and copper cyanide were calculated; the latter was identified as being a better catalyst. IntroductionLeaching of gold from its ores using cyanide has been employed for well over a century (Habashi, 2016). Addition of cyanide converts the gold into a cyanide complex (Au(CN)2 -) that is soluble in water (Wang and Forssberg, 1990). The leaching reaction can be represented as Equation [1]:"

Dec 1, 2018