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By K. I. Cunningham, C. S. Spirakis

Two types of native sulfur deposits have been found in Lechuguilla Cave: thin late-stage crusts and massive early- formed deposits. Most, if not all, of the crusts appear to have formed by remobilization of native sulfur contained within gypsum and sulfur masses. The process is occurring today and is slowly converting the sulfur to gypsum. The absence of primary gypsum or reductants in the cave indicates that the early-formed massive sulfur deposits did not form by in-place reduction of sulfate, which is the process that formed the commercial sulfur deposits in the Delaware basin. Instead, it appears that H2S dissolved in basinal brines was oxidized by oxygen in near-surface ground waters in the cave. Fluid- inclusion data, which suggest the presence of both fresh water and saline water as the sulfur formed, support this interpretation. Although individual sulfur deposits in Lechuguilla Cave are no more than several tens of metric tons, the abundance of secondary gypsum (as much as 10 meters thick) indicates that native sulfur may once have been much more extensive.

Jan 1, 1992

By Roe-Hoan Yoon

Froth flotation is widely used for separating particulate materials from one another in aqueous media. The basis of this important separation process is to control the hydrophobicity of particles. However, it is difficult to predict the kinetics of flotation based on contact angle (?), which is a thermodynamic property. A solution to this difficulty would be to develop a relationship between ? and the gradient of the hydrophobic forces across the solid-liquid and bubble-liquid interfaces. Such information can be obtained using the surface force apparatus (SFA), the atomic force microscope (AFM), and the thin film balance (TFB). The present communication reviews the results of the measurements conducted using these methods, and offers a methodology for deriving a rate equation for bubble-particle interactions

Jan 1, 1999

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulphide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular S02 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, i.e., pyrrhotite, pentlandite, pyrite, chalcopyrite and violarite, have agglomerated and reacted to form two intergrown phases: pyrrhotite solid solution (FeO.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu 0.03S). Magnetite formed euhedral crystals, skeletal crystals and dendrites at the margins of the matte. Prismatic, ferrohypersthene and octahedral Mg-Al-Fe spinet crystals and dendrites are present in the glassy slag. Key words: Nickel sulfide concentrate, Iron silicate slag, Bath smelting, Mineralogy, Microscopy

Jan 1, 2003

By L. G. Austin

The general manner in which the liberation function must change during size reduction is described. Data from float-sink (washability) analysis of a coal is used as an illustration, and a Locking Index is defined and calculated. Ash is not distributed equally with respect to sieve size but is concentrated more in the finest sizes. On the other hand, the ash is less locked with coal in the finer sizes than in the larger sizes. Further crushing showed decreased locking in intermediate sizes, but the material in the fine sizes (produced from breakage of highly locked larger sizes) was more locked than material of the same size in the feed. Future work is also discussed.

Jan 1, 1995

By Terry L. Logan, Arfon H. Jones, James C. Seccombe

Deeply buried coal seams [greater than 3000 ft (914 m)] are difficult and sometimes hazardous to test and complete due to coal sloughing, formation pressure anomalies and coal fine generation. Data collected while stimulating two deep coalbed methane wells located at the Gas Research Institute/Resource Enter¬prises, Inc. "Deep Coal Sean Project" test site in the Piceance Basin, Colorado, is presented in this paper. A single thick coal seam was completed openhole in each well. Core data, reservoir data, in-situ stress measurements, and pre-stimulation calibration test data were collected at the site to use in the design of the fracture stimulation treatments for both wells. A nitrogen foam fracture fluid treatment was selected for the first well and a linear gelled water for the second well. Treatment pressures were monitored with a downhole quartz pressure transducer. Atypically high treating pressures were observed, possibly indicating coal fines plugging at the fracture tip or increase in fluid viscosity caused by interaction of the generated coal fines with the fracturefl uid. In addition, a comprehensive fracture diagnostic effort was employed during the fracturing of the second well; namely, triaxial borehole seismic, seismic televiewer, hydraulic impedance monitoring, gamma ray log (in conjunction with radioactive additives in the sand), and temperature log. The results indicate a vertical fracture was created parallel to the face cleat as expected.

Jan 1, 1986

By E. V. Manlapig, B. K. Gorain, N. W. Johnson, K. Ward

A flotation model developed at the Julius Kruttschnitt Mineral Research Centre was used to predict the performance of copper rougher and scavenger circuits at the copper concentrator at Mount Isa Mines. The model describes the kinetic response of an ore in a flotation cell in terms of ore floatability, cell characteristics and froth recovery. The floatability parameters of the rougher feed ore were obtained directly from a detailed plant survey. Flotation analysis was carried out for twenty different size-by-liberation classes to account for the effects of particle size and liberation on flotation. This paper investigates the capability of the model to predict the flotation behavior of 20 different size-by liberation classes in the rougher and the scavenger banks.

Jan 1, 2000

By J. A. Brierley, C. L. Brierley, R. C. II Blake, S. McGinness

A principal long-term goal of this laboratory is to achieve a detailed understanding at the molecular level of the microbial-dependent solubilization of minerals. Three recent advances in this research are summarized. (i) An in situ electrolytic procedure is described whereby large quantities of autotrophic iron-oxidizing organisms may be achieved for fundamental or applied studies. Over 600 grams wet weight of Thiobacillus ferrooxidans were harvested from a single 55-gallon growth vessel. (ii) A basis is presented for classifying some 70 different iron-oxidizing bacteria into one of 4 categories, depending on the type of redox-active electron transport proteins expressed during aerobic respiration on reduced iron. Comparative spectroscopic analyses indicated that different electron transport mechanisms exist in different genera and species of acidophilic bacteria that respire on iron. (iii) A method is introduced to investigate the binding interaction between bacteria and minerals, based on changes in the electrokinetic properties of the two species. Preliminary experiments indicated that the electrophoretic mobilities of pyrite and Thiobacillus ferrooxidans were both altered when the two colloid particles were mixed prior to the actual electrokinetic measurement. The need for more basic information regarding all aspects of the microbial-dependent solubilization of minerals is evident.

Jan 1, 1993

By John A. Herbst, William T. Pate

Column flotation is emerging as one of the most important new separation technologies of the decade. Attendant to this development is the need for a quantitative understanding of the dynamic characteristics of columns. An understanding of the many important sub-processes occurring in the cell makes possible the development of dynamic simulators for flotation columns which will aid in the design of control systems for dynamic and steady state optimization. This paper presents a dynamic model for the column flotation cell developed from a population balance point of view similar to that which has been successfully applied to conventional flotation cells. In particular, the mixing that occurs within the pulp is modeled with a distributed-volume, mixer-in-series model as an approximation to the axially dispersed plug flow transport that occurs in the cell. This simpler approach avoids the distributed transport model which often leads to mathematical intractability. Other phenomena dealt with are the attachment and detachment of particles from bubbles in the froth and pulp, the transport of water and the bubble volumes with the froth and pulp phases. Simulation of the flotation of an Illinois No. 6 coal in a pilot plant flotation column were performed to test control strategies.

Jan 1, 1989

By D. Altizer, E. Thompson, K. F. Unrug

Because of frequent sudden changes in the geologic composition of strata, the extrapolation of rock properties obtained from core samples to the surrounding areas can cause problems. To address this issue, a method of rapid strength testing in situ using a borehole penetrometer is being developed. This method, as opposed to conventional laboratory testing, does not require rock samples to be retrieved and handled/machined before testing. Rock strengths are determined di¬rectly on the drill-hole wall. The latest development is a borehole penetrometer that requires only a 38.1-mm- (1.5-in.-) diam hole. The small diameter of the penetrometer body allows for the drilling of test holes with production mine equipment such as a roof bolter. The new penetrometer allows for the possibility of a broad application in coal mines, as well as in hard rock mines and tunneling. The principles of the apparatus are described and are illustrated with examples of its applications.

Jan 1, 2002

All coal preparation unit operations in which fine coal is handled depend to some extent on wettability of coal surface by water. The wetting results from interactions between the coal surface and water molecules that are determined by the composition of coal matrix (interrelated with coal rank) and heterogeneous constituents such as oxygen functional groups, mineral impurities and pores. The contact angle of water on an unoxidized, homogeneous coal hydrocarbon matrix is calculated to be 100o, and much lower values measured on real coal specimens result from contributions from the heterogeneous constituents. While the effect of wettability is critical in flotation and oil agglomeration, suppression of respirable dust, and coal water fuels, it has been shown to play a significant role also in coal flocculation with semi-hydrophobic and totally hydrophobic flocculants.

Jan 1, 1995

By Malcolm Scoble, Sean Dessureault, Scott Dunbar

Budgets are key financial and behavior drivers for most businesses, including mining. Budgets are used to link strategic objectives to tactical decisions, to measure performance, and to provide basic financial planning. More accurate and pertinent budgets should result in improved strategic decision making and performance measures. This paper discusses how a process based production and cost database, based on activity based costing models and the one year production plan, can be used to create the annual budget for an operating mine as an Activity Based Budget (ABB). A case study is used to compare budgets derived from traditional methods and an ABB approach. It is evident that the ABB method is more accurate.

Jan 1, 2002

In the hierarchy of performing mine planning tasks, production scheduling is naturally at the bottom. Yet good production scheduling is probably the most demanding and difficult task to achieve for various reasons. Being the last task in the mine planning hierarchy, a proper production schedule must not only conform to both the long-range and the short- range mine plans but also satisfy many practical details that are unique to day-to-day operations. For example, the averages which were good enough for both long-range and short- range mine planning are no longer good enough for production scheduling. Instead, the variations become the overriding concern. The answer must also be obtained quickly and on time, thus adding another dimension to the overall problem. Because of these considerations, many production scheduling problems have been begging for solution during the past decade. Many attempts were made to solve the production scheduling problems in the past using computers and the available operations research (OR) techniques, particularly among academic groups. However, it is probably true that, compared with the current full-time computer usage in long-range and short-range mine planning, very little computer usage is being made in production scheduling to date.

Jan 1, 1979

By G. R. Tostengard

Gold plant performance during the start-up period, which extends until capacity production is sustained, has a major impact on the internal rate of return and the net present value of gold projects regardless of mining and processing configurations. The start-up period experiences substandard production, extra expenses, and sometimes reduced recovery. This results in lost profits, a portion of which are recouped at the end of the life of the mine. Poor start-up performance can put projects into financial jeopardy. The gold mining industry regularly experiences start-ups ranging from good to poor. Problem areas, which affect start-up performance, include shortcomings in ore reserve sampling and testing, equipment design and installation, untrained plant operators, inability to cope with problems which arise, and organization of the maintenance program. An investment, equal to 0.5% to 1.0% of plant capital cost, in programs to prepare for start-up, in advance, is recommended. Investment in such a program will make a good start-up possible. Without it the best result which can normally be expected is a fair start-up. Developers of new gold mines are urged to compare the cost of this investment with the anticipated increase in project net present value. Funds for this investment should be included in feasibility studies.

Jan 1, 1988

By M. J. Virnig, C. P. J. Van Vuuren, A. J. Botha

The Zadra, AARL and organic elution processes and variations of them are presently widely used to recover gold from activated carbon. Despite this the study of the kinetics of elution have received relatively little attention. It is the aim of this study to investigate the rate processes taking place during elution in both inorganic and organic solutions. Batch adsorption and elution rate and equilibrium experiments were performed. The spatial concentration of gold inside carbon particles at various stages of the adsorption and elution processes were measured with a scanning electron microscope using an image analyzer to control and manage the micro-analysis data. The activated carbon particles exhibited film and intra-particle mass transfer rate- controlled behaviour during adsorption in a caustic aqueous solution at 95°C. Elutions in the aqueous caustic acetone solution at 30°C and the caustic aqueous solution at 95°C were unaffected by change in stirring rate. Elution was modelled by desorption reaction rate-control at the outer surface of the carbon particle. Adsorption and elution isotherms under duplicated solution conditions showed reasonable agreement for the inorganic solution and a large disparity for the organic solution.

Jan 1, 1993

By Thomas H. Hibner, Daniel Tempelis, John E. Shamma

Environmental protection of nearby resources is an issue that can not be ignored in tunnel construction. The Inland Feeder Arrowhead Tunnels Project is no exception. With keen interest from various stakeholders, Metropolitan developed a Groundwater Monitoring and Mitigation Plan. This plan provides for monitoring and management of selected water resource features within the San Bernardino National Forest along the proposed tunnel alignment. The plan specifically provides for monitoring of streams, springs, seeps, and piezometers for water temperature, pH, specific conductance, and chemical analyses, as well as flow or groundwater elevation. Metropolitan uses the data to evaluate for and manage potential impacts from groundwater ingress during construction of the Arrowhead Tunnels.

Jan 1, 2003

By Jerry M. Whiting, Samuel Frimpong

Superior ventures selection and the subsequent management of their development and production are crucial in the competitive environment of the upstream minerals and energy industry. An important element of this chain is the management of uncertainty and risk dynamics. In the world of faster and more complicated technological and environmental changes, international competition and commodity market dynamics, thorough and sophisticated valuation must be carried out to establish a venture's value and return on investment. Thus, managers and investors must use methods that respond to market dynamics, investment and feasibility study options and provide relevant information for strategic investment decisions. Conventional methods have no built-in procedures to help investors analyse these options. Modern financial methods based on the dynamic arbitrage theory overcome these and other limitations of conventional methods. In this study, dynamic arbitrage theory has been used to formulate 3D parabolic differential equations that govern the stochastic processes of a copper mining venture with ongoing feasibility studies. The alternate direction implicit algorithm is used to solve the numerical approximations of the differential equations and their boundary conditions. Phase dynamics of the venture have been analysed to provide investors the appropriate timing for strategic investment decisions. The study also shows the amount and value of appropriate feasibility studies required to maximize the value of the mining venture.

Jan 1, 1996

By Charles L. Karr

Grinding is a necessary component in the processing of a number of minerals, and improvements in this area could provide substantial cost savings for the minerals industry. Optimizing the process of grinding, however, is a difficult task because there are multiple objectives; i.e., several aspects of the process are important including the fineness of the ground product, the energy consumed in the process, and the viscosity characteristics of the final slurry. Genetic algorithms (GAs) are search algorithms based on the mechanics of natural genetics and have been proven capable of solving multiple objective optimization problems. These robust search techniques are able to rapidly locate near-optimum solutions across a broad spectrum of very difficult optimization problems. In this paper, two varieties of GA are used to optimize a grinding process as it is described by a computer model: (1) a simple genetic algorithm (SGA) and (2) a micro genetic algorithm (MGA). The performance of these techniques is compared to the performance of a more conventional search technique, a simplex algorithm. Results indicate that the GAs are efficient, versatile, quite capable of improving the grinding process, and easily incorporated into the toolbox of today's process engineer.

Jan 1, 1993

By John F. Spisak

Versatile living organisms, historically exploited as functionaries in the food processing, pharmaceutical and chemical industries, have not been successful in achieving similar or significant acceptance within the minerals industry. The current biotechnical revolution coupled with its expanded understanding, dictate that a flagging minerals industry reconsider the use of biotechnology in metallurgical applications. Living resources, either singly, in commensal association or in complex communities, are capable of duplicating fully integrated and complex processing functions. Organisms can mine and extract metals, detoxify chemical effluents and synthetically produce compounds. They have been criticized as exhibiting poor kinetics, excessive energy consumption and environmental sensitivity. However, expanding knowledge reveals that these organisms are surprisingly adaptable, variable and extremely durable. Applied biotechnology in specific cases offers favorable economic returns, environmental benefits and aesthetic value. Selective implementation of living systems can offer opportunities for reduced labor, increased productivity and technological advance. Success will not come easily. Capital must be risked, controversial decisions made and new ground plowed. Traditional, specialist thinkers will of necessity give way to interdisciplinary expertise and unorthodox methodology if success is to be achieved. Those who vigorously persevere, however, are likely to be rewarded with a dynamic and profitable new role in a restructured minerals industry.

Jan 1, 1985

By Allan D. Fernie

Many long conveyors, 2 - 20 km plus, have been installed over the past 10 years. Conveyor belt life, depending on the conveyor length and material handled, will generally range from 10 - 15 years. To replace long conveyors splicing one or two rolls into a conveyor run on an intermittent basis can be prolonged in an operating system involving considerable downtime and scheduling problems. This paper presents some of the methods used to- date and highlights forward planning for such an event. Special belt handling equipment required and the execution of a belt change operation are described in detail. Wright Engineers Limited have worked in collaboration with Canada Conveyor to design and implement the methods described herein.

Jan 1, 1993

By E. M. J. A. Pallone, F. N. Cunha, W. S. Resende, R. M. Stoll, R. C. Bradt

Utilization of the magnesium aluminate spinel in refractor' applications is briefly reviewed. The synthesis of a magnesia aluminate spinet aggregate from natural raw materials is considered in terms of the crystal chemistry of the spinet structure and expected impurities. Principles for the formation of this spinet refractory aggregate from different natural raw materials are presented. The basic concepts were then applied to the reaction of a bauxitic clay with a natural magnesite. This combination of raw materials has the potential to produce a low-cost refractor' aggregate that is a composite of spinel and forsterite. Experimental results are reported to produce a spinel refractor.' aggregate containing a small amount of forsterite. It possesses low apparent porosity and high bulk density suitable for industrial refractor' applications, including steelmaking, aluminum and copper foundries and cement production.

Jan 1, 2002