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By J. A. Harle

Introduction When considering power in Alberta, there automatically come to mind ideas of either hydro or thermal generation, leaving in one's thought an uncertainty as to which one would propose. There is frequently an obvious source of power in some locations on our fastflowing rivers, the major possibilities being described in the report on Surface Water Supply and Water Power of Alberta issued by the Alberta Government in 1948, but it must be realised when reading that report that the sites so described will require extensive geological and other surveys before they can be exploited, and account must be taken also of the transmission distances involved in each instance. From a conservation point of view, where water power can be economically developed and power transmitted to the load centres, this should be done, and our thermal resources should be husbanded for our coming generations, especially if our water resources are falling owing to glacial shrinkage.

Jan 1, 1951

By L. M. Pidgeon

Introduction The production of magnesium by direct reduction of the oxide has far passed the experimental stage and was responsible for 30 per cent of the recent wartime production of 246,000 tons per annum. This paper describes the small-scale experiments which culminated in a number of the wartime plants. The paper traces the author's early experiments on various direct reduction reactions leading to his choice of the ferrosilicon reduction of dolomite and the realization that this reaction would proceed at a satisfactory rate at temperatures obtainable in metal apparatus. MgO has a standard heat of formation of 146,100 cal. and is therefore one of the most difficult oxides to reduce. However, if advantage is taken of the relative volatility of magnesium metal, thermally unfavourable reactions may be utilized. In reaction MgO + X = XO+ Mg . . . . . . . . . . . . . (1) the removal of Mg as a gas at high temperatures displaces the equilibrium to the right in the face of the unfavourable thermo-chemistry which is inevitable with any X other than calcium metal. If X is carbon, not only is the reaction highly endothermic, but CO is gaseous. A temperature of l,864°C. is required to produce a pressure of one atmosphere of Mg. Between l,900°C. and perhaps 400°C., the back reaction takes place readily and special shock cooling devices are required to recover magnesium from the gaseous mixture. This reaction does not lend itself to small-scale experiments and was not examined by the author. If, in reaction, carbon is replaced by a relatively pan-volatile metal, the oxide of which is also non-volatile and possesses a fairly high heat of formation, a reduction reaction is offered which is free from the difficulties associated with carbon. The typical case of silicon will serve as an example: 2MgO + Si = SiO2 + 2Mg (g) . . . . . . . . . . . . . . . . . . . . . . (2) At temperatures above l,000°C., a positive pressure of magnesium will exist over the system. Removal of the magnesium vapour will displace the reaction to the right in the face .of an unfavourable thermal balance. Since magnesium is the only volatile component at this temperature, it may be evolved and condensed, using attractively simple distillation technique.

Jan 1, 1946

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

By D. Brisebois, J. M. Fecteau, S. Poirier

"This paper focusses on new developments regarding thermal rock fragmentation applications. The technology consists of a strong burner powered by diesel fuel and air. The thermal reaction that is created allows for the enlargement of 125 mm to 450 mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and the Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining.Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project.This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests carried out since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed."

Jan 1, 2003

By X. Zhong

Thermal shock resistant properties of reaction sintered bauxite-based ß -Sialon bonded corundum have been investigated, and the results are compared with those of Al2O3 based counterpart. It is found they all have very good thermal shock resistance. Their residual strength ratios after one thermal shock cycle at ? T=1200°C and A T=1350°C are 61-73% and 53-65% respectively. TSR parameters are calculated based on thermal expansion, modulus of elasticity, and fracture toughness determined. The reasons for improved TSR of these composite materials are discussed.

Jan 1, 2004

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By E. Nurminen

Thermal transport properties of copper flash smelting flue dust have been investigated. Such values of the dust are needed to correctly model the process and to optimize its heat recovery performance. Dust accretions on heat recovery boiler walls may have a significant influence on the boilers heat transfer efficiency. Measurements of the thermal transport properties have been made for industrial flue dust and for pure sulphate components. The measurements have been conducted at temperatures up to 400 °C and the effect of porosity on these properties has also been investigated. The results indicate that the flue dust and the sulphate components are effective thermal insulators and the dust build-up on the boiler walls is likely to greatly decrease the heat transfer efficiency of the boiler.

Jan 1, 2007

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By A. R. Farkoosh, K. Korgiopoulos, McGill University, O. Rodop, L. A. Villegas Armenta

"New generation of Al-Mg-Si alloys with thermally stable dispersoids that prevent recrystallization and grain growth during hot deformation are currently used in automotive components requiring good formability. Alloy chemistry controls the phase formation especially age-hardening precipitates, dispersoids, and primary intermetallic which have pronounced effect on grain structure, strength and formability. In this work, thermodynamic calculations have been used to predict the effects of varying levels of Si (0.5-1.5wt%), Mg (0.5-1.5wt%) and Mn (0.1-2.5wt%) on phase selection. Thermodynamic calculations have been performed in equilibrium and non-equilibrium conditions via the FactSage™ software using the FTlite database. Selected compositions have been cast, heat treated, extruded and characterized through scanning electron microscopy with energy dispersive spectroscopy and electron channeling contrast imaging techniques. The calculations showed that at the hot deformation temperature of ~540 oC, exceeding certain Mg and Si levels would lead to retained *-Mg2Si intermetallics and Si particles at the grain boundaries in addition to a-Al-(Mn,Fe)-Si. It was found that retained *-Mg2Si phase which adversely affects formability can be avoided for Si+2Mg levels lower than 2.3wt%. FactSage calculations also showed that increasing Mn from 0.5wt% to 1wt% leads to an increase in the amount of dispersoids (from 1wt% to 2wt%) that can potentially slow down recrystallization and grain growth during hot deformation and improve formability. Calculations at room temperature also show that for an alloy with 0.7wt% Mg, excess Si beyond 0.7 wt% promotes the precipitation of Si clusters in the Al matrix that accelerate natural age-hardening. Results were confirmed by experimental investigation.INTRODUCTIONAluminum alloy 6082 (Al-Mg-Si) is used in the automotive industry because of its high strength, and good weldability (I. J. Polmear, 2006). The alloy is age-hardenable through the precipitation of ß-Mg2Si and its precursors, and the recrystallization is usually inhibited by Mn- and Cr-containing dispersoids formed through high temperature heat treatments (I. Polmear & Couper, 1988). However, it is known that minor changes in alloy chemistry (Mg/Si ratio) can have significant influences on the ductility and formability of these alloys by altering phase selection and the resultant microstructure (Gupta, Lloyd, & Court, 2001; McQueen & Celliers, 1997; Zajac, Hutchinson, Johansson, & Gullman, 1994). For automotive applications where wrought alloys (usually extrusions) are cold-formed to produce suspension components, the chemistry of the alloys and the extruded structure are of crucial importance as they determine the formability at room temperature (Asensio-Lozano, Suárez-Peña, & Vander Voort, 2014). In this study, thermodynamic calculations along with experimental investigations were carried out on the Al-Mg-Si system to understand their phase formation and precipitation hardening as a function of alloy composition."

Jan 1, 2016

By Xian Jian Guo, Lei Li, Hua Wang

Direct smelting of copper concentrate to blister copper has the advantages of energy saving and environmental protection. There has been a lot of effort invested in process development including test work and theoretic analysis in the past half century. However, the process has only been applied commercially to a few smelters that treat chalcocite types of copper concentrate. The main limitation to treating chalcopyrite types of copper concentrate is high copper content in smelting slag and low direct copper recovery. Thus intensive slag cleaning is needed. In this paper, the thermodynamic analysis was mainly carried out for the multiphase equilibrium of direct to blister copper smelting for both chalcopyrite and chalcocite concentrates. The practical problems in direct to blister copper smelting, which are mainly in copper content in slag, are clarified. The operational window of slag composition for different temperatures and oxygen partial pressure for the treatment of chalcocite type concentrates is identified. The process operation optimization for the blending of chalcocite, pyrite and chalcopyrite concentrates was done. INTRODUCTION The extractive metallurgy of copper can be divided into two broad groups of processes, namely, pyrometallurgy and hydrometallurgy, and the former is dominant. About 80% of copper in the world is produced by pyrometallurgy (Christopher et al., 2006). The first stage of conventional copper pyrometallurgy processing is to smelt copper concentrate to copper matte composed of FeS and Cu2S with slagging to remove a proportion of the iron (Gargul, Boryczko, & Bukowska, 2017). The smelting processes include bath and flash smelting. The second stage of the process is to convert copper matte to blister copper. In most cases, the copper matte is converted in Peirce Smith (P-S) converters, which are batch operations (Kubiszewski, 2015). The P-S converting can be divided into two periods, slagging and copper blowing. During slagging period, FeS in copper matte is oxidized to FeO, which reacts with silica flux forming slag. When the iron content in matte is less than 1%, copper begins to oxidize and reduce to form blister copper (Kucharski, Sak, Madej, Wędrychowicz, & Mróz, 2013).

Jan 1, 2019

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By S. R. Steinacker, H. Schnideritsch, J. Antrekowitsch

Primary copper industry flue dust plays an increasingly important role in the creation of matte and slag. From a thermodynamic point of view, the chemically formed section of fine particles play a techno-logically interesting role in comparison to the mechanical carry-over. Here, the volatilization and the sub-sequent condensation in the off gas system lead to a characteristic distribution of the contained elements which are represented by various compounds of desired metals like zinc and lead. On the contrary, certain undesired components such as arsenic, bismuth and cadmium accumulate within the product as well. This paper describes existing models and theories concerning the formation of flue dust in the copper smelting process and presents a thorough investigation of the physico-chemical fundamentals by verifying assump-tions with thermodynamic calculations. By fully understanding the formation patterns at different stages and temperatures within the process, better knowledge for flue dust in the first step of the pyrometallurgi-cal copper smelting can be obtained - hence leading to new ideas and incentives for the following stages in the copper production cycle.

Jan 1, 2015

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By R. C. Reed, L. T. Wu, H. C. Harada, K. Kawagish, R. T. Wu

Oxidation of pure metals is a chemical reaction in which the metal loses one or more electrons, such that the atom of the metal changes from the neutral state to a positively charge ion and reacts with oxygen to form an oxide of the metal. The oxide can form as a protective and adherent scale that slows down further oxidation, or may spall off repeatedly, exposing fresh metal surface to react with oxygen. In multi-component alloy systems such as typical high temperature NiCrAlY bond coats, more than one oxidation mechanism may take place at once and thus, complicates the study of oxidation. To better understand the competition between formations of oxides of different compositions, a thermodynamic assessment is carried out to study the oxidation mechanism of a Ni-27Cr-9Al (at %) ternary alloy. Based on the assessment, it is demonstrated that the layering of different oxides can be determined, with the most stable oxide (alumina) existing directly above the metal-oxide interface and the least stable oxide (nickel oxide) locating on the outer most layer. A comparison between the calculated results and previously published experimental observations shows excellent agreement.

Jan 1, 2010

By Y. -B. Kang

New databases are being developed to provide the capability to evaluate the suitability of present and potential new Mg alloys for automotive applications through cost-effective calculations. An extensive and complete thermodynamic database is being prepared for Mg alloys formed from among 25 present and potential alloying elements. The database is being developed by critical evaluation, modeling and optimization of available phase equilibrium and thermodynamic data. It contains model parameters giving the thermodynamic properties as functions of temperature and composition. Using the FactSage thermodynamic software, users can access the database to calculate the amounts and compositions of all phases at equilibrium at any temperature and composition or to calculate any phase diagram section in multicomponent alloys, to follow the course of equilibrium or non-equilibrium cooling, to calculate corresponding heat effects, etc. A database of densities and lattice parameters of Mg alloys and intermetallics (as functions of temperature and composition) is also being developed in order to permit the calculation of volume changes during cooling and phase transformations, c/a ratios of the hcp phase, etc.

Jan 1, 2006

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By I-H. Jung, J. Kim, B. Konar

"The usage of FeNdB permanent magnet, containing Rare earth elements (REEs), is steeply increasing with its demand for wind-turbine and electrical vehicle. The improvement and recycling of the permanent magnet require good understanding of chemistry of all constituent elements. In order to understand the chemical interactions between REEs and Fe, all Fe-RE binary systems have been critically assessed and optimized based on reliable literature data. The Modified Quasichemical Model and Compound energy formalism is employed to model the liquid phase and the solid solutions present in the binary systems respectively. The enthalpy of the liquid and the intermetallic phases showed a systematic trend along the lanthanide series. This helped to mitigate the discrepancies in literature data and also to predict the binary interactions between some less well investigated Fe-RE binary systems. INTRODUCTIONRare Earth elements (REEs) are a group of seventeen elements (including Scandium, Yttrium and the lanthanide series) that exhibit same characteristic chemical and physical properties. These properties make them valuable to the electronic, appliance, green technology, weapon and medical device manufacturing industries. Compounds of REE with other metals (like Co, Fe, Ni etc.) have unique properties of luminescence, thermal and electrical conductivity, magnetism and ability to act as catalysts and polishing compounds (Gschneidner ,2011).They are not only indispensable for some electronic gadgets of today, like computers, music systems, mobile devices, televisions and MRI machines, but also holds a key to more greener technology of the future. They contribute to the development of more efficient and environment friendly version of everyday products such as cars and light bulbs. REE compounds revolutionized the magnet industry by making them smaller and more powerful with increased longevity, and high temperature workability, which are used in motors and generators that power electronics, telecommunications, electric automobiles and turbines(Humphries, 2011)."

Jan 1, 2012

By M. Mezbahul-Islam

Thermodynamic modeling of the Mg-Cu-Ni system is carried out as a part of multi component thermodynamic database for Mg alloys. This system is being modeled for the first time using the modified quasichemical model, which considers the presence of short range ordering in the liquid. The thermodynamic descriptions of the binaries Mg-Cu, Cu-Ni and Mg-Ni have been extrapolated to the ternary Mg-Cu-Ni system using Toop geometric model. The constructed database has been used to calculate and predict thermodynamic properties, isothermal sections and liquidus projections of the Mg¬Cu-Ni system, which showed very good consistency with the experimental data.

Jan 1, 2011