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By M Reza Afshar

In this work a mathematical model was developed to study the effect of electromagnetic force on the magnesium melt containing nonmetallic inclusion in an electrical isolated channel. The electromagnetic force exerted on the inclusion induced by DC current field was calculated. A three dimensional turbulent flow equations were solved numerically to compute the velocity field within the channel. On the basis of computed velocity and magnetic fields, the trajectories of inclusions were calculated using the equations of motion for inclusions. Parametric studies were carried out to evaluate the effect of various parameters such as current density, channel diameter and particle density on the removal efficiency of inclusions from magnesium melts.

Jan 1, 2004

By E. Ferguson

In evaluating refractory designs for cast house applications, thermal calculations are frequently performed to determine cold face shell temperatures, temperature profiles and metal freeze plane locations within the refractory layer, and heat loss in the steady state condition. A problem arises when looking at molten metal transport crucible designs in that these structures are usually operating under non-steady state conditions throughout their production cycle. Because the molten metal temperature varies with time, and material properties such as thermal conductivity are temperature dependant, mathematical solutions are at best... complicated. This paper presents a relatively simple, iterative solution, that can be set up on a standard computer spreadsheet program, to calculate heat transfer in non-steady state conditions. These calculations can provide curves for (1) molten metal temperature vs time and (2) cumulative heat loss vs time, given variable starting conditions, to aid in the evaluation of molten metal transfer crucible refractory designs.

Jan 1, 2004

By J. R. Perumareddi, V. S. Sastri, M. Elboujdaini

Economics of corrosion, the corrosion modes and causes, corrosion control methods to combat corrosion, along with a summary of issues and their implementation in the aerospace industry are briefly discussed.

Jan 1, 2004

By Raj Thamburaj, Li. Ping, Prakash C. Patnaik

"An effective prognosis system for aircraft engines may involve the application of a wide range of technologies and methodologies, which may include: - On-line, real-time and in-situ non-destructive inspection/detection/sensoring - Aircraft/engine instrumentation - Airborne data recording system - Advanced signal filtration - Data compression technologies - On-line engine health monitoring technologies - On-line engine component life usage monitoring technologies - Mission severity analysis algorithm based on life prediction and damage tolerance analysis models - Life assessment methodologies - Optimized repair/overhaul/maintenance planning - Optimization of mission assignment and homogeneous life usage - Web-enabled information delivery and sharing system - Decision making logistics This paper will demonstrate some efforts that Orenda has accomplished over the last decade in collaboration with the Institute for Aerospace Research of National Research Council Canada and the Department of National Defense. The presentation will focus on the following projects:"

Jan 1, 2004

By P. A. Hacquebard, M. P. Avery

"Gondwana coal deposits are widespread and are known to occur in four continents. They are present in Brazil, India, South Africa, and Australia. From coal petrographic examinations and a detailed literature survey, it is interpreted that Gondwana coals are present also in Canada and the United States. Laurasia, or Northern Hemisphere, coals occur in the United States, Canada, and Europe. They form the main coal producing fields of the world. Megascopically, Gondwana coals have a uniform, micro-banded appearance, with a dull lustre; Laurasian coals are bright and have distinct bands of vitrain and clarain. Petrographically, Gondwana coals, compared to Laurasian coals, are lower in vitrinite, but higher in inertinite, particularly in semifusinite. Mineral matter averages 16% in Gondwana coals and 5.7% in Northern Hemisphere coals.Gondwana coals are characterized by thick seams that terminate through lithification (Versteinerung), whereby coal passes laterally into shale. Laurasian coal seams are thinner and terminate by splitting and digitation.Vitrinite/inertinite ratio data indicate deposition of the Gondwana coals in dry marshes under strong oxidizing conditions. The Laurasian coals originated in wet marshes in a reducing environment. As deduced from fossil plants and fossil spores, temperate and near arctic conditions apply for the Gondwana coals. A tropical and subtropical climate is indicated for the Laurasian deposits. The Gondwana coals were formed under allochthonous conditions. They derived from vegetation that drifted into the peat bogs. The Laurasian coals are autochthonous and originated from vegetation that grew and was buried in the peat bogs. The Gondwana coals are Late Carboniferous and Early Permian. The Laurasian coals are entirely Late Carboniferous."

Jan 1, 2004

By S. -H. Sohn, M. -K. Cho, G. -G. Hong

In order to evaluate the properties of coating materials for BOF, the effects of dolomites (dolomite and light burned dolomite) addition on durability of coating materials were investigated. In all coating materials, matrix was dicalcium ferrite(C2F) and both free MgO and dicalcium silicate(C2S) were precipitated. Fe203 content must be controlled to improve the adhesion and durability of coating materials for BOF during oxygen blowing process. The amount of dolomites added to BOF slag must be controlled in optimum condition with high refractoriness of C2S to improve the adhesion of coating materials for BOF. The weight ratio of converter slag to dolomite must be below 8 to improve the adhesion and durability of coating materials simultaneously.

Jan 1, 2004

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By B. Zhu, W. E. Lee, N. Li

Al powder is used extensively as an antioxidant in carbon-containing bricks, but it cannot be used directly in water-based carbon-containing castables due to its hydration tendency. To overcome this problem, in this work, SiO2-PVA (polyvinyl alcohol) inorganic-organic hybrid coatings have been prepared via sol-gel processing, and used to coat Al powder. The hydration behaviour of uncoated and coated Al powders has been investigated in water at 60 or 100°C for 36h by examining phase and microstructural changes. While significant hydration is detected in uncoated Al powder, no obvious hydration is detected in coated Al powder, indicating that its hydration resistance has been greatly improved. Oxidation resistance of graphite coexisting with uncoated or coated Al powder was also investigated in air at 1250°C for 1.5h. The oxidation ratio of graphite coexisting with coated Al powder was similar to that of graphite coexisting with uncoated Al powder, indicating that both powders showed similar antioxidising behaviour. This, along with the much improved hydration resistance, makes the coated Al powder a potential antioxidant in carbon-containing castables systems.

Jan 1, 2004

By Y. G. Yaroshenko, V. Y. Baldin, Y. M. Gordon

The manufacture of sulphuric acid from the off-gas of pyrometallurgical processes in the production of heavy metals is one of the common methods of effective recycling of sulfuric anhydrite. The new Impact-Inertial Devices with the rectangular contact channels (IIRCh) and the internal circulation of liquid allow the injection of an absorber into the phase's interactive cell by utilizing the gas stream energy and by this way increasing the sulphuric acid yield and reducing the power consumption. These devices have the following advantages: simplicity of design, smaller size, low capital expenses, absence of irrigating system, high operational reliability, simultaneous cleaning of solid, gaseous and liquid impurities and also cooling of gases etc. The IIRCh efficiency is almost 18 % higher and they require 1.3-2 times lower energy when compared with Venturi Absorbers. Also the elevation of spraying nozzles or injectors is 1.5 times lower in the IIRCh case.

Jan 1, 2004

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

Competition between stress generation and relaxation mechanisms during the oxidation process has been observed. However, the nature of the intrinsic growth stress in thermally grown scales is not well understood. In this talk, we will propose a conceptual model to calculate the intrinsic growth stress based on the analysis of stress-driven diffusional process of oxygen ions along the oxide grain boundary. The calculated stress, which is considered to originate from the constrained lateral expansion of the oxide, is in agreement with a range of experimental observations.

Jan 1, 2004

By D. Getzlaf

"Oilfield cementing has been utilized in the industry since the turn of the century. Originally, wells were shallow and criteria for well integrity were somewhat limited. Since that time, wells have stretched the envelope in depth, temperature, and pressure. Environmental regulations have also become more stringent, thus, the importance of hydraulic isolation between permeable zones, and between these zones and surface has become more and more important.Initially, oilfield cements were comprised predominantly of construction cement and very limited additives. As time progressed, additives were incorporated to control pumping time or placement time and little effort was placed on optimizing actual components within the cement chemistry. This paper presents issues and concerns created by adding just one new component to the fundamental chemistry of an oilfield cement."

Jan 1, 2004

By Jean Vavrek, Rob Barber

"What is CIM’s role on a planet-wide scale?That question has been coming back to the forefront of many discussions regularly in the months since we came on board as Executive Director and Vice- President International. CIM, by its name and by the nature of its history and make up, has mainly been a Canadian entity. It has been created by an act of Canadian Parliament and it is set up to work within the Canadian federal and provincial framework.Yet the name CIM is one well known and recognized for quality and professionalism worldwide. One could say that CIM has established a level of brand recognition that transcends it name and its origin. CIM has also evolved with the times, as the world has evolved and more so as the world of mining has evolved. So we stand today with a fairly large portion of our membership residing outside Canada and outside the United States. We also stand today looking back at the role CIM has played in events that we have been partners in organizing outside Canada; and for a long time CIM has provided insights into what is going on in the rest of the mining world by inviting authors and by featuring topics from around the globe.Today, Canada is still a leader in the mining industry. Canadian mining companies are involved in exploration and operations around the world. Canadian operations serve a good portion of the global demand of many metals and minerals, recently adding diamonds to the slate. Canadian expertise in various areas also makes Canada a good base for exporting a wide range of products and services around the world."

Jan 1, 2004

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By G. Ozbayoglu, Z. Ozdemir

Turkey is the main boron minerals producing country in the world. The most important boron minerals are tincal, colemanite and ulexite. All mining, beneficiation and handling operations generate fines which cause ecological and economical problems. Utilization of this accumulated material requires both upgrading and agglomeration. The aim of this research was to exploit the ulexite fines by improving their grade and size. Attrition-scrubbing followed by washing and screening was employed for upgrading the fines. It was found that the grade can be increased from 23-25% B2O3 to 29% B2O3 with 73% recovery. Briquetting was applied as the size enlargement process. During the briquetting, the effect of moisture content, pressure, amount and type of binder, and drying on the quality of briquettes were investigated. The tests showed the possibility of production of strong briquettes by adding water alone, but the briquettes had no resistance to abrasion and water. Binders, namely boric acid and borax have been added to improve the properties of briquettes. The results showed that the compressive strengths and abrasive resistances of briquettes obtained with both binders were acceptable. However, the briquettes have no water resistance properties.

Jan 1, 2004

By R. V. Kumar, F. Tailoka

In order to use ZnO laden dust as a possible desulphurization reagent, it is important to evaluate thermodynamics of the Zn-O-S system. At temperatures greater than 1450 K, there is an uncertainty in the thermodynamic data for the reaction of zinc with sulfur to form Zinc sulfide. In this work, the standard free energy has been determined using an electrochemical cell: Pt, Mo, MoO2/YSZ/ZnO, ZnS, S02, Pt., between 1198 and 1602 K. AG° varies from -145,880 to -88,100 J (± 2500) , with a phase change to ZnS (g) by sublimation occurring between 1450 and 1460 K. This is supported by thermogravimetric analysis which shows about 80% weight loss in ZnS from 1273 to 1473 K. Feasibility reactions were also performed and confirmed that ZnS (g) is formed when ZnO reacts with FeS (1473 to 1653 K) or with Fe-Csat-S(1473-1673 K). There is therefore potential for the utilization of ZnO laden waste as an additional or alternative reagent for desulfurisation.

Jan 1, 2004

By Jian Li, V. Y. Gertsman, David C. Katz, M. Elboujdaini

Analysis of stress corrosion cracking (SCC) usually involves high-end analytical tools including scanning electron microscope (SEM) and analytical transmission electron microscope (TEM). In recent years, focused ion beam microscope (FIB) has found many applications in materials science fields. In this study, high-resolution FIB images have shown details of crack morphology and a plan-view TEM specimen containing the selected crack-tip was successfully prepared. The preparation of cross-sectioned samples containing crack tips was of paramount importance for subsequent TEM analyses.

Jan 1, 2004

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which 'collected' unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004

By M. J. Hadianfard

The effect of holding at temperature on fatigue life of a 10 vol% particulate SiC reinforced Titanium alloy has been investigated. The influence of holding time at 600°C on fatigue of this material has been studied by using tension-compression tests, scanning electron microscope and image analysis. The specimens were heated to 600°C by using a controlled atmosphere furnace; hold at this temperature for time ranging from 0 to 100 hours, and then fatigue tested at room temperature under controlled constant plastic strain. The number of cycle to failure found to decrease with increasing of the holding time. In addition the fracture mechanism and number of debonded particles has been significantly influenced by holding time at 600°C.

Jan 1, 2004

By A. Cadieux, J. -B. Pineault, C. Allaire

The temperature measurement of the molten metal in the aluminum transformation process is of prime importance. This is particularly the case for aluminum treatment furnaces, such as holding and melting furnaces. Such reverberatory type of furnaces involve a thermal gradient across the metal line which limits the life of conventional thermocouple protective ceramic shields, due to the action of locally induced thermal stresses. This paper presents a novel thermocouple assembly using a composite refractory protective shield allowing long term resistance to such above conditions. Example of results obtained from various tests in aluminum holding furnaces are presented. The results confirm the superiority of the novel thermocouple assembly, as compared to conventional thermocouple units.

Jan 1, 2004

By A. Lopez-Valdivieso

Particle size enlargement processes play an important role in solid/liquid separation, and in beneficiation unit operations. In the latter, not only the size of the formed aggregates but also their surface properties are very important. Oil agglomeration has a special place among such processes: it is a selective process in which hydrophobic particles are agglomerated into hydrophobic agglomerates which can be recovered by flotation. This explains the broad applications of oil-assisted beneficiation processes not only in the beneficiation of fine coal, but also in agglomerate flotation of many different types of ores, and in coal/gold agglomeration.

Jan 1, 2004