Search Documents

By T. Yue, Z. Gao, X. Tong, R. Liu

"Lead ions (lead nitrate) were introduced to modify the surface properties of scheelite, effectively and selectively improving the flotability of scheelite, with benzohydroxamic acid (BHA) serving as the collector. A series of experiments about the mode of addition and the ratio of lead ion to BHA were conducted and indicated Pb-BHA complexes were the active species responsible for the flotation. And two adsorption models of BHA on the surface of scheelite were established. For both the two adding methods, some kind of complexes formed by lead ions and BHA played a key role in the flotation process. Zeta potential, FTIR, and XPS studies indicated that the adsorption amount and intensity of BHA on the surface of scheetlie were larger by adding the reagents as a mixture. The mixed addition is conducive to form Pb-BHA complexes and improve the adsorption efficiency of BHA on the surface of scheelite, as well as the recovery of scheelite. INTRODUCTION Scheelite, as an important tungsten-bearing mineral, is nowadays utilized mainly by flotation (YIN and WANG, 2014; Sun et al., 2011; Gao et al., 2015; Gao et al., 2015). Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physico-chemical characteristics such as solubility, hardness, specific gravity, point of zero charge (PZC), etc. (Arnold and Warren, 1974; Deng et al., 2016; Deng et al., 2015; Ozcan and Bulutcu, 1993a; Yongxin and Changgen, 1983). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives (Bo et al., 2015; Oliveira and Sampaio, 1988; Shi et al., 2014; Sivamohan, 1988; Yongxin and Changgen, 1983). It is difficult to separate scheelite, especially from calcite, with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan and Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is inadequate for a low-grade calcitic scheelite ore. Unfortunately, reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Bo et al., 2015; Schubert et al., 1990; Shi et al., 2014; Yongxin and Changgen, 1983), used for calcite depression also depress scheelite to a large extent. Cationic collectors, such as amine and quarternary ammonium (Yang et al., 2015) and collector mixture (Gao et al., 2015) have been used to improve the scheelite flotation. However they have not been applied in industry due to the poor separation from silicate minerals."

Jan 1, 2017

By M. G. Bakker, D. D. Murphy, D. R. Spears

The US Bureau of Mines studied the mechanism of shear flocculation of silica with stearic acid. At pH 6 and 12, shear flocculation of silica was not observed with the addition of up to 4.5 x 10-4 M (5 lb/st) stearic acid. However, in the presence of 0.1 M NaCl at pH 6, shear-flocculation was observed at stearic acid concentrations = 10-4 M (22.5 lb/st). Adsorption of stearic acid on silica was studied using stearic acids spin-labeled with a doxyl group. The presence of the spin-labeling group did not greatly affect the shear flocculation properties of stearic acid. Adsorption of labeled stearic acid on silica was measured as a function of surfactant concentration with electron paramagnetic resonance (EPR) spectroscopy and gas chromatography (GC). The GC results indicated that the stearic acid was predominately adsorbed on the surface at concentrations above 10-4 M. From the EPR spectra, the formation of aggregates of stearic acid was apparent at concentrations of approximately 10-5 M (22.5 lb/st). The results are discussed in terms of a possible mechanism for shear flocculation.

Jan 1, 1995

By D. D. Murphy

The Bureau of Mines has studied the mechanism of shear-flocculation of silica with stearic acid. At pH 6 and 12, shear-flocculation of silica was not observed with up to 10-4M (5 lb/st) stearic acid. However, in the presence of 0.1 M NaCl at pH 6, shear-flocculation was observed at stearic acid concentrations 10-4 M (5 lb/st). Adsorption of stearic acid on silica was studied using stearic acids spin-labelled with a doxyl group. The presence of the spin-labelling group did not greatly affect the shear-flocculation properties of stearic acid. Adsorption of labelled stearic acid on silica was measured as a function of surfactant concentration with electron paramagnetic resonance (EPR) spectroscopy and gas chromatography (GC). The GC results indicate the stearic acid was predominately adsorbed on the surface at concentrations above 10-4 M. From the EPR spectra, the formation of aggregates of stearic acid was apparent at concentrations of approximately 10-414 (5 lb/st). The results are discussed in terms of a possible mechanism for shear-flocculation.

Jan 1, 1993

By F. Dehghani, M. Kebe, H. Askari-Sabzkoohi, T. Ghosh

The depletion of bauxite reserves around the world has necessitated the search for viable alternative sources of aluminum. The major non-bauxite source of aluminum is alunite [KAl3 (SO4)2(OH)6]. Lixiviation is the common industrial process to recover aluminum from alunite. Due to the presence of quartz (40%) as the main gangue mineral, this process causes the formation of Sodium aluminosilicate and Potassium aluminosilicate complexes that leads to loss of alunite, and chemical reagents. Thus, pre-concentration of alunite is required to remove the gangue minerals. Because of the low degrees of freedom (DOF) of alunite, froth flotation, as a preconcentration method, is a viable alternative to increase selectivity in downstream processes. In this work, the possibility of Alunite preconcentration with micro flotation and mechanical flotation cells was studied. The influence of type and dosage of collector, pH, solid percent, particles sizes were considered on the flotation. Flotation tests were designed based on Taguchi method, followed by performing based on surface charge differential between alunite and quartz on direct and revers flotation. In the reverse flotation, Ca+ 2 and Ba+ 2 were used to activate the quartz surface. Under optimum conditions of reverse flotation, alunite grade and recovery were 40% and 62.1% respectively. In the direct flotation, the surface of alunite was activated by F- . The grade and recovery were 50 and 89%, respectively.

Mar 2, 2022

By Yoshinori Iwasaki, Shosei Serata, Yutaka Mochida

A new comprehensive insitu instrumentation technique named this RCC Method has been developed for rapid assessment and improvement of the structural stability of underground openings. When applied to tunnel construction, the degree of present and prospective safety of underground openings can be determined in quantitative terms within 10 to 20 minutes of microcreep observation. When applied to mining, roofs and floors can be stabilized by controlling the stress conditions. This stress control method has eliminated the need for intensive roof bolting and extensive floor renewal in all cases where it was applied. Use of this technique is illustrated by field examples from the Seikan Undersea Tunnel of Japan and deep potash mining in Canada. NEW INSTRUMENTATION TECHNIQUE: THE RCC METHOD Failure problems in underground excavation usually arise in weak non-elastic grounds where conventional rock mechanics theories of elasticity are not only useless but also misleading. Presently, discontinuity planes in the ground are being considered a factor in assessing these failure problems, and while this development is interesting academically, it is not of much use in actual excavation work, where it is nearly impossible to identify and quantize all existing planes of discontinuity. Even if such an extraordinary task could be accomplished at an underground excavation site, effective use of the data would be difficult and impractical for rapid excavation work, with the possible exception of rare cases of ideally elastic ground.

Jan 1, 1976

By A. J. S. Spearing, B. Forbes, T. Kostecki, A. Hyett

Improving upon the past understanding of the interaction between installed rock bolts, the immediate roof and sidewalls is vital for the implementation of sound support system design, as this has a direct impact on rock-related safety. This is the primary goal in rock-bolt-related research. The earliest research in this field concentrated on limited laboratory and in situ measurements accompanied by theoretical analyses, based on the Kirsch equations. This represented the initial insight into understanding relative ground movements and their impact on primary support. However, these studies were far from complete. More recently, major technological advances in computing power within the mining industry has changed the scope from theoretical analysis to computer simulation. Even with these advancements our understanding of rock bolts in situ and in the laboratory has not progressed, particularly concerning bending and shear. To measure the behavior of rock bolts, the widely accepted practice is to populate the bolts with an array of strain gauges. Historically, resistive foil strain gauges or long displacement sensors have been used. Additionally, all instrumented rock bolts have used only two diametrically opposed slots. Rock bolts instrumented with these methods have significant shortcomings, one of which is the inability to capture shear and bending. The shearing and bending of rock bolts are particularly common in tabular soft rock mining, such as coal mining. This paper discusses the use of three slotted rock bolts, cut diametrically 120º apart, and two new optical fiber technologies populated along the entire rock-bolt length.

Jan 1, 2015

By A. Newman, M. Goycoolea

"In this paper, we consider an underground production scheduling problem consisting of determining the proper time interval or intervals in which to complete each mining activity so as to maximize a mine’s discounted value while adhering to precedence, activity durations, and production and processing limits. We present two different integer programming formulations for modeling this optimization problem. Both formulations possess a resource-constrained project scheduling problem structure. The first formulation uses a fine time discretization and is better suited for tactical mine scheduling applications. The second formulation, which uses a coarser time discretization, is better suited for strategic scheduling applications. We illustrate the strengths and weaknesses of each formulation with examples.IntroductionProject scheduling is an important aspect of underground mine planning that consists of determining the start dates for a given set of activities so as to maximize the value of a project while adhering to operational and re-source-availability constraints. Important activities that require scheduling include development, drilling, stoping and other ore-extraction techniques, and backfilling. Precedence relation-ships impose an order in which activities can be carried out based on their location in the mine: for example, the activity a associated with development of an area must be completed before the activity a´ associated with extraction of that same area can begin. Re-sources include attributes of the mining operation, such as the amount of extraction and mill capacity available per time period, and are determined by capital and equipment availability and other factors. In this paper, for our set-ting, resource-availability constraints consider the amounts of material that can be extracted and sent to the mill — that is, processed — per time period."

Mar 1, 2017

By J. Szarkowski

"INTRODUCTION The Butte district of Montana is well-known as one of the biggest historic producers of copper in the world. It is also a classic example of a porphyry Cu-Mo system that has been overprinted by zoned, polymetallic (Cu-Zn-Pb-Ag) lode mineralization. After copper, silver was the next most important metal mined from Butte, with over 700 million ounces of total Ag production between 1880 and the present day. Although many papers have been written on the mineralogy of the early porphyry Cu-Mo mineralization and the high-grade Cu-rich lodes in the center of the district, relatively little information exists on the mineralogy of silver in Butte. The purpose of this paper is to summarize past and present silver production trends for the district, and to combine previously published work with new research to examine the mineralogy of silver in the Butte mining district. BUTTE HISTORIC SILVER PRODUCTION According to a recent USGS compilation1, Butte is one of the most Ag-rich porphyry deposits in the world, both in terms of average Ag grade (8.6 g/ton) and total production + reserves (Fig. 1). It is also the 2nd biggest Ag-producing mining district in the U.S. (after the Couer d’Alene district, Idaho). Annual silver and copper production data for the Butte district, compiled from various sources2,3,4, are summarized in Figure 2. Peak production of Ag and Cu was in 1917. While Ag production gradually declined in the ensuing decades, Cu production remained strong until the years leading up to the closure of the Berkeley Pit in 1982. In 1984, mining of the nearby Continental Pit resumed under a different operator, and continues to the present day. The Continental mine produced an average of 35,000 metric tons Cu and 575,000 oz Ag per year between 1984 and 20044. These figures do not take into account a period of mine closure in 2001-2003 due to an unexpected hike in utility prices. The long-term decline in Ag/Cu ratio of ore mined in Butte (Figure 3) is due to several factors, including: 1) changes in metal prices; 2) a downwards decrease in Ag/Cu ratio of most of the lodes with depth below surface; and 3) a shift in mining methods from selective underground mining of high-grade veins to open-pit mining of the bulk rock."

Jan 1, 2016

By W. H. Jay, F. Lawson, D. F. A. Koch

Ion exchange resins may in the future displace activated carbon in gold plants where cyanidation is practiced. Recently patented technology based on interpenetrated polyurethane polymers shows that these new materials offer significantly improved loading kinetics over both activated carbon and commercially available ion exchange resins. These polymers are not restricted either in particle size or in density and therefore offer the gold industry the potential for a further technological advancement.

Jan 1, 1995

By Peter Van deVelde

Many companies in North America because of economic or environmental reasons are considering reprocessing material from their waste ponds. The Japanese have developed highly specialized machines and techniques to reprocess industrial/mining wastes from settling ponds. This paper discusses the techniques and results of applying this technology to North American applications.

Jan 1, 1983

By I. Martinez-Dominguez

In September 1992, mining in Mexico was opened again to foreign investment by President Salinas-de Gortari, after thirty years of "Mexicanization" of mining industry which limited foreign participation up to a 49 % (or 34 % in case of national reserves) on a Mexican mining corporation. During said period mining in Mexico was controlled by four or five big mining companies and besides mining production was focused mainly on silver, lead, zinc, copper and fluorspar. Suddenly in middle of a big crisis on Mexican mining industry due to low prices of minerals in the world and also in a period on which it seems that mining industry in the United States and Canada has been condemned to die for environmental reasons, it appears a new Mexican Mining Law to permit foreigners to participate in mining in Mexico' trough Mexican mining corporations that they may control up to 100 %

Jan 1, 1994

By Michael Prince

"Managing slurry is a constant challenge for mining operations. Since slurries are not uniform, the challenge is complicated by varying rheology, velocity, temperature and pressure, all of which affect how the slurry moves through the pipeline and how destructive it is to the system it is flowing through. Picking the right equipment from the outset — the right size pipe, the right size pump and the proper valves for the application — allows mines to operate more efficiently. Better valve designs deliver multiple benefits — they can lower the cost of operations, reduce the amount of maintenance and associated downtime required and are better for the environment. Historically, modulating systems have used ball, plug and pinch valves to manage the flow of slurry, but each of these alternatives has limitations. Ball valves require ceramic lining in order to delay wear, and once a ball valve does wear, the entire valve must be replaced. Similarly, plugs in plug valves should be coated to perform in control systems, and whole valves must be swapped out upon wear. Pinch valves are expensive and only require replacement of the sleeve. However, sleeve replacement involves an extremely arduous process in which the valve is completely taken apart.Traditionally, designers have avoided using knife gate valves (KGV) in modulating systems because KGVs have not been able to hold up under the harsh operating conditions. The throttling that is required in some of these processes rapidly fatigues conventional KGVs, rendering them useless and in need of replacement. Fortunately, innovative design changes have the potential to change established views.Breaking new groundRecognizing the need for improved components, Victaulic took on the challenge of designing a valve that could withstand abrasive slurry systems for a much longer period of time. The first step in this process was to talk to miners, maintenance personnel, process engineers and operators in the field about the limitations of current offerings and then determine design specifications for an ideal replacement.Many of the responses to these inquiries were very similar and reflected challenges with current operations; the primary objective was to find a valve that would be lighter and cheaper than the valves currently in use. In theory, a lighter valve would be easier to replace, and since replacements need to be performed frequently, a cheaper valve seemed like the right idea."

Feb 1, 2019

By C. V. Deutsch, O. Babak

A longstanding problem in geostatistics is that kriging usually assigns significantly greater weights to end samples in strings of data than it does to central samples. These weights are theoretically valid, but suboptimal estimates may result when there are geological trends in the variable near contacts, that is, large weights may be applied to samples that are systematically lower or higher than average. A number of ad-hoc corrections exist, each with pros and cons; none are fully automatic with a well-defined measure of optimality. A new method for estimation in a finite domain is proposed. This method is referred to as finite domain kriging. The method is based on kriging with a successively larger number of data. The total number of relevant data (n) is established, and then n kriging matrices are solved. The first matrix has the closest single data value (n-1 weights are set to zero); the second has the two closest data (n-2 weights are set to zero) and so on. The final matrix has all n data. The kriging weights used for estimation are the average of the weights from the n successive kriging runs. Each kriging run is optimal, yet with different smoothing and a different treatment of data at the end of the strings. The result is a set of weights that does not give undue influence to data values at the end of strings. The methodology is developed with examples. Cross validation shows that finite domain kriging outperforms conventional kriging.

Jan 1, 2009

By H. Staton, N. Michaelson

"INTRODUCTION Lundin Mining’s Eagle Operation, located in Marquette County, upper Michigan consists of a mine and concentrator that process a Ni-Cu-(PGE) ore. The mine itself is an underground operation and the ore is trucked from the Eagle mine site 66 miles to the Humboldt mill where both nickel and copper concentrates are produced. Operations began in 2014 and continued with an average production of approximately 23,000 tonnes of Ni and 20,000 tonnes of Cu per year for the first three years of operation. The Humboldt Mill, currently operated by Lundin Mining, processes the nickel/copper ore from Eagle Mine and performs the concentration through several stages of flotation. Originally built in 1954, the Humboldt Mill began operations as an Iron Ore processing facility, and was converted to a gold processing plant during the 1980s. Various groups owned the site after closure of the gold operation. Eagle purchased the Mill in 2008 and invested more than $280 million to clean up historic mine waste and refurbish the plant (see flowsheet in APPENDIX). This paper will overview the ramp-up of the operation, and discuss some specific areas that went well and some that could have gone better during the design phase. HIGH LEVEL DESIGN CRITERIA Coarse ore arrives from the mine and is stored in a building with a capacity of 10,000 tonnes. Ore is crushed in three stages to a final product size of 100% Passing 12mm. Crushed ore is conveyed to the mass flow fine ore bins, which have a live capacity of 3000 tonnes. Crushed ore is fed to two parallel 900 HP ball mills, charged with 3” high chrome grinding media, and ground, in closed circuit with hydrocyclones, to a p80 of 110 microns in the flotation feed. Soda ash is added to the mills based on process water hardness. Cyclone overflow passes to the bulk conditioner where Sodium Isopropyl Xanthate (SIPX) and Methyl Isobutyl Carbinol (MIBC) are added. The slurry is pumped to the rougher bank for bulk flotation. Rougher concentrate is fed to a 500HP vertically stirred regrind mill and is ground to a p80 of 50 microns, using 5/8” high chrome balls. Rougher tailings report to the tailings thickener. The regrind cyclone overflow is sent to the single stage cleaner bank followed by two scavenger banks. The cleaner concentrate is pumped to the copper-nickel separation circuit. Cleaner tailings report to the tailings thickener. In the copper-nickel separation circuit, the pH is raised to 11.5 and a copper concentrate is recovered from the bulk cleaner concentrate in two stages, namely the copper roughers and the copper cleaner columns. The concentrate from the copper flotation columns is the final copper concentrate. The tailings from the columns return to the head of the copper-nickel separation. The nickel concentrate is the copper rougher tailings stream."

Jan 1, 2018

By Jeff Easton, J Johnson, D. Foot

The Mina Santa Rosa mine in Panama was the victim of a mine closure 24 years ago that left the community in dire straits. The mine showed the potential resources of greater than 1M ounces of gold and 4.5M ounces of silver. Veragold Mining Company decided to reopen the mine and address all the issues that were involved in the startup of an historic mine. This paper provides methods to restore the community trust, provide a transparent process, and develop an environmentally sound flowsheet. Immense scrutiny surrounded the Tailings Storage Facility, and the company developed a plan focused on paste thickening and surface stacking to eliminate the need for a conventional tailings’ facility. Paste thickener principles and benefits are also provided.

Feb 1, 2024

By H. R. Coles

Test work conducted in the 6.4 and 10.52 m Aerofall Mills at the Iron Ore Company of Canada Carol Project showed that the conventionally used ?deflector?-type liners which form the basic principle of Aerofall Mill grinding did not necessarily provide the best grinding performance. A new design, using low profile liners incorporating radial ribs of a proper height, actually improved the mill throughput in the order of 9 to 20% without sacrificing grinding efficiency. In addition, the new design reduced liner weight and scrap losses, which resulted in a reduction of liner consumption by 25%. It provided better protection to the mill shell and reduced the overall maintenance cost for the mill

Jan 1, 1980

By Im C. J.

The addition of coal preparation plants changed the coal industry during the past. Now it is time co once again improve the quality and types of coal products coming from future coal preparation plants to meet the changing needs of our society. Clean Coal Technology, along with federal support provided, is forcing our industry to provide cleaner coal products for industrial applications. Liquid fuels from coal is just one of many new products from a coal preparation plant that has a ready market in the transportation sector. UCC Research Corporation is developing these new liquid coal products and this paper will describe the progress and the new slate of coal products to be provided from future preparation plants.

Jan 1, 1989

"Caterpillar has developed the Cat GH800B longwall plow system, designed for mining very low coal seams at high rates. Building on the attributes of the proven GH1600 plow system, the Caterpillar longwall team in Lünen, Germany, worked with the German Ibbenbüren Mine to design and construct a system for mining an anthracite seam averaging only 0.85 m (33.5 in.) thick. The result is the GH800B plow and associated longwall system, which is now operating in the Ibbenbüren Mine - where the seam does not exceed 1 m (39 in.) in height.The Cat GH800 plow, with an installed power of 2 x 400 kW, has been the plow of choice for seam heights from 0.9 to 2 m (35 to 78 in.), regardless of seam inclination or coal hardness. But the lower the coal seam, the more difficult the extraction process. Flexibility, reliability, efficiency and serviceability of the whole system had to be refined for maximum productivity in such a minimal height, but several key modifications led to success.The armored face conveyor (AFC) modifications for the GH800B plow system include PF4 plow line pans with a replaceable top trough and a new plow guide made of a one-piece casting to provide extra strength and durability while being lower in height than the previous welded version. External dogbone connectors between the line pans and a strong and flexible relay bar between the AFC and the roof supports (shields) further adapt the conveyor for very low seam operation. To increase coal throughput, the engineering team widened the conveyor crosssection with extended side plates."

Jan 1, 2014

By E. M. Spokes

Starting in 1980, a committee of the National Research Council studied the question of why some underground coal mines are safer than others and what could be done to improve the ones with poorer performance. The results indicated that safety is improved by management commitment to safety, by cooperation between labor and management on safety matters, and by quality training of employees and managers. Younger miners have higher accident frequencies, but are less likely to be killed or permanently disabled by a lost-time accident. Methods for improving safety performance are proposed.

Jan 1, 1987

By E. M. - Technical Papers Spokes

A.B. Rushton The work and resulting publications of the Committee on Underground Coal Mine Safety and The President's Commission on Coal were appropriate at the time of publication. The statistics cited in the publications appeared to be valid, and the actions proposed by the committee had merit. Although the actions proposed to achieve further improvements in safety may have been worthy of repeating, to associate statistics (Table 1) that are seven to eight years old with company names is bad. Statistics are readily available from the Mine Safety and Health Administration (MSHA) and are usually within three months of being up to date. A review of the most recent Coal Controlling Co. Report will reveal significant changes in the rankings. The more recent statistics should have been cited, or at least compared with those used in the article. Westmoreland Coal Co. is listed as having a 21.1 disabling injury rate for the period (1/78-12/80). The disabling injury rate for the Company for the year ending 1985 was 7.4 for the underground mines and 6.25 for the total facilities. Through March 1986, the dis- abling rate for the underground mines was 2.86. The management and employees of Westmoreland Coal Co. are committed to safety. The improvements achieved over the past five years attest to that commitment. We are justifiably proud of the achievement and dislike being misrepresented as in the April 1986 article Reply by E.M. Spokes I regret that the lapse of time since the original work gives a picture of safety practice that is no longer true today. That Westmoreland has reduced its disabling injury rate by 65% to 7.4 in 1985 is most commendable, and I congratulate you for this accomplishment. It is typical of the progress sought by the National Academy of Science and National Research Council when they funded the original study and published "Toward Safer Underground Coal Mines" in 1982. If a significant number of companies do as well as Westmoreland, the report will have served its purpose. Since the paper was primarily a condensation of the original report, it would not have been appropriate to seek access to later statistics. The purpose in seeking its publication at the time of presentation was to reach those who might have missed the original report. The fact that publication was delayed has not voided that purpose and may have reminded some who were aware of the original that its recommendations still apply to improvement of underground coal mine safety

Jan 1, 1987