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By Mark Godfrey, Wickus Slabbert, Debra Miller, Dave Dew

Sao Bento Mlnerai;;ao Mine (SBM), located 100 kms northwest of Belo Horlzante, Brazil, was commissioned In 1987t1l to produce 185 kg per month of gold from 240 tpd of refractory sulphide flotation concentrate. The concentrate Is processed by a Sherrill Gordon design pressure oxidation circuit followed by conventional CIL gold recovery process (Flgur .. J). The original plant design foresaw expansion to 480 tpd, and In this regard the acidic effluent neutralisation, CIL and carbon circuits were designed for future expansion to treat the higher tonnage. The pressure oxidation section was sized for 240 tpd with the Intention to double the Installed plant equipment to provide 480 tpd capacity when required. This decision was based In part on the novelty of pressure oxidation to treat refractory sulphide concentrates in 1984 when the process design was finalised. General Mining, Metals & Minerals (Pty) Ltd (GENMIN), has been actively Involved for the past 30 years in the development of bacterial process for the oxidation of refractory gold concentrates; the results of this development program have provided the registered process BIOx®. The successful Implementation of BIOx® technology for treatment of refractory gold concentrates at GENMIN's Fairview Mine In October 1986t2l, as well as the substantial experience accumulated in laboratory and pilot testing of some 40 other sulphide concentrates, Justified reconsideration of the oxidation process best suited to provide the Incremental sulphide oxidation capacity planned for SBM.

Jan 1, 1992

By Brian D. Smith, Batric Pesic

Typical sulfide gold bearing ores are refractory to standard cyanidation practice. This type of ore always needs some form of oxidative pretreatment to destroy the original host mineral matrix to make the cyanidation possible. The oxidative pretreatment can be achieved by roasting, autoclave leaching, bioleaching, or some other chemical method. Today, the most common practice of ore oxidation is either roasting or pressure leaching. The other methods are still considered developmental.

Jan 1, 1992

By Jean Paul Duterque, Morris J. V. Beattie

In many parts of the world, pyrite and arsenopyrite occur together in sulphide ores either as the only sulphide minerals or in conjunction with other valuable sulphides. It is desirable to produce separate concentrates of the various sulphide minerals, including pyrite and arsenopyrite, so that the contained desirable metals can be recovered economically. It is common, for instance, for gold in an ore containing both pyrite and arsenopyrite to be associated almost exclusively with the arsenopyrite. It is desirable in this instance to produce an arsenopyrite concentrate for gold recovery while rejecting the barren pyrite.

Jan 1, 1992

By James T. Furey, Laurence D. Hartzog, Graham A. Karklin

A pilot plant study was conducted to evaluate the performance of column flotation in the recovery of gold from the gold/tellurides bearing sulphide ore of the Kensington deposit (Echo Bay Mines and Coeur d'Alene Mines), and to compare the performance of column flotation to conventional "mechanically agitated" flotation, Tests were conducted in a 150 mm diameter, 60 liter glass column with ground flotation feed split from a concurrently operating conventional pilot plant, thus permitting direct comparison between the two processes. During the test program, the effects of wash water rate, gas holdup, froth depth, residence time and flow bias were examined in detail. The bulk metallurgical ore sample had an average "as tested" feed grade of about 5 git gold and 1 % sulphur, with the gold occurring primarily as inclusions of montbrayite (Au2Te3) in pyrite, with minor amounts of native gold. Conventional flotation using 60 minutes residence time across four roughing stages recovered about 97% of the gold into concentrates grading about 50 g/t Au. A single stage of column flotation roughing using 25 minutes residence time matched the conventional circuit recovery of97%, but produced grades of +150 git Au.

Jan 1, 1992

By Malcolm Wills

Hedges Gold Pty. Ltd. mines and processes a lateritic gold orebody approximately 120 km south east of Perth in the Darling plateau. The operation is approximately 26 km from the town of Boddington and 31 km from the town of Dwellingup. Hedges operates under The Western Australian Environmental Protection Act, Licence Number 3183. Presently, nine Limitations and Conditions are applicable to the tailings dam. These conditions apply to maximum discharge/disposal quantity permitted. Hedges mine is located in state Forest within the eastern, low rainfall section of the Darling Range and within the waler catchment area of the Murray River. Ore is carted by 120 tonne haulpacks to the plant. The plant and tailings dam is on private farm land some six kms from the mine.

Jan 1, 1992

By William M. Schafer

Mining projects which contain sulfide mineralization face increasing regulatory hurdles due to environmental concerns over acid rock drainage (ARD) and the ability of long-term reclamation to protect water quality. Among regulatory agencies, much of the perception about sulfide projects has been based on conditions at historic mining sites at which little or no effort was made to control ARD. With proper design measures, ARD production can be greatly reduced or eliminated. The science of ARD prediction and control must be expanded to enable mine planners to anticipate the effect of various facility design options on ARD potential. Some common-sense examples of geochemical prediction techniques and mitigation measures for waste rock dumps, spent ore heaps, and mine pits are described.

Jan 1, 1992

By P. R. Altringer, R. H. Lien, B. E. Dinsdale

The Bureau of Mines, U.S. Department of the Interior, is investigating biodegradation of cyanide as a means of decommissioning heap leach operations. Biological oxidation decreased weak acid dissociable (WAD) cyanide in process solutions from 50 to 170 ppm down to 0.1 ppm. The tests were conducted both in trickling column reactors, using quartz as the growth surface, and in upflow columns, using activated carbon as the growth surface. In addition, exploratory tests indicated that bacteria will destroy residual cyanide in leached ore. A flowsheet has been proposed for closure of heap leach operations in which the metals processing portion of the plant, possibly the carbon adsorption columns, or a collection pond is used as a bioreactor. The cyanide in the process solution is destroyed in the bioreactor and the treated water is used to rinse residual cyanide from the spent heaps. The water is recycled until the effluent WAD cyanide concentratio� meets discharge standards.

Jan 1, 1992

By A. B. Phillips

The Randfontein Estates Gold Mining Company (Witwatersrand) Limited (REGM) operates three metallurgical complexes for the recovery of gold from the Witwatersrand Gold Reefs at the town of Randfontein, 40 kilometers west of Johannesburg. Mining operations in the. area commenced in March 1889 and ceased temporarily in 1965 when the viable ore reserves had been depleted. Exploratory drilling in the 1960's indicated viable deposits of gold in the Elsburg reefs, south of the Witpoortjie Horst Block, _which formed the Southern limit of the previously exploited areas. Three shaft complexes have been established to exploit this area, known as the Cooke secti'on. In 1983 the Doornkop shaft was sunk to the north of the Cooke section to mine Kimberley reef and the South reef.

Jan 1, 1992

By E. Ghali, L. Tremblay, M. Lanouette, J. McMullen, G. Deschenes

Since the start of this decade, our society has attached great importance to matters concerning environmental protection. Currently, most mining operations use the cyanidation process in working gold deposits. While this process is efficient, the dangerous aspects of cyanide are delaying the development and marketing of cyanidation in underground sites. There is a growing need to consider installing an underground leaching system that will make the processing of low-grade gold ore profitable by reducing certain major operating costs (transportation, crushing and grinding). Underground leaching is performed in two ways. The first way is in-site or underground and the second way is in-situ. CANMET (Harrison et al.), in collaboration with Dennison Mines, developed the underground leaching of uranium. This process is used commercially. Copper, salt and sulphur are recovered by in-situ leaching (Jacobson and Murphy). The recovery of gold and silver is under development (Van Staden and Laxen).

Jan 1, 1992

By Stuart K. Nicol, Malcolm D. Engel, Neville T. Moxon

Ion flotation of gold is a process continuing to be developed to selectively beneficiate dilute aurocyanide liquors using a novel surface­active complexing agent. Aeration of these liquors causes accumulation of the precious metal species in the froth concentrate produced in a flotation column. Successful development of ion flotation for concentrating solids-free liquors would offer a low--cost method for recovering specific metals from heap leach runoff or waste tailings solutions. The cost of constructing and operating a 100 tph gold ion flotation facility has been compared with the relevant carbon adsorption plant costs. Reductions in operating costs of 25% and installed capital of 40% are possible in relevant expenditure areas. For an 'average' processing plant, this equates to annual operating savings of A$ 170 000 and a capital saving of A$ 515 000, with a three-point increase in total (mine and plant) site DCF ROI. High gold inventories are eliminated and the number of processing steps is reduced. The application of gold ion flotation will initially be confined to heap leach operations in the western U.S.A., although use of the process in mine abandonment programmes elsewhere is also an area of future development.

Jan 1, 1992

By Peter Krag, Rob Henson

It is well known that titanium and zirconium alloys offer superior corrosion resistance in the oxidizing sulfuric acid environments present in sulfide pressure leaching operations. The use of these materials is limited, however, due to their pyrophoricity; several accidents attributed to titanium equipment have been described in technical literature, and other, minor incidents·occur regularly1 • We describe an application of a commercial titanium alloy, Nb-55 Ti, with suitable mechanical properties, corrosion resistance similar to Grade 2 Ti, and featuring a significantly reduced field of ignition conditions

Jan 1, 1992

By Richard H. Follis

Activated carbons used for precious metal recovery from carbon-in­pulp (CIP), carbon-In-leach (CIL) and carbon-in-column (CIC) circuits often become fouled with Inorganic precipitates (i.e., CaCOa, CaS04, SI02), and adsorbed organics (I.e., petroleum distillates from lubricants, dissolution products from wood) (1,2). These contaminants occlude carbon pore structure, such that diffusion controlled adsorption and desorption (elution) of Au(CN)2-and Ag(CN)2· are lmpeded(3,4l. Thus, after only short exposure to the hydrometallurgical environment, the characteristic carbon activity is reduced(5l. By frequently regenerating circuit carbons, activity losses associated with fouling can usually be minimized. Regeneration typically Involves (not necessarily Is this order): 1) elution to remove adsorbed ionic species (e.g., until they are removed from the carbon pore structure, Au(CN)2" and Ag(CN)2-are contaminants )(6l; 2) acid washing with 3-15% (wt/wt) hydro­chloric acid, to dissolve soluble Inorganic precipitates such as CaC03; 3) neutralization and/or water rinsing to remove residual acid; 4) thermal regeneration at 350-650 °C to remove adsorbed and/or pyrolyzed organ­ics; and 5) screening to remove fine carbon particles produced by Impaction and abrasion in the various stages of the hydrometallurgical circuit (i.e., adsorption, elution, and regeneration). The overall process Is purposed to reopen the circuit carbon pore structure, and to maintain the activity and qualities of virgin (new) carbon(7,8l. While most CIP, CIL and CIC operators regenerate circuit carbons, few evaluate the effect of the process on carbon quality in a systematic way. Process control usually Involves Iterating critical regeneration parameters such as: acid concentration; time frames for acid washing and water rinsing; and temperature and residence time for thermal regeneration. Carbon quality control frequently comprises only sporadic activity tests performed on non-representative grab samples dipped from conve­niently accessed carbon storage bins. So, regenerated carbon quality may vary and (at times) be unacceptable for effective hydrometallurglcal circuit operation. To verify the efficacy of the regeneration process and assure accept­able adsorption and elution rates for Au(CN)2· and Ag(CN)2·, operators should systematically assess regenerated circuit carbon quality. This paper, then, suggests methods for effectively assessing circuit carbon quality, Including: carbon sampling procedures; standardized physical and chemical test methods; and criteria and general procedures for comparative adsorption rate (activity) testing. Also, a two tier quality control testing scheme is proposed, and techniques for presenting and interpreting test data are demonstrated.

Jan 1, 1992

By W. Baguley, L. P. H. Greenhalgh, R. P. Riley

The traditional impeller system for aeration and suspension of slurries, e.g. in bacterial oxidation plants, is the vertical flat blade turbine (VFBT) . This type of impeller is energy-intensive, which results in a heavy-duty design of shaft, gearbox and drive. The Mixtec BX04 agitator development programme is designed to evaluate the use of the new generation of hydrofoil impellers which consume less power and thus have potential for capital and operating cost savings as well as being possibly less damaging to the bacteria. The early tests on pyrite oxidation in a 300 litre laboratory pilot tank using the Thiobacillus ferro oxidans bacteria, showed that hydrofoil impellers had superior characteristics to the VFBT impeller and to air-agitated pachucas, with lower energy input. The geometry of the air sparge ring was found to be very important in optimizing the system. These early successes resulted in a prototype impeller and sparge ring beinq tested in a 9m3 tank where oxygen uptake in water, impeller cavitation at different impeller speeds and air flows were evaluated. Resulting from this work was the supply of an agitator unit to an operating bacterial oxidation plant where it has been successfully evaluated. This paper describes the development work so far carried out

Jan 1, 1992

By Somia Gurunathan, Harry Castrantas

Hydrogen peroxide and calcium peroxide are used to improve the extraction of gold/silver and reduce cyanide consumption in heap leaching and mill leaching operations. FMC's standard grade H2O2 and FMC's Permeox™ solid peroxygen, a formulated product containing cao2, was used for the experimental work. It was found that the rates of release and the longevity of these peroxygens in ore-cyanide mixtures are significantly different. When choosing a peroxygen, one of the key factors is extrac­tion time, with the longer extraction times of heap leaching primarily favoring calcium peroxide and the shorter extraction times of mill leaching primarily favoring hydrogen peroxide. A series of laboratory leach tests showed the choice between H2O2 and CaO2 to be ore and process specific. H2O2 and/or Permeox™ improved the gold extraction in four out of five ores tested. (2 sulfide and 2 oxide). Mixtures of H2o2 and Permeox™ were also found to significantly increase the gold extraction rate. A fifth ore (sulfide) did not respond to peroxygen treatment. In addition, savings in NaCN consumption was obtained with Permeox™. Both peroxygens offer economic incentives to gold processing.

Jan 1, 1992

By Dan Walker

The success of the heap leaching process for extracting precious metals from low grade ores in many cases depends on successful agglomeration of clay fines. This paper relates the development of a new agglomera­tion agent, named Leachit, that has demon­strated an ability in some ores to decrease leaching time. Data from a commercial test­ing laboratory is presented to illustrate a comparison of leaching efficiencies with other agglomerative agents, such as lime and portland cement. Conclusions will point out certain advantages of Leachit to the heap leaching gold recovery industry.

Jan 1, 1992

By Sepp A. Kutschera

are gaining increased interest for over­burden removal and ore production at large open cast mines. The application of bucket wheel excavators is still tied to soft un­consolidated rocks and soils, while belt conveyors can cope with all kind of matri­als restricted only by the top grain _ size. Therefore, mode of transport and the re­quirement of down stream ore processing de­fine the materials size distribution. These requirements are usually met by primary crushing or scalping. The paper discusses general applica­ tion criteria of bucket wheel excavator with systems primary for in-pit overburden crusher removal. and It _indeapits scalper units and discusses their technical and operational features. It further com­pares the capital and operating cost struc­ture relative to the syste

Jan 1, 1992

By Donald R. East

In the planning and design of mill tailing disposal facilities, the chemical and physical nature of the fine­grained material to be disposed of has to be fully understood in order to create an efficient and safe long­term storage facility. Disposal of tailing has become the single most important source of environmental impact for mining projects and the development of many promising ore bodies has been delayed or even stopped due to problems of facility siting and design under pressure of increasingly stringent regulatory require­ments.

Jan 1, 1992

By Sean E. Armstrong, Deepak Malhotra

The current trend in gold ore processing is the development of lower grade or highly refractory deposits. The perplexity of treating low grade oxidized ores has been adequately addressed by heap leach technology. However, refractory gold ores are very difficult to positively characterize the gold association within the mineral matrix. Gold accompanied with refractory sulfitlc or carbonaceous mineralization can often be sub­micron In size and occur interstitially. Mineralogical examination of these ores Is difficult, expensive, and occasionally Inconclusive. Hence, the metallurgist Is given little information for the selection of processing alternatives. The purpose of this paper Is to demonstrate the use of diagnostic leach procedures to assist the metallurgist' s decision-making process to solve some of these problems. By sequentially liberating and/or leaching gold associated with specific minerals, the amount of recoverable gold in each stage can be determined. Through careful interpretation of the results obtained by diagnostic leaching, the metallurgist can devise a flowsheet for treating the ore or solve a problem at an existing plant

Jan 1, 1992

By Jack F. McOuat

This paper describes how Canada's mineral exploration and development industries are on the decline as is its mineral reserve base. Not surprisingly, these are being offset by extensive and growing participation by Canadian companies and personnel in many other countries. The paper illustrates the extent and origins of this foreign activity as well as the present and future impact on Canadian mining and mining professionals.

Jan 1, 1992

By Kambhampati C. Rao, Cecil Lue-Hing, Nabih P. Kelada, William B. Willborn

improvements in the analytical techniques for cyanide speciation can furnish useful information about the behavior of the different cyanide species in the receiving environment. This could be of help to the environmentally concerned public and the regulatory agencies in the assessment of cyanide limits for effluents, stream quality, and land disposal of cyanide bearing wastes. In addition the ability to distinguish the free cyanide and the weakly bound cyanide from the strong ULTRAVIOLET IRRADIATION UNIT (LAMP, COIU3' HOUSING) FIGURE 1 complexes, as well as transformation to thiocyanate is also needed by different industries, such as mining and metal finishing, etc., to evaluate the efficiency of several processes. Cyanide has been used for the recovery of gold since the late 19th century. Although cyanide leach solutions are mostly recovered and used again, a large quantity of cyanide bearing wastewater becomes unfit for use and has to be treated before it can be released into natural waterways.

Jan 1, 1992