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By Henry L. Ehrlich

This survey compares bioleaching and biobeneficiation by autotrophic bacteria with that by heterotrophic bacteria and fungi Some physiological principles are reviewed. Advantages and disadvantages of autotrophic and heterotrophic leaching are discussed. Principles of anaerobic leaching by autotrophs and heterotrophs are introduced. and the advantages? over aerobic heterotrophic leaching are discussed. Examples of useful organisms in the autotrophic and heterotrophic categories are cited.

Jan 1, 1991

By P. L. Claessens, S. Belisle, C. Bowen

"Use of zinc shot feed is a well-established procedure among North American electro-galvanizers. This form of zinc is easy to handle and relatively inexpensive when compared with zinc oxide. This paper reports results on the kinetics of zinc shot dissolution in traditional pure zinc solutions and in electrolytes used for the plating of nickel/zinc alloys. Despite the cementation of minor amounts of nickel in the latter solution, acceptable dissolution rates of the zinc shot can be achieved through proper adjustment of the solution velocity. Under these conditions, the nickel shell produced by cementation is continuously abraded, exposing the underlying zinc.IntroductionThe use of insoluble, noble metal-containing anodes rather than soluble zinc anodes for the operation of high current density electro-galvanizing lines has gained almost universal acceptance. Two major reasons for this trend are:• improved control of the process by virtue of constant inter-electrode distance; and• increased productivity because the operation of the lines does not require the relatively frequent interruptions for replacement of consumed anodes .The results of the principal anode and cathode reactions are, respectively, depletion of the zinc content of the electrolyte and the increase on its acidity;"

Jan 1, 1991

By V. Rajaram

The Metropolitan Water Reclamation District of Greater Chicago (MWRD) imposed a no-blasting specification (blasting is restricted to the construction shaft and shaft bottom or boot) on the Deep Tunnel project in 1988. This was prompted by numerous complaints from the residents in the vicinity of the project, and controversies experienced on previous projects from blasting the rock overlying the tunnel. This paper will describe the methods utilized by two major contractors who are driving 20 km (12.5 of tunnel along with drilling over 36 shafts under this restrictive specification. The impacts on design, construction, schedule, cost, and the environment are detailed.

Jan 1, 1991

By Fredley D. C

Georgius Agricola wrote in De Re Metallica in 1556 that a prudent a miner should not work in a region ruled by a tyrant-a person inimical to mining. In 1926, Associate Chief Sherman of the United States Forest Service in a speech stated, "It is the policy of the Forest Service to encourage the development of the mineral resources within the boundaries of the National Forests ... a man who fails to cultivate a friendly, helpful, cooperative spirit in his relations with those who are endeavoring to develop the mineral wealth of our mountains has no place in the Forest Service." Both statements are as true today as they were in 1556 and 1926. The challenge to the Forest Service and the mineral industry today is to maintain that cooperation in a world that has changed significantly since Agricola and Sherman. The United States Forest Service manages 77,000,000 hectares of land-mostly in the Western United States-an area equal in size to New South Wales. The vast majority-75 million hectares are National Forests, and 1.6 million hectares are National Grasslands. National Wilderness Areas account for 13 million hectares or rough- ly 17 per cent of the National Forest System. National Forest System lands (NFS) are some of the most visible, scenic and controversial lands in the country. They are also some of the most valuable for their mineral potential and production. The value of mineral produced exceeds US$4 billion per year. There are over 1200 producing mines, 15,000 oil and gas leases, and some of the largest lead, copper, silver, gold, platinum, molyb- denum, and coal deposits in the hemisphere. Every year the Forest Service approves nearly 5,000 mineral operations on the NFS. Much of the NFS (75 per cent) is open to location of mining claims pursuant to the 1872 Mining Law. And an equal amount of land is legally available for oil and gas leasing.

Jan 1, 1991

By B. A. Paponetti

The following report discusses the bioleaching of chalcopyrite of italian origin catalyzed by Thiobacillus ferrooxidans. The developments vcr.ius time of the main .biochemical and chemical reactions involved in the production of soiuble and insoluble species were investigated focusing on the times at which they begin and bow long they last. The precipitates were characterized both in quantity and in quality relating the rate of the process to the precipitates fonnatiom. A material. balance has been made to verify the proposed mechanism.

Jan 1, 1991

By John R. Bartels

This U.S. Bureau of Mines report describes the development, system by system evaluation, and preliminary surface testing of a flywheel-powered shuttle car (FPSC). The use of a self-contained flywheel-power source has the potential to eliminate the numerous safety and routing problems associated with tethered mobile equipment. An alternative to conventional power cable systems was developed consisting of the world's fIrst seven-rotor stacked flywheel system capable of storing 6 kW·h of energy at 16,700 rpm. Numerous interdependent systems were necessary for successful interfacing with a conventional shuttle car. Each of these systems was evaluated and tested individually. Finally, the entire shuttle car was surface tested. The tests indicated that the flywheel energy system can function and operate a shuttle car. The economics of the system and the design of required support systems were not addressed in the project.

Jan 1, 1991

By 13409, B. Arjang

"Ground stresses are one of the significant factors in the context of rockbursts and underground instability at some hard rock mines in Canada. Overcoring strain relief measurements using triaxial strain cells were performed at several mine sites to provide stress data for stability evaluations and mine design. Pre-mining stress determinations carried out at depths between 60 m to 1890 m resulted in the following average stress gradients:Maximum horizontal stress, s Hmax = 8.18 + 0.0422 MPa/m depthMinimum horizontal stress, s Hmin = 3.64 + 0.0276 MPa/m depthAverage horizontal stress, s Ha = 5.91 + 0.0349 MPa/m depthVertical stress, a; = 0.0266 ± 0.008 MPa/m depthThe maximum and minimum horizontal compressive stresses, with an average ratio of J.75 ± 0.45, prevail in east-west and northerly directions, respectively. Horizontal compressive stresses in excess of vertical overburden load were determined, indicating large variations in ratios to a depth of about 1000 m with decreasing trend toward depth.From present data, a particular regional zoning for the magnitude and direction of horizontal stress fields cannot be outlined.A common feature at mines with near vertical orebodies is that the maximum horizontal stress acts perpendicular to strike while the minimum horizontal stress is aligned on-strike. The vertical stress components approach the gravitational overburden load."

Jan 1, 1991

By Johnson N. W, Ralston J, Lauder D. W, Smart St C R

The flotation behaviour of the Hilton ore of Mount Isa Mines has been examined in the presence of two collectors (sodium ethyl xanthate (Ex) and sodium diisobutyldithiophosphinate (3418A)) over a range of flotation Eh values and collector additions. Tests were also conducted in the absence of collector to determine the relative contributions of natural and self-induced floatability of the major minerals in the feed. In these tests the influence of metabisulphite on the self-induced floatability of the minerals was also determined. Attention focussed on optimising the selectivity of galena flotation. It is shown that the Hilton ore sample contained lower levels of naturally hydrophobic iron sulphide minerals than are generally contained in the Mount Isa lead-zinc ore. Furthermore, the self-induced floatability of galena was less than that exhibited by the galena in the Mount Isa lead-zinc ore. Sodium metabisulphite (MBS) reduced the self-induced flotation of galena but had no effect on the natural floatability of the iron sulphide minerals.

Jan 1, 1991

By Walter Jr Duke

The security of explosive materials is a vital concern to every mine, quarry and contractor engaged in blasting. Proper construction of magazines and sufficient locking mechanisms are the fundamental means of maintaining secure storage. The object of this paper is to review the proper methods of construction of storage facilities for explosives as defined by the Alcohol, Tobacco, and Firearms regulations. Subpart K subsection 55.208 and the Institute of Makers of Explosives recommendations.

Jan 1, 1991

By J. R. Diehl, R. W. Lai, R. W. Hammack, S. U. M. Khan

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of a selected coal pyrite and a mineral pyrite. Surface properties of pyrite were evaluated in terms of flotation response in the presence of both an anionic fluorosurfactant and sodium hydrosulfide. The charge transfer adsorption and oxidation potential of sodium hydrosulfide were evaluated using cyclic voltammetry. Drastic differences in the flotation response have been observed between the coal pyrite and the mineral pyrite. Significant differences in the cyclic voltammograms at pyrite surfaces of these two sources were also observed. Measurements by XPS and EGA were used to determine the oxidation products and the rate of oxidation of the coal-pyrite and the mineral-pyrite surfaces.

Jan 1, 1991

By C. I. Basilio

Pearson's hard and soft acid and base (HSAB) principle may be applied to flotation systems. The HSAB principle states that hard acids prefer to bond with hard bases and soft acids prefer to bond with soft bases. By determining the Drago E and C parameters for the different components of a flotation system, the HSAB principle could be used to explain the selectivity of some collectors such as thionocarbamates against some minerals. Determination of these parameters is done by utilizing Drago's theory and flow micro-calorimetry.

Jan 1, 1991

By H. L. Cheng, C. H. B. Leitch, C. T. Hood, A. J. Sinclair

"Epithermal Zn-Pb-Cu-Ag-Au quartz-carbonate-barite veins at the Silver Queen mine near Owen Lake, west-central British Columbia, are hosted by Late Cretaceous Tip Top Hill andesitic volcanic rocks. The veins form a rectilinear northwest-northeast pattern that differs slightly from regional structural trends. The main northwest-trending veins are oriented very close to the trend of regional northwest faults, but the crossing veins tend to be more east-north-easterly (070 degrees)compared to a regional north-easterly trend (040 degrees). The character of the veins suggests they are extensional features formed by dextral slip related to Paleogene oblique subduction, or intrusion of magma at depth, or both.In detailed exploration at the mine, the veins cannot be modelled as simple tabular sheet-like bodies. Instead, they are complex structures that divide and rejoin, forming multiple veins or stringers, or are found in shear zones as replacement features with quartzsericite- clay-carbonate-pyrite alteration haloes of variable width that make definition of vein margins and correlation from hole to hole ambiguous. In addition, individual veins within each of the main structures have en echelon characterboth along strike and down dip.Geological and assay data must be carefully studied to define the margins of these complex veins before any estimation of ore reserves may be made. Where multiple veins occur in a section, ore/gangue mineralogy, assays, character of wallrock alteration, and thickness of vein and mineralized hangingwall, median and footwall zones must be used to evaluate continuity of mineralized structures. Well-defined sections are projected into areas of increasing complexity. Once the vein boundaries are defined, metal concentrations, important metal ratios(Au/Ag, Pb/Zn, Cu/Zn), and true thicknesses of the vein provide the basic data for reliable ore reserve estimation."

Jan 1, 1991

By Corrans I. J, Yan D. S

The CIP process for gold recovery has enjoyed widespread application in most gold-producing countries. The development of a mathematical model of the CIP process has value for use in process design, process optimisation, and process control. Mathematical model development through laboratory experimentation is an important step in the design and optimisation of the CIP process. For this purpose, data has been generated through small scale laboratory leaching and adsorption tests both in batch and continuous mode. This test program has been carried out on specific ores of various types prior to the application of the models to production CIP plants utilising these ores. The applicability of leaching models derived from batch experiments was tested in a continuous five stage CIP pilot plant. The models were then adapted to scale-up the batch to the small scale continuous operation.

Jan 1, 1991

ABSTRACT- I Chemotrophic bacteria, capable of oxidising inorganic species such as Fe(II) and S(-]I) for their metabolic energy, have been known for many decades and interest in these bacterial species has increased since their ability oxidise auriferous arsenopyrite ores has been demonstrated. The rate at which bacterial cultures can oxidise a solid sulphide ore is of importance but a number of difficulties arise when attempting to evaluate this oxidative activity. The two major problems are counting the number of viable bacteria present in the reactor and identifying the types of bacteria that are active in both the solid and liquid phases. Enumerating the numbers of bacteria responsible for an observed change is necessary to compare the activity of different isolates. For selection and identification of bacteria during the development stages of a project, and for monitoring an operational process, the recognition of different species will be of importance. Methods for the taxonomic discrimination of bacterial species rely on observations, different culturing techniques, and the degree of DNA base homology between isolates. A method reported recently uses IR spectroscopy for comparisons between isolates. This spectroscopic method and its application is discussed.

Jan 1, 1991

By Raimo Vuolio

"Over the past 30 years, the Nordic countries have developed similar practices for estimating damage caused by rock blasting vibrations. However, over the last few years the risk of damage has sometimes been estimated by using international values, which have created unnecessary costs, since they are too conservative. This paper gives a proposal for Finnish blast vibration standards and a calculation model for the extent of the zones for building inspection, risk analysis, and vibration measurements. The international conclusion is that particle velocity is the best descriptor for limiting damage potential for structures. Over 900 000 vibration data recordings from 52971 blasts were collected for this paper during 1970-1989. They show that the most practical description is the vertical component of the peak particle velocity. As rock is a nonhomogeneous medium, it is hard to predict the need and scope of risk analyses, building inspection, and vibration measurements. As a large number of blasts were monitored for the recording of the peak particle velocity in several locations in Finland, and the data combined, it is possible to establish safe scaled distances for the calculation of the need and scope of risk analyses, building inspections, and vibration measurements."

Jan 1, 1991

I In an optical microscope, mild attack by cyanide solutions on various minerals can be observed by means of colour changes as well as etching patterns. However, the mineral may not be identifiable due to the coloured film. In some cases, a transfer algorithm between mechanical stages enables the surface-altered mineral to be identified in the SEM. A more severe attack may not be so informative, as it is not known whether the mineral attacked has been completely dissolved away. The leaching behaviour of some common minerals is described.

Jan 1, 1991

By W. D. Riley

Engineered Scavenger Compounds (ESCs), developed by the U. S. Bureau of Mines I are a novel class of compounds that can selectively recover a desired element from 'a solid or molten alloy. Lithium titanate (Li2Tip7 or Li20' 3TiO.) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (AI-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both of the structures are metastable, the hexagonal phase that forms during the scavenging of Li from AI-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electtodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li.Til07 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1991

By Garry W. Warren

The brass foundry industry produces a significant amount of waste sand containing Cu, Zn and Pb which is often classified as a hazardous waste due to Pb content. The potential application of a hydrometallurgical process to treat the sand by extracting metal values and thus detoxifying the material has been investigated. The process involves leaching of metal values followed by cementation. The emphasis of this investigation was on the leaching step, although some preliminary cementation experiments have been performed. In order for any alternative treatment scheme to be successful, the smaller size fractions of the sand must be addressed. Experiments have been performed on five individual size fractions using various lixiviants HCI, acetic acid and HCI/NaCI. Cu extraction was found to be slower than either Zn or Pb. Results obtained in this investigation indicate that copper is present in two forms, an oxide form which dissolves rapidly and is insensitive to the level of oxygen, and a less soluble form, probably metallic which dissolves more slowly and requires an oxidizing agent. The presence or absence of oxygen had no influence on the rate of Zn dissolution indicating that zinc is present mostly in oxide form. Toxicity Characteristic Leaching Procedure (TCLP) tests showed that residues could be produced which meet the toxicity limit for lead. Preliminary cementation experiments have also demonstrated the feasibility of Cu and Pb recovery.

Jan 1, 1991

By Liu X

The solubility of cobalt oxide in iron silicate slags has been measured at 1573 K by equilibration of silica and alumina saturated slags with liquid Co-Au-Fe alloys, and by equilibration of silica unsaturated slag with solid Co-Fe alloys, at oxygen pressures of either 10-9 or 10-10 atm (1 atm = 1.013 x 105 Pa). The activity coefficient of cobalt oxide has been calculated and compared with previous studies.

Jan 1, 1991

By D. Leppert

Large deposits of natural zeolites may provide cost-effective alternatives for treatment of soil and water contaminated ) with heavy metals and radionuclides. Research on the Bikini atoll demonstrated that addition of clinoptilolite to the soil significantly reduces cesium uptake by plants. Re- search on the potential use of zeolites in soils at Bunker Hill, ID indicated only minor benefits at very high contamination levels vs. US Bureau of Mines (USBM) work on the use of zeolites for treatment of mine waste waters emphasized problems with natural waters that previous studies have not addressed. High levels of competing calcium in natural waters significantly decrease the effectiveness of zeolites for heavy metal sorption and may limit the usefulness in these applications.

Jan 1, 1991