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By Manfred K. Walther

"Tests were conducted on instrumented plates cast in the Abex Experimental Foundry to compare recorded solidification histories with results computed for corresponding models simulated with the C.A.S.T. program. The first plate was cast of low alloy steel and the second of carbon steel with a graphite chill at one end. Both were cast in molds of bonded silica sand. Temperature histories were recorded in the castings, molds and chill. Exceptionally good agreement was achieved between computed and experimental data. Other investigators will find the results useful as a benchmark against which they can compare the results of their own calculations.IntroductionSince the early 1970's our foundry engineers have used both two- and three-dimensional versions of the G.A.S.T. program to gain knowledge of the solidification process [1,2,3]. Study of the computed data gave insight as to how the rigging and risering of specific castings might be changed or adjusted to improve quality and yield. New schemes based on such analyses were then recommended for implementation on the foundry floor. The degree of success of the new practice was subsequently evaluated after the part had been poured, shaken out and examined. Similar conditions were noted in the sectioned castings whenever porosity and voids had been predicted by the computations. Appropriate modifications, when found successful in the model, were applied to the process. This led to a reduction, if not complete elimination, of the defects. Such results gave credence to the use of these programs as an aid in the production of better castings.Earlier investigations on simple shapes revealed excellent correlation between output derived with the G.A.S.T. program and exact solutions. Results also compared favorably with data calculated using other codes as reported in the literature [4] and summarized in the Appendix. However, since the computer program had not been verified by direct experiment, it was decided to run instrumented tests to check the theoretical predictions with actual measurements."

Jan 1, 1986

Titanium dioxide (TiG ) is produced 2 commercially by two methods generally referred to as the "sulfate" route and the "chloride" route. The SCM Corporation, in supplying 15% of the world's demand for TiO 2, uses both of these processes. Of the two processes the sulfate route is generally regarded as the older and more established technology. Worldwide the sulfate route accounts for some 70% of total Ti02 production. However, in the U.S.A. the chloride process accounts for 80% of production. The processes vary in chemistry and raw material requirements. In the "sulfate" process finely ground ilmenite or titanium slag is digested with sulfuric acid to produce a porous "cake" vrnich is extracted with water and recovered liquor. The solution is treated with scrap iron to reduce any ferric ions to the ferrous state which is then crystallised and removed as ferrous sulfate heptahydrate. The liquor is concentrated by evaporation and hydrolysed to form the insoluble hydroxide which is filtered and washed free of impurities. This is converted to the dioxide by calcination at 800 - 1000¦C and milled to break up any aggregates. The "chloride" process uses a higher quality feedstock of natural or synthetic rutile and/or high grade titania slag. The feedstock is mixed with ground high-purity coke and chlorinated at 950¦C in a fluidised bed. The resulting crude titanium tetrachloride is purified by distillation and chemical treatment. The purified titanium tetrachloride is burned with oxygen or oxygen enriched air to give titanium dioxide and chlorine, which is recovered and recycled to chlorination. Titanium dioxide pigment from both processing routes undergoes similar finishing techniques. It is subjected to further stages of wet and dry milling, then coated with layers of inorganic oxides in order to enhance its properties for specialist applications.

Jan 1, 1986

By P. Bartel

Coal cleaning can be effected by the bacterium Sulfolobus acidocaldarius, which in oxidizing sulfur and dissolving mineral matter requires carbon dioxide and oxygen; carbon dioxide as a carbon source and oxygen as an electron acceptor. The desulfurization of coal by thermophilic bacteria under elevated partial pressures of carbon dioxide and oxygen was studied at a total pressure of 1 atm. The partial pressure of carbon dioxide was varied over the range 0.00032 to 0.33 atm (0.00032, 0.007, 0.10, 0.33 atm), and the partial pressure of oxygen was varied over the range 0.14 to 0.40 atm (0.14, 0.21, 0.30, 0.40 atm). The maximum rate of coal desulfurization increased by 32%, from 9.0 to 11.9 mg S/1 hr, as air was enriched in carbon dioxide from its atmospheric level of 0.00032 atm to 0.10 atm. Enrichment with carbon dioxide up to 0.10 atm, at constant oxygen partial pressures, increased the desulfurization rate, but enrichment to 0.33 atm caused the rate to decrease. At constant carbon dioxide partial pressures, the desulfurization rate was maximum at oxygen partial pressures of 0.21 and 0.30 atm. At higher (0.40 atm) and lower (0.14 atm) oxygen partial pressures the rate decreaed by 9 to 20%. The desulfurization rate decreased by 58X, from 9.0 to 3.8 mg S/1 hr, when the air pressure was increased from 1 atm to 3 atm. The effects justify an economic analysis during design and operation of a commercial air feed in a process to desulfurize coal by microbial action.

Jan 1, 1986

By Charles D. Litton

Introduction The successful performance of a mine-wide fire detection system depends upon its ability to detect the presence of a fire rapidly and reliably. It should be sufficiently rapid so that there remains enough time to either safely evacuate a mine or successfully extinguish and control the fire or both. It should be reliable so that false alarms are minimized without sacrificing sensitivity or time response. Systems should also be durable enough to withstand the mine environment over long periods of time while maintaining a high degree of re1iability. Maintenance and calibration of the system should be simp1 e and not require the expenditure of excessive time and manpower to keep it operational. Sensitivity, reliability, and durability of mine fire sensors and their electronic support systems have been the subject of significant Bureau research within recent years. The bulk of this type of information, along with the reports from which the remainder of this paper is derived, can be found in the Bibliography. It suffices to say that there exist commercially available systems for use in mines. This paper addresses a strategy for the use of such sensors and systems. Many factors influence the design of a mine-wide fire detection system, such as the potential sources and modes of ignition, the types of combustibles involved and the quantities avai1able for fire growth and flame spread. Mine air ventilation influences the growth and spread of a fire and also serves to transport the products-of-combustion to other areas of a mine remote from the fire. Fire sensor alarm thresholds place limits on the sizes of fires that can be detected. The time to respond to a detected fire, either in terms of evacuation or control and extinguishment, place additional time constraints on the design of fire detection systems. These factors interact with each other, often in complex ways, and it is the definition and understanding of these factors and their interactions that hold the key to the design of adequate and re1iable fire detection systems. Our level of understanding of the problem has increased dramatically within recent years and it is the intent of this paper to discuss the progress that has been made and how the information can best be used to improve the level of fire detection in underground mines.

Jan 1, 1986

By Lilly PA, Kavetsky AP

An empirical, kinematic model is developed which calculates the trajectory of individual blocks of rock in a blast, their point of impact in the muckpile and the final shape of the muckpile. The method is based on the determination of initial block velocity and requires input on stemming length, bench height, subdrill, burden, spacing, energy of explosive per unit length of blasthole, energy attenuation rate and resistance to movement. The model, which will form part of a comprehensive blast simulation package, has application in open cut mining in predicting muckpile geometry and the movement of grade blocks during blasting, which in turn impact on shovel productivity and grade control.

Jan 1, 1986

By Qing-Wang Hao

In this paper, the authors attempt to develop engineering based approaches for estimating safety factors against pillar and floor failures and predicting likelihood of subsidence events over abandoned coal mines in Illinois. There are two critical problems involved in the analysis: determination of geotechnical properties, and consideration of time effect. The authors attempt to solve the problems by generating hypotheses, which are used to modify existing engineering models for estimating pillar and floor safety factors. The modified models are validated using data from two well established databases of subsidence events over active and abandoned mines in Illinois. The data analysis suggests that most of the trough type subsidence events in Illinois were caused by floor failures rather than pillar failures. The subsidence incubation period seems to be directly related to initial floor safety factors at the time of mining. This correlation can be used to predict the likelihood of subsidence and to assess subsidence risks within both spatial and temporal contexts where detailed mine maps are available.

Jan 1, 1986

By J. Szekely, S. Rhee

"A mathematical formulation has been presented to describe heat and fluid flow phenomena in CVD operations. In the statement of the problem, which included consideration of plasma enhanced CVD systems, emphasis was placed on identifying the parameters which play a key role in determining the rate and the spatial uniformity of the deposition process. This was done both through the appropriate dimensionless groups and by presenting an extensive set of computed results. The main conclusions that may be drawn from this work are that the deposition rate will be inherently non-uniform for atmospheric CVD systems; this may be somewhat ameliorated by inclining the susceptor or changing the vessel contours. Operation at greatly redeced pressures and for PECVD systems will give a much more spatially uniform deposition rate.1. INTRODUCTIONIn recent years, there has been a growing interest in chemical vapor deposition techniques for the preparation of thin films for semiconductor, photovoltaic applications and for coatings in general, as evidenced by numerous journal articles and symposium proceedings devoted to this topic (1-6). An interesting variant of this technique is to perform the deposition in a plasma or glow discharge at low pressures because this technology obviates the need for the thermal decomposition of the precursor at the substrate surface and permits operation at greatly reduced temperatures (7-10).By far, the largest portion of the reported work dealing with both these aspects of the technology has been concerned with the characterization of the deposit, quite properly so. However, in more recent times it has been realized that the transport aspects of these processes are also deserving of attention because the understanding of heat flow, fluid flow and diffusional phenomena may provide the key to the solution of problems associated with obtaining uniform deposits and the proper scaling of laboratory measurements in order to design industrial CVD systems."

Jan 1, 1986

By Eric G. Kok

Complying with respirable dust standards is presently a critical problem for many longwall faces equipped with double drum shearers. Results are presented of research performed to increase the quantity and optimize the distribution of the water supplied to the shearer drums to control the shearer operator dust exposure. The effect on the total respirable dust produced by the shearer was also examined. During the research effort, a simple and inexpensive manually controlled valve system was designed and implemented on a shearer to distribute the water supplied to the shearer drums. Research showed that increases in water quantities are beneficial but associated pressure increases may induce respirable dust boilover negating potential advantages. Other essential parameters such as location of shearer operator, outside spray orientation and air quantity were considered in the evaluation.

Jan 1, 1986

By Grimstone LR, Leach JHJ

An analytical technique is described to identify areas of structural disturbance to coal and interseam strata in coal measures. It is based on exploration borehole data which records seam intersections and interseam lithologies. Computerised data bases have been developed to allow processing of large quantities of borehole records. The case study discussed is located in a tectonic setting dominated by thrust faulting. It provides a mechanism for the identification of low angle and bedding plane faults. In addition it allows the preparation of plans showing the areal distribution of the thrust sheets in the statigraphic section throughout the mine prospect. The technique requires the identification of normal undisturbed depositional thickness of coal seams and interseams to be determined. This is done for coal by the identification of coal ply distribution over the area. For interseam lithologies it is based on sedimentological modelling of lithology distributions, related back to the original depositional environments. Variations from the expected values are interpreted as structural Deformations.

Jan 1, 1986

By N. Kyriazi, W. Duerr, J. Shubilla, J. G. Kovac, J. Kravitz

A joint effort by the Bureau of Mines and the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, was undertaken to determine how well self-contained self-rescuers, deployed in accordance with Federal Regulations (30 CFK 75.1714), held up in the underground environment. This report presents findings regarding laboratory-tested breathing apparatus from the first year of a 5-yr program as well as other related findings. The SCSR's were tested on human subjects and on a breathing and metabolic simulator. These results indicate that the apparatus, if well-treated, perform as expected except for manufacturing defects or quality control problems, which are identified. However, when the apparatus are carried in and out of the mine every day and stored at the working section, they may suffer abuse that can be extreme. Physical signs of abuse, unless extremely obvious, frequently are not detected by the miners or the mine operators; this poses a danger to a potential user in case of emergency. Recommendations include improved training in inspection procedures.

Jan 1, 1986

By Richard K. Thorpe, Francois E. Heuze

The concept of a reusable underground nuclear test facility, named HEDEF, has been under study for some time. This rock chamber would have to be engineered to sustain the repeated mechanical and thermal shocks of internal explosions. In this paper, we summarize preconceptual studies performed in support of HEDEF, including -simple dynamic calculations for internally loaded tunnels, -outline of proof-of-concept tests of proposed reinforcement, - and initial dynamic testing of reinforcement components in an underground high explosive (HE) test.

Jan 1, 1986

By M. S. Basich, J. S. Scope1, J. H. Raeder

During 1983, The Youghiogheny and Ohio Coal Company's lost-time-incidence rate was 8.1, equal to the average for underground bituminous operators. How- ever, one half of all lost-time injuries were low back, back and neck related. In reviewing these results, we determined that substantial improvement could be made. We investigated existing back schools and the possibility of opening an in-house clinic. In September 1984, we began The Youghiogheny and Ohio Coal Company's Back Care Program. The objectives of the program are to reduce the number of back injuries incurred at the work site, hasten recovery time, decrease medical and workers' compensation costs and provide the employee with a thorough understanding of his problem. A state-of-the-art clinic capable of treating injuries to the spine and extremities has been established at the work site. The clinic is staffed by a licensed physical therapist and is offered to all employees on a voluntary basis under physician referral. The approach to treatment is multi-phasic. For the typical patient, the initial goal is to reduce pain and correct dysfunction. Treatment modalities such as auto-traction, extension exercises, ultra sound and moist heat are frequently used. During this period the patient is given extensive education regarding his problem. As soon as more vigorous activity can be tolerated, a work-hardening pro- gram consisting of job simulation activities designed to improve flexibility, strength and functional capability is begun.

Jan 1, 1986

By Erwin Flender, Preben N. Hansen, Peter R. Sahm

"Until now FDM-Techniques have been widely used for Modeling Solidification Processes in Castings. Often a rigid, regular type of enmeshment (cubes, , --) have been used. This has the advantage of low CPU-costs, but the disadvantage of a zig-zag presentation of the interface between the casting and the mold. The last point is the reason why FEM-Techniques, giving the possibility of a true presentation of the shape in the enmeshment, are increasingly used. The disadvantage is the high CPU-costs. In this paper, a technique is presented, which uses the FDM-Mesh with the zig-zag presentation of shape and ADI-Algorithms to calculate temperatures and gradients. The new idea is that the calculated parameters are not presented related to the mesh in which they are calculated, but displayed using the true shape of the casting. Such an advantage of both low CPU-costs and shape correct presentation of the calculated results are achieved. IntroductionThe main reason for using a regular type of enmeshment is that it gives the possibility, via ADI-Algorithms, of obtaining a very fast FDM-Technique. The technique presented by P.R. Sahm and P. N. Hansen (1984), and also used by E. Flender (1985), is numerically so stable that average time steps, at least 200 times larger than the limit given by the explicit FDM-Technique, can be applied. To obtain reasonably good results, average time steps in the range of 20 to 50 times the explicit limit seems to be applicable. It should be pointed out,however, that FDM-Techniques can be used on arbitrary nets, the disadvantages being the same as for the FEM-Techniques. This has, among others, been discussed by P.R. Sahm and P.N. Hansen (1984)."

Jan 1, 1986

One of the often overlooked factors affecting the capital investment decision in new or existing plants is the value of stock holdings necessary to maintain the plant. This paper puts forward a simple decision matrix on whether a part should be stocked depending on 1. the criticality of the item of equipment in terms of the effect on cash flow of its failure, 2. the lead time of the part, and 3. the stock holding value if it were Stocked.

Jan 1, 1986

By John B. Bennett

This Bureau of Mines report presents a method of standardizing forecasts of mineral consumption that attempts to resolve the problems caused by the use of different data bases, different definitions of minerals consumption, and different base years for making projections. Using this method, forecasts of U.S. and world mineral consumption, in the year 2000, for nine commodities (aluminum, chromium, cobalt, copper, manganese, nickel, tin, tungsten, and zinc) are standardized and compared. Also selected forecasts or associated growth rates are used to generate implied values of consumption for 1980-83, which are then compared to actual values of consumption for 1980-83. The economic growth predictions underlying the forecasts are examined, and some general conclusions are drawn. A description of each methodology used to generate these forecasts is given in an appendix.

Jan 1, 1986

By S. K. Ghosh

This paper discusses how the information on ash composition, ash-fusion temperatures, and ash-slag viscosity can be used to predict slagging and fouling potentials of a particular coal. A review of several empirical parameters that are commonly used for determining such potentials is given. Also, some guideline values for interpreting the relative propensity of slagging and fouling of various types of coal are provided.

Jan 1, 1986

By A. L. Craven, J. P. L. Bacharach, D. B. Stewart

"Inert gas use for underground mine fir e control is a well-established mature technology in some parts of the world. This paper reviews three candidate inert gases and describes three case histories where inert gas fire-fighting technology was used in actual underground fires.IntroductionInerting is the introduction of an inert gas into an atmosphere in contact with a fire to reduce the level of oxygen and hence the intensity of the fire 10 the point of extinction. The benefits of inerting include:a. Reduced Explosion HazardBy displacing oxygen from the atmosphere surrounding the fire the risk of secondary gas explosions is reduced. For example, simple methane-air mixtures at standard temperature and pressure are non-explosive below 12% oxygen. In actual mine fires, combustible gases may include hydrogen and carbon monoxide as well as methane. Such gases are also rendered non-explosive with oxygen removal to below 40/0. Fuel-rich oxygen-deficient mixtures can however be made explosive through dilution with air. Such dilution can occur downwind of the fire. It is also important to remember that the atmosphere in a sealed-off fire zone is rarely homogenous.b. Reduced Fire Intensity and SpreadIn a fire zone the initial combustion may well set alight materials surrounding the fire. Inerting can reduce the intensity and spread of secondary combustion and can cool the area surrounding the fire zone after the fire itself has been extinguished.c. Reduced Air LeakageLeakage of air into sealed areas in excess of the natural leakage may be reduced either by introducing inert gas into the leakage paths to replace air or by pressure balancing seals and providing a chamber of nitrogen on the outbye side of the seals. Both methods assist in the reduction of the intensity of combustion and hasten oxygen starvation."

Jan 1, 1986

Develop technology for preparing thick corrosion-resistant coatings and electroforms of iron-chromium-nickel alloys. Approach To reduce the United States' dependence upon foreign sources for supplies of strategic and critical metals such as chromium, cobalt, and nickel, new technology must be devised to conserve these valuable commodities. One approach being investigated by the Bureau of Mines is the use of a modified-aqueous-electrodeposition method to prepare thick (-25 µm), complex alloy coatings (e.g., stainless steel composition) with properties similar to the commercial alloys. An alloy coating on a low-alloy steel or carbon steel substrate would require significantly less strategic and critical metals than those contained in an equivalent mass of the commercial alloy. Coatings applied to appropriate mandrel materials make possible the preparation of intricately-shaped alloy electroforms (near-net-shape parts). As a result, the loss of valuable metals associated with machining finished products would be minimized.

Jan 1, 1986

By G. T. Lineberry, L. Adler

Due to safety-imposed constraints on clearances for mobile bulk handling equipment, it is necessary to optimally select a unit based on speed and size. The unit cannot be both large and fast. Since output is proportional to both size (or capacity) and speed, the combination must be carefully examined to maximize output. A simple graphical procedure and a calculus-based solution are presented to accomplish this. While the procedure applies to all mobile bulk handlers, as an example of the solution technique, attention is focused on shuttle cars. Background Major variables To fully define a bulk handling problem, the conditions, equipment, and activities must be characterized. The conditions and activities, when lumped together, are termed "encumbered space," since they "act to impede motion, as with a burden" (Lineberry, 1979). The insertion of mobile bulk handling equipment into what is already a difficult set of conditions and activities compounds the state of encumbrance, as limited space is competed for by many normal and life support systems. Long (1972) recognized the effects of design criteria, including road width, on haulage vehicle speed and, therefore, on production. Velocity-clearance curves Velocity-clearance curves are either available or can be constructed in the field. A preliminary set of curves for average conditions and activities is shown in Fig. 1, where clearances are only for the side of the vehicle (Lineberry and Adler, 1984). These curves set the safe speed limits for a vehicle operating at given clearances, under given conditions and activities. When feasible, velocity-clearance curves should be constructed through field measurement and observation. Curve construction should also consider haulway roughness, distances, and operator skill, as well as loading and dumping characteristics. It should be noted that haulage capacity determination is a total systems problem, not one just dependent on velocity and clearances. Production requirements and company capabilities also influence capacity determination.

Jan 1, 1986

By Thomas S. Mackey

The industrial types, sources, and quantities of USA tin residues are identified and the methods of treatment reviewed. The effect of a lower tin price, due to a current major world surplus of tin metal, is mentioned and covered in some detail. The names and locations of over 100 USA firms recovering tin residues are listed. Current smelting and refining charges are included to convert the residues into tin metal and alloy. The impact of the suspension of the LME daily tin price since October 24, 1985 to date, and the failure of the International Tin Council to support the Buffer Stock Manager are reported with comments.

Jan 1, 1986