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By O. W. Ellis

In view of the extensive use of the brasses and bronzes in engineering practice it is indeed surprising that so little scientific work has been done on the oxides in these alloys. Recognition of the ill effects of these compounds is universally accorded, both in foundry procedure and in such specifications as cover the melting of these useful mixtures. In the latter, limits, for example, are placed on the proportions of scrap metal In the charge, and clauses governing the use of fluxes are included, the addition of fluxes to the charge being made with the object of avoiding oxidation during the process of melting and of subducing and separating non-metal-lic matter from the melt.1 In the manufacture of brass it occasionally, though rarely, occurs that the virgin metals, copper and zinc, alone arc used. In the event of virgin metals being employed, that of the higher melting point is always melted first. If it is melted under suitable conditions, little or no oxidation will occur. Whether oxidation has occurred or not, however, can best be determined by microscopic examination of a sample taken from the melt. Avoidance of Oxidation in Furnace Practice When melting virgin copper in crucible practice, the avoidance of oxidation is not difficult, nor is it hard to forestall trouble in the electric furnace. In gas-fired furnaces of the barrel type, however, the avoidance of oxidation is almost impossible, no matter what the condition of the flame, the flux employed, or the amount of charcoal included in the charge. Copper melted in furnaces of this type is almost invariably so highly oxidized as to requirc very considerable additions of such deoxi-dizers as, for example, silicon copper to render it free from cuprous oxide. As a result,, the castings produced are decidedly inferior, on account of the. large amount of silica which is engendered in the metal as a result of the reaction, Cu2O + Si = SiO2 + 2Cu. The deoxidation of such oxidized copper could, of course, be effected by means of zinc with, however, even more disastrous results.

Jan 1, 1930

By M. H. Merriss

Some years ago, at the plant of the Baltimore Copper Smelting & Rolling Co., the receipt of large quantities of copper blister running high in lead, nickel, and arsenic resulted in the formation of a great amount of very foul slag, in the anode furnaces. A typical analysis of this slag was: Gold, oz. per ton......... 0.09 Arsenic, per cent.......... 0.60 Silver, oz. per ton......'.. 13.20 Antimony, per cent........ 0.50 Copper, per cent......... 19.50 Silica, per cent............ 28.30 Lead, per cent........... 11.90 FeO, per cent............. 19.20 Nickel, per cent.......... 4.60 CaO, per cent............. 1.60 The problem was to get out the copper in marketable form, to save the gold, silver, and particularly the nickel, and to get rid of as much as possible of the lead, arsenic, and other elements that were valueless to the Baltimore plant. In a copper refinery that does not take custom material for matte smelting, the usual method is to smelt the anode slag with coke in a reducing furnace, the black copper thus formed being sent back to the anode furnaces; this was the custom at Baltimore. An average anode slag will contain, perhaps, 40 per cent. copper and such small quantities of lead, nickel, etc., that smelting will get rid of most of these impurities in the black-copper furnace slag. To treat such an impure slag in this way, however, would result in a large nickel loss, and would send back to the anode furnaces all the lead and nickel not so lost, where it would be slagged off again and returned to the black-copper furnace as a slag still more concentrated in impurities. The result would probably be a constantly increasing amount of anode slag containing a likewise constantly increasing percentage of impurities. To avoid such a disastrous closed circuit some other process had to be devised. A small multiple-tank room, built for impure copper as an adjunct to the main series electrolytic refinery, was available, so the following standard process was suggested:

Jan 1, 1924

By Karl Eilers

During my stay of two years in this country, I have heard of only four electric mine-locomotive plants, of which three were built by the firm of Siemens & Halske, and the fourth by the Allgemeine Elektricitatsgesellschaft, both of Berlin. The earliest of these was established in 1882 in the royal coalmines at Zaukeroda, Saxony. In 1883, the Consolidated Paulus and Hohenzollern colliery at Beuthen put in a plant; and in the

Jan 1, 1892

By Paul Bechtner

THE name bentonite formerly was applied solely to a peculiar clay occurring in Wyoming and South Dakota, which was distinguished from other clays by its unctuous feel when wet and the property of swelling in water. In the last decade scientific studies of clay have recognized that bentonite is composed mainly of the clay mineral montmorillonite and the name bentonite has been extended to cover the entire family of clays that have montmorillonite as their chief constituent. Montmorillonite has the chemical formula of A1203-4Si0-xH2O, With Fe203 and MgO replacing part of the A1203. The montmorillonite crystal is an Si-Al-Si clay mineral, being formed of two silicon-oxygen sheets with an aluminum-oxygen sheet sandwiched between them. In contrast, kaolinite-the chief clay mineral of most clays other than bentonite-is Si-Al, one silica and one alumina sheet. The unit crystal of montmorillonite is much thinner than that of kaolinite, with greater surface area. These differences in crystal structure patterns are leading factors in the dissimilar properties and commercial uses of bentonite compared with other clays. Mineralogically, bentonites are 85 to 90 pct montmorillonite with fragments of feldspar, gypsum, calcium carbonate, quartz and traces of other minerals. They vary in color; the widely used Wyoming type is creamy white when dry and a light shade of tan when wet; the low-swelling bentonites of the southern United States and elsewhere are found in many shades of gray, blue, yellow, red, and brown. Pure white bentonites are rarer and generally of the medium or low-swelling type, though there are a few exceptions to that general rule. PROPERTIES Bentonites may be divided into two general classes: (1) those that adsorb large quantities of water, "swelling" greatly in the process, and that remain in suspension in thin water dispersions; (2) those that adsorb only slightly more water than ordinary plastic clays or fuller's earths, do not swell noticeably, and settle rapidly in thin water dispersions. Another distinction is that some varieties of the No. 2 type

Jan 1, 1949

By Thomas P. Forbath

THE sudden realization that known sulphur reserves amenable to mining by the Frasch hot water process are nearing exhaustion focused attention on widely scattered surface deposits throughout the world. These deposits are not necessarily of lower sulphur content than ores located underneath Louisiana or Texas salt domes which usually average about 30 pct sulphur disseminated in limestone matrix. Their near surface occurrence, however, renders exploitation by the Frasch process impossible. As is well known, the Frasch process depends on the presence of 500 to 1000 ft of overburden and cap rock above the sulphur deposits to permit melting underground sulphur in place by diffusing hot water under pressures of 200 to 600 psig in the formation and raising the molten sulphur to surface by air lift. This process renders possible the production of pure sulphur which is 99.5 pct pure without any subsequent treatment. Surface deposits contain sulphur in the same range of concentrations as the salt dome deposits, i.e., from 10 to 50 pct sulphur, associated with various gangue materials such as silica, limestone, and gypsum. The pirincipal distinction, then, does not lie in the percentage of sulphur contained in the ore, but in the geological nature of the deposit. A recent study' of the world sulphur supply situation estimated 1950 sulphur production in the free world countries at 5.6 million long tons, of which the United States produced 5.2 million tons, or 93 pct of the total. While America's domestic needs alone would have been covered by national production, about 1.4 million tons were exported during the same year. Despite all the steps which are being taken to restrict use of elemental sulphur and to force the fullest possible development of alternate sulphur sources here and abroad, the deficit in elemental sulphur production will probably increase with time. As a result of intensive prospecting for oil throughout the Gulf Coast area discovery of significant new salt domes is held unlikely. With the growing scarcity of sulphur and what appears to be an inevitable rise in price, recovery from deposits not amenable to Frasch-process mining assumes greater economic importance. Untapped Reserves The most important deposits in this category are located in Sicily, where elemental sulphur occurs in Miocene limestone and gypsum formation. Sulphur content of these ores ranges from 12 to 50 pct with an estimated average of 26 pct. Although quantitative estimate of these reserves is not available it is held that they exceed 50 million tons of sulphur. Similar deposits occur also on the mainland which contribute about one-third of Italy's total current annual production of 230,000 tons, but these are known to be nearing exhaustion. Significant surface deposits of volcanic origin are located in South America, Japan and western United States, silica being characteristic gangue con-stituent. The largest of these deposits are in South America. More than 100 extend over a zone 3000 miles long, paralleling the west coast of South America. 'Total sulphur content of these deposits has been estimated to be as high as 100 million tons. The main islands of Japan also possess at least 40 known volcanic sulphur deposits with probable reserves of 25 to 50 million tons.' Prospected reserves in western United States might amount to 2 million long tons, principal deposits being located in the northwestern part of Wyoming, southern Utah, and eastern California. Volcanic deposits of lesser importance are found around the Mediterranean, in Turkey and Greece, and in Africa, Egypt, Abyssinia, and Somaliland. Beneficiation Methods Different methods of beneficiation have been used in these various locations. In Italy the Calcarone kiln and Gill regenerative furnaces are used exclusively. Both utilize heat liberated by burning part of the sulphur in the ore to liquify or vaporize the remaining sulphur, which is recovered by solidification or condensation. The Calcarone kiln is of conical shape, generally 35 ft in diam at base and 18 ft high. A kiln of 25,000 cu ft capacity burns for about two months and yields about 200 tons of sulphur. The Gill furnace consists of a series of chambers with domed roofs. Sulphur is burned and melted in one chamber at a time and the hot combustion gases are used to preheat the ore charge in the subsequent cell. These furnaces operate on a cycle of 4 to 8 days. The recovery yield of both systems is about 65 pct. Sulphur losses amount to 25 pct through the combustion to sulphur dioxide; about 10 pct is retained in discarded calcines. Ores containing less than 20 pct are not considered suitable as furnace feed. These methods are not only wasteful because of the low recovery obtained, but represent a serious atmospheric pollution problem. Sulphur produced ranges from 96 to 99 pct purity and thus does not match Texas or Louisiana sulphur. Owing to the present shortage, sulphur in the Middle East sells

Jan 1, 1954

By John C. Shyne, Eric R. Morgan

BORON as a hardenability agent of commercial importance has been the subject of extensive study in recent years. It has been suggested in the past that boron increases hardenability by combining with nitrogen, thus rendering it innocuous.&apos; More recently it has been proposed that boron increases hardenability by reducing the free energy of sites of ferrite and pearlite nucleation.&apos; The segregation of boron to grain boundaries, the primary site of nucleation, would account for the large hardenability effect of minute additions of boron in steel. This grain boundary theory has found general acceptance while the concept of boron as a nitrogen scavenger has been disregarded. However, the interaction of boron and nitrogen in steel is considered to be important to hardenability because boron may be made ineffective by combination with nitrogen.". * The present work was undertaken to examine some of the effects of boron and nitrogen arid their interaction in steel. A base composition of moderate hardenability was chosen. This was a 0.35 pct C steel containing 2.50 pct Ni and 0.30 Mo. This composition was used because it contained no strong carbide, nitride, or Table I. Composition of Steels by Analysis, Wt Pct Steel C Ni Mo 0&apos; B N* Base 0.35 2.50 0.30 0.0012 nil <0.0001 Boron 0.35 2.50 0.32 0.0012 0.0022 <0.0001 Nitrogen 0.33 2.60 0.35 0.0015 nll 0.0052 Boron plus nitrogen 0.35 2.48 0.30 0.0006 0.0020 0.0040 * Obtained by vacuum fusion technique. boride-forming elements. The other alloys examined were modifications of the base composition and contained nitrogen, boron, or nitrogen plus boron. The compositions of the four alloys used are listed in Table I. The alloys were vacuum melted from electrolytic iron, electrolytic nickel, ferromolybdenum, and fer-roboron. When required, nitrogen was added by admitting a partial pressure of nitrogen over the melt after vacuum melting. The alloys were cast into 21h-in. diam ingots and hot rolled to %-in. sq bars. No ingot pattern was discernible on the polished and etched cross sections of the hot-rolled bars. The alloys were normalized at 1650°F, then machined into standard %-in. diam end-quench hardenability test bars. Four different austenitizing treatments were used: 60 rnin at 1550°F, 45 rnin at 1800°F, 30 rnin at 2000°F, and 20 rnin at 2000°F followed immediately by 30 rnin at 1550°F. The 1550" and 2000°F treatments were carried out in duplicate for each of the four steels. In order to prevent surface oxidation the bars were austenitized while buried under charcoal in an atmosphere of argon. After quenching the bars in a conventional end-quench fixture, the hardness surveys were made in the usual fashion on parallel flats ground along opposite sides of each bar. These were ground 0.050 in. deep rather than the conventional 0.015 in., to avoid decarburized or deboronized regions.5 The austenite grain sizes which resulted from each heat treatment were observed metallographically using Vilella&apos;s etch for martensite. The criterion used as a measure of hardenability was the distance from the quenched ends of the bars at which a hardness of RC 35 was observed. This hardness represented the inflection point on the hardness vs distance plot. Fig. 1 shows the hardenability of each steel after the several heat treatments. The duplicate tests demonstrated excellent reproducibility; the distance to Rc 35 was reproduced within 1/16 in. for duplicate test bars. All four alloys had the same grain-coarsening characteristics. Neither boron nor nitrogen had any observable effect on grain size. The grain sizes resulting from the various austenitizing treatments were ASTM 7 at 1550°F, ASTM 4 at 1800°F, and ASTM 2 at 2000°F. The small amount of boron in the boron steel greatly enhanced hardenability when the samples were austenitized at 1550°F. The low hardenability of the boron plus nitrogen steel showed that nitrogen eliminated the boron contribution to hardenability. Both steels containing nitrogen, with and without boron, exhibited lower hardenability than the base composition when quenched from 1550°F.

Jan 1, 1958

By S. C. Das. Gupta, B. S. Lement

isothermal formation of martensite occurs in the range of —65o to —197oC and is always preceded by some athermal transformation. By rapid cooling the isothermal, but not the athermal, component of transformation can be suppressed. Stabilization against isothermal transformation can be induced by cycling from below M. to room temperature. A LTHOUGH the transformation of austenite to XV martensite is generally believed to occur only on cooling, recent evidence indicates that this reaction can also occur at constant temperature. Isothermal formation of martensite was observed in tool steel by Fletcher, Averbach, and Cohen.&apos;. They found that the hardening reaction that occurs during the quenching of a plain carbon or low carbon alloy tool steel does not stop immediately when room temperature is reached; instead austenite continues S. C. DAS GUPTA is Research Fellow, Department of Metallurgy, University of Notre Dame, Notre Dame, Ind. B. S. LEMENT, Associate Member AIME, is on the Research Staff, Department of Metallurgy, Massachusetts Institute of Technology, Cambridge, Mass. Discussion on this paper, TP 3123E, may be sent, 2 copies, to AIME by Dec. 1, 1951. Manuscript, April 16, 1951. Detroit Meeting, October 1951. This paper represents part of a thesis by S. C. Das Gupta submitted in partial fulfillment of requirements for the degree of Doctor of Philosophy in Metallurgy to the University of Notre Dame. to transform at room temperature although at a decreasing rate. Since only a small amount of austenite transforms in this fashion, isothermal formation of martensite was considered to be merely a "tailing off" effect of the main hardening reaction. Another point of view was advanced by Kurd-jumov and Maksimova"&apos; * who reported that the austenite-martensite reaction could be suppressed by rapid cooling of a 6 pct Mn-0.6 pct C steel in liquid nitrogen and that as much as 25 pct martensite could be formed by reheating to and holding at subzero temperatures above that of liquid nitrogen. These investigators came to the conclusion that martensite is thermally nucleated at certain special regions in the austenite and subsequently grows to observable dimensions. Isothermal transformation of austenite to martensite was cited by Fisher, Hollomon, and Turnbull" as evidence supporting another nucleation and growth theory of martensite formation. According

Jan 1, 1952

By E. C. W. Perryman

The recovery and recrystallization characteristics of superpurity aluminum have been investigated using electrical resistivity, X-ray line breadth, and hardness measurements for the former and the micrographic method for the latter. The three different properties recover at different rates and have different activation energies. The recrystallization results agree well with Avrami&apos;s theory and furthermore indicate that the perfect subgrains formed during recovery are not the nuclei for re-crystallization. WHEN a metal is plastically deformed, its physical and mechanical properties generally undergo considerable changes and by subsequent annealing these changes are partly or wholly annihilated. Thus, a recovery process can be discussed, taking this term in its general sense. In practice, however, there is reason to discriminate between two apparently different processes, one most easily followed at low temperatures, in which the properties return to an almost constant value between that of the cold worked and fully annealed material, and a second process in which the properties return to their original values before cold working and which is accompanied by the formation and growth of new grains having an orientation different from that of the matrix. In this paper the word recovery will be taken to mean the changes in some property as a function of annealing time which occur either without the appearance of new grains or under conditions such that the new re-crystallized grains are very small (= 2 microns), are very few in number, and substantially do not affect the property being measured. This definition is rather abitrary, for it will depend upon the sensitivity of the technique used for the observation of new recrystallized grains, which in the present work was about 1 to 2 microns. However, it is helpful to use the term recovery in this sense and to reserve the term recrystallization for the processes of nucle-ation and growth of new grains in the cold worked matrix. Although considerable work has been done on recovery and recrystallization, most workers have based their study on the measurement of one or perhaps two parameters. Since very small amounts of impurities have such a profound effect on the recrystallization characteristics of a pure metal, it becomes extremely difficult to correlate one piece of work with another. With this in mind, the present work on recovery and recrystallization was done on the same material. Experimental Procedure Material Used and Fabrication: The composition of the superpurity aluminum used throughout this investigation was 0.002 pct Cu, 0.003 pct Fe, 0.003 pct Si, and <0.001 pct Mg. The ingot was hot rolled to 0.250 in., annealed, and cold rolled to 0.034 in. A large number of reductions and intermediate anneals were carried out so as to produce material with a minimum of preferred orientation and maximum homogeneity. For the recovery part of the investigation, the final cold reduction was 20 and 80 pct and for the recrystallization part, 20 pct. After each pass in the cold rolling process, the material was quenched in cold water in order to keep the rolling temperature as near room temperature as possible. Annealing Procedure: For the recrystallization work, specimens 1x1 in. were cut from the 0.034 in. cold rolled sheet and a hole was drilled in each through which a wire was threaded to support it in the salt bath. The temperature of the salt bath was controlled to +2°C and the time taken for a specimen to reach temperature was approximately 5 sec. These 1 in. squares were then divided into three groups, one of which was given 5 min at 318°C and another 2 hr at 244°C. These treatments were such that recovery was almost complete and a well defined subgrain structure produced. Separate specimens of each group were annealed for different times at 301°, 318°, 355°, and 373°C, i.e., three specimens for each annealing time. The delay between finish of cold working and start of annealing was about 1 hr. For the recovery work, strips 0.062 in. thick were cut from the cold worked sheet, annealed, and then given the last cold rolling operation. This was done for each annealing temperature. By this means it was possible to minimize the delay between cold working and annealing. In general, all measurements were carried out within 1 hr of the last cold rolling operation. Annealing at low temperatures was done in an oil bath the temperature of which was maintained constant to +1°C. Electrical Resistivity Measurements: Strips 20x0.5x0.05 in. were machined and the electrical resistance measured using a Kelvin double bridge. Measurements were made in an oil bath maintained at 20rt0.1°C. The same specimen was used for the complete isothermal annealing curve.

Jan 1, 1956

INTRODUCTION Porphyry copper deposits have been reported from the Caribbean area by Pease (1966), Cox, et al. (1973), Guild (1974), Kesler, et al. (1975), and others. This chapter summarizes the most widely known characteristics of those deposits. Only one deposit that conceivably can be classed as a porphyry copper occurrence is in production (Pueblo Viejo, Dominican Republic), but others are known whose tonnage and grade are of economic interest. Deposits in this province may be classified as copper-gold or copper-molybdenum types (Kesler, 1972), but deposits associated with quartz-rich plutons that have high Na2O:K2O and high gold:copper but low molybdenum: copper ratios dominate. Porphyry copper occurrences are reported in the literature from Puerto Rico, Haiti, the Dominican Republic, Jamaica, and Cuba. Only the porphyry copper deposits from Puerto Rico are extensively described in the literature; consequently the Caribbean porphyry copper province in general is not as well documented as the southern Cordilleran orogen. Because past published technical descriptions are incomplete, some data presented here are new to the literature. The Caribbean includes the island arcs between North and South America. Porphyry copper occurrences are known from the Greater Antilles, the generally east-west trending group of islands that lies south of North America. Fig. 48, therefore, only covers the Greater Antilles portion of the Caribbean. Porphyry copper deposits in this area are not described by the Lowell and Guilbert (1970) model in details of metallization (general paucity of molybdenum), alteration (scarcity of orthoclase), or petrography (preponderance of quartz diorite). Therefore, this model should be modified to include deposits associated with quartz-bearing plutons such as those found in the Caribbean. In the Meme deposit on Haiti ore occurs in skarn adjacent to the quartz diorite phase of a composite quartz monzonite-granodio-rite-quartz diorite pluton (Kesler, 1968). This deposit, with a K-Ar 66 m.y. date, is not included in Fig. 48 as a porphyry copper deposit because metallization is restricted largely to the intruded rocks. Although the intrusive rocks at the Meme deposit may contain sulfide near skarn contacts they are otherwise essentially unaltered. Porphyry molybdenum deposits as defined by Clarke (1972) have not been reported in the Caribbean area.

Jan 1, 1978

By J. Holms Pollok

The determination of specific gravity dates from such antiquity, and the various published methods of determining it are so numerous, that one may well be skeptical as to the value of a new means of obtaining so well-known a quantity. I make no claim to any great novelty for the little device here described, the principles, though not the convenient details, of which are more or less embodied in the publications of Mr.

Jan 1, 1900

By T. Sterry Hunt

The deposit of rock-salt which is known to exist along the eastern shore of Lake Huron, in the province of Ontario, has lately been more completely explored than before, by a boring with a diamond drill, put down by Henry Attrill, Esq., of New York City, and the results obtained are so important in every way that I make no apology for presenting them to the Institute of Mining Engineers. I may be permitted to preface an account of this remarkable exploration, and of its results, with a historical sketch of the discovery and development of this salt-region. It was in December, 1865, that a boring was begun near the town of Goderich, in the hope of finding petroleum. In this the adventurers were disappointed, but, after passing through about 800 feet of limestone, they encountered a series of variegated marls, in which, at a, depth of 964 feet from the surface, a bed of rock-salt, 30 feet in thickness, was met with in May, 1866. The boring was carried to a depth of 1010 feet, ending in hard rock, and yielded, by pumping, a very pure saturated brine when examined by me in August of the same year. In the report of the Geological Survey of Canada for 1863-66, published early in 1867, I described this salt-well, with many geological details, and gave an analysis of the brine. In the next three years a considerable number of wells was sunk in and around Goderich, and numerous trials were made in various other parts of the region. Salt was found at Kincardine, thirty miles north-northeast from Goderich, at a depth of about 900 feet, and also at Clinton, thirteen miles southeast, at 1180 feet. Records of these wells, with analyses of the brine from them, were given by myself in a subsequent report of the Geological Survey, 1866-69, published in 1870 (pp. 211-244), together with accounts of various unsuccessful borings in the neighborhood, analyses of the brines from the various wells (including one analysis by Dr. Goessmann), with many details of the salt-manufacture at Goderich, at Syracuse, New York, and at Saginaw, Michigan. The geological character of the region was there discussed at length, and it was shown that the salt here occurs in the Onondaga or Salina formation, which

By T. Sterry Hunt

THE deposit of rock-salt which is known to exist along the eastern shore of Lake Huron, in the province of Ontario, has lately been more completely explored than before, by a boring with a diamond drill, put down by Henry Attrill, Esq., of New York City, and the results obtained are so important in every way that I make no apology for presenting them to the Institute of Mining Engineers. I may be permitted to preface an account of this remarkable exploration, and of its results, with a historical sketch of the discovery and development of this salt-region. It was in December, 1865, that a boring was begun near the town of Goderich, in the hope of finding petroleum. In this the adventurers were disappointed, but, after passing through about 800 feet of limestone, they encountered a series of variegated marls, in which, at a, depth of 964 feet from the surface, a bed of rock-salt, 30 feet in thickness, was met with in May, 1866. The boring was carried to a depth of 1010 feet, ending in hard rock, and yielded, by pumping, a very pure saturated brine when examined by me in August of the same year. In the report of the Geological Survey of Canada for 1863-66, published early in 1867, I described this salt-well, with many geological details, and gave an analysis of the brine. In the next three years a considerable number of wells was sunk in and around Goderich, and numerous trials were made in various other parts of the region. Salt was found at Kincardine, thirty miles north-northeast from Goderich, at a depth of about 900 feet, and also at Clinton, thirteen miles southeast, at 1180 feet. Records of these wells, with analyses of the brine from them, were given by myself in a subsequent report of the Geological Survey, 1866-69, published in 1870 (pp. 211-244), together with accounts of various unsuccessful borings in the neighborhood, analyses of the brines from the various wells (including one analysis by Dr. Goessmann), with many details of the salt-manufacture at Goderich, at Syracuse, New York, and at Saginaw, Michigan. The geological character of the region was there discussed at length, and it was shown that the salt here occurs in the Onondaga or Salina formation, which

Jan 1, 1877

By F. Lynwood Garrison

The study of the microscopic structure of the iron of car-wheels, which it is the aim of this paper to describe, was made at the suggestion of Dr. Dudley, whose paper upon the constitution of cast-irons (page 795 of the present volume) should be read in connection with this one. Although the two wheels referred to in that paper possess nearly an identical ultimate chemical composition, they possess, as Messrs. Dudley and Pease have shown, physical properties so widely different, as to make one of them nearly worthless for the purpose for which it was cast. Considering the chemical similarity, such a marked difference in strength cannot but be very striking, and goes to show how little reliance can be placed upon chemical analysis alone, if not properly interpreted. I say " not properly interpreted," because I believe that very few analyses of iron or steel are thus fairly dealt&apos; with. That an analysis may read so much of one thing and so much of another, tells us very little as to the properties of the metal; for these are determined to a large extent by the conditions and relations in which the elements are present. To the unaided eye the difference between the two wheels under consideration is not striking. The inferior one would be described as light gray, and the other as somewhat darker. Upon careful examination of an etched fragment, however, the difference in structure will be found to be very marked, as may be seen in Figs. 1 and 2 (produced from photographs by the Ives process). It is exceedingly difficult to produce a photograph giving a fair notion of the appearance of the metal under the microscope, so as to give to persons not familiar with microscopical study, a proper appreciation of what a microscopist would consider a decided difference in structure. I would, therefore, urge any one especially interested in this subject, not to depend upon the photographs of others, but to prepare and etch the specimens himself, and then examine them with a good microscope. As is well known, iron possesses the property of uniting with a number of elements, forming products which are either highly intimate mixtures of several substances, or else compounds of an indefinite character. Indeed such mixtures may be regarded as alloys, or as Matthiessen puts it, " solidified solutions of one sub

Jan 1, 1886

By Lewis Stockett

During the year 1903, a building having machinery corresponding to ail anthracite-coal breaker was erected at the town of Stockett, Cascade county, Mont., for the purpose of breaking-up and cleaning bituminous coal. The coal is mined from a vein of the Kootenai group of the Lower Cretaceous measures having the following section: The vein is nearly horizontal in position, and each bench differs in quality as shown in Table I.

Jan 1, 1905

By Howard Eavenson

IN a discussion in the Transactions of the Institute (vol. xl, page 835 et seq.) the writer gave some data about explosions of gas and dust in the coal mines of the United States, Canada, and Mexico, among which was a table showing all explosions in the countries mentioned, in which five or more fatalities occurred, which had been reported from Oct. 2, 1871, to Mar. 28, 1908. Since the elate of publication of this discussion, as opportunity has presented, this table has been extended by the addition of explosions occurring since that time, by including several explosions which occurred prior to 1871, and by adding to the list all explosions of gas or dust in which less than five fatalities occurred, this having been clone by a search through the various mine reports, partly by the author and partly by the Librarian of the United Engineering Societies, and by correspondence with mine inspection officials of the various States, to all of whom acknowledgment of assistance is made: The accompanying list, Table I, is believed to be as nearly correct as such a statement can be made, and, while only extending to Dec. 20, 1912, contains all of the data now available in reports. An analysis of Table I, showing the occurrence by months of all explosions of gas or dust, including those in which less as well as those in which more than five fatalities occurred, is given in Table II. The statements are frequently made, in technical papers, that the number of explosions, particularly the larger ones, is increasing more rapidly than the number of mines, and that the number of fatalities caused by mine explosions, particularly the more disastrous ones, is increasing faster, proportionally, than the production of coal. To investigate the correctness of these statements Table III was prepared, in which the number of accidents and fatalities is taken from Table I, using those in the United States only, on account of lack of other data for Canada and Mexico; the production is from the records of the U.S. Geological Survey, and the number of mines, from 1909, from the same source; previous to 1909, the number of mines, for the decennial periods, was furnished by the U. S. Census records.

Jan 10, 1914

General discussion on the above subject, presented at the Pittsburgh meeting, October, 1914. GEORGE S. Rice, Pittsburgh,. Pa.-Undoubtedly there is a serious problem through the juxtaposition of gas and oil wells and coal mines, not only at the present time, but possibly of far more serious import for the future. If one examines a map of the coal fields on which is superposed the oil and gas fields of the country, one finds that they overlap to a very great extent. I may say at the beginning that we have not, so far as I know, had any very large number, of accidents growing out of this situation causing loss of life. Such accidents, or rather incidents, that have occurred have all been rather potential possibilities for disasters due to the leakage of gas from wells into the adjacent coal mines. The condition has been most acute in the Fairmont district of West Virginia, and in the general coal fields southwest of Pittsburgh in Pennsylvania. The accidents which have actually occurred were summarized in Bulletin No. 65 (Oil and Gas Wells through Workable Coal Beds) issued by the U. S. Bureau of Mines, reporting the transactions of several meetings in Pittsburgh, February, 1913, of oil and gas well representives, State geologists, State mine inspectors, coal-mine operators, and representatives of the U. S. Bureau of Mines. This conference was partly brought about through a case in which the Pennsylvania State inspection department had brought suit to restrain a gas company from completing a well through a certain mine. The office of the Attorney General of Pennsylvania asked the opinion of the Bureau of Mines upon the matter; about the same time the Association of State Geologists, at its New Haven meeting, asked the Bureau to take up the problem. Accordingly, it was thought advisable to bring together the several, interests. For the most part the danger is, I think, greater in the future, than at the present time Many parts of the coal fields of Pennsylvania, in Greene County particularly, have been penetrated by numerous wells very close together, and with the present practice of having a large coal pillar around each well, has made or will make the mining of many areas difficult or pro-

Jan 4, 1915

OF what use is the federation to me and why should I support it?" is a question that has been asked by many members of the constituent societies of the F. A. E. S. during the last year; a question that is asked because the speakers do not realize what the Federated is doing or what is the field of its activities. "What is it doing for the profession and for mankind?" would be a more appropriate question, the answer to which is found in the closing chapter of Prof. Cassius J. Keyser&apos;s "Mathematical Philosophy."&apos; The chapter is entitled "Science and Engineering." Professor Keyser writes from the layman&apos;s point of view. He is looking at the profession and at engineers from the outside. We have in his thoughts the oppor-tunity that Burns sought when he wrote "Oh wad some power the giftie gie us to see oursels as ithers see us." With the permission of the author and the publisher, we quote the following paragraphs: A layman, viewing a profession from the outside, seeking thus to ascertain its proper relations to the common weal, may bring to the task a certain freedom, which, were he a member of the profession, he might have lost. "Men trained in a profession," said Prof. David Swing, "come by degrees into the profession&apos;s channel, and flow only in one direction, and always between the same banks. The master of a learned profession at last becomes its slave. He who follows faithfully any calling wears at last a soul of that call-ing&apos;s shape. You remember the death scene of the poor old schoolmaster. He had assembled the boys and girls in the winter mornings and had dismissed them winter evenings after sundown, and had done this for fifty long years. One winter morning he did not appear. Death had struck his old and feeble pulse; but, dying, his mind followed its beautiful but narrow river-bed, and his last words were: It is growing dark-the school is dismissed-let the .girls pass out first."&apos; I shall not be so much concerned with the present status of the science as with its potency and promise. Of individual engineers the ideals may be high or low, worthy or unworthy; but of engineering itself the ideal is great and mighty. It is of that ideal that I intend to speak.

Jan 9, 1922

By B. G. Zambre, G. A. Parks, J. N. Roco

Automatic controls have long been a fact of technological life. Some understanding of control systems is rapidly becoming essential to the competence of mineral engineers. Students in undergraduate mineral engineering curricula, however, should not be expected to develop proficiency in the design and interpretation of control systems. They should be provided the opportunity to absorb some of the fundamental concepts and cant of such highly specialized peripheral fields as automatic controls. The present paper describes the components of a simple, flexible and relatively inexpensive control system designed primarily for the use of students in independent study projects. The control system is based on a continuous on-stream optical analyzer analogous to commercially available systems using X-Ray fluorescence analysis. The components can be easily adapted to control other separators and separations. As described here, they have been arranged to control the magnetic separation of a magnetite bearing specular hematite from quartz to produce a quartz product of fixed hematite content using a minimum of power. The control system consists of the magnetic separator* with a vibrating feeder, † a sampler, an optical scanner, a differential amplifier, a millivolt recorder ‡ and a motor driven, metered variable DC power supply for the separator electromagnet. An optional magnet current recorder is useful. The system as arranged for closed loop control is illustrated in Fig. 1. The elements of the loop are identified in automatic control jargon in Table I. The same components can be easily adapted for use in other control modes.§.1 * A Carpco Induced Roll High Intensity Magnetic Separator (Carpco Manufacturing, Inc., Jacksonville, Fla.); modified for external magnet power supply. A Jeffrey-Traylor Vibrating Feeder Type 1B (Jeffrey Manufacturing Co., Columbus, 0.). A Beckman Laboratory Potentiometric Recorder (Beckman Instruments, Inc., 619-A) fitted with adjustable limit switches for external circuit control (Beckman Instruments, Inc.. 71980). Terminology is taken from ref. 1. CLOSED LOOP OPERATION The separation is monitored through the optical reflectivity of the tailings stream which is proportional to the hematite content, THA. The difference, A, between the measured analysis (actually a proportional voltage) and a reference analysis (also a proportional voltage) is continuously recorded. The separation is controlled through changes in the electromagnet current, I, supplied from a motor driven variable source. The two primary variables, ? and I, are linked through adjustable limit switches on the

Jan 1, 1965

By Cornelius Kelley

I HAVE been asked to discuss "What Can be Done to Revive the Mining Industry," particularly from the standpoint of the copper industry. It is impossible to consider this problem, if in fact there can be one, from an isolated position. The mining industry is but a part, although a very important one, of that exceedingly complicated machine characterized as commerce, which comprises within its operation and functions the-multitudinous activities that, combined, make up the sum total of the production, manufacture, distribution, sale and utilization of goods and products resulting from the agrarian, industrial and commercial effort of mankind. We survey a world today with its disturbed mass of humanity permeated with discontent, passions loosened by brutal combat not yet brought under control, class hatreds aroused, national prejudices in a state of stimu-lated excitement, governments for the most part enfeebled, some destroyed to their foundations, with fragile structures raised in place of those that seemed enduring, and which have disappeared. A burden of indebtedness incurred in defiance of all economic law exists, to meet the exactions of which, levies of taxation that constitute a grievous burden upon effort and industry are exacted by the needs of those nations that are most favored, while printing presses are busy manufacturing currency that either has, or approaches, a negative value among those less favored. This picture, while not pleasant, is one that should be looked at squarely and carefully appraised in estimating the immediate future. For four years the world marshalled, and exerted without stint, its combined endurance, vitality and resource in an effort of destruction, which violated no less the orderly working of physical and economic laws than it did the conventions of social and civic relations. To have imagined that without travail the orderly processes that governed the relations of mankind could at once be reestablished and begin functioning, was, as has been demonstrated, fallacious; perhaps no more so than the error that is committed today by those opportunists who fail to take cogni-zance of basic conditions which must be remedied be-fore the world can resume its progress to a universally prosperous and satisfactory condition. Please do not gather from this somewhat unpleasant recital that I regard the future with gloomy foreboding or entertain pessimistic doubts, for, emphatically, I do not.

Jan 2, 1922

H. M. BOYLSTON, Cambridge, Mass.-We should feel greatly indebted to Mr. Miller for collecting this admirable series of photographs, but I cannot quite agree with his conclusions as to their significance. He apparently concludes that these needle-like constituents which he has shown in a good many cases, in the welded material at least, are cementite; that is, as we understand it, a carbide of iron. Now there seem to be

Jan 4, 1918