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By A. Zhecheva

A commercial titanium alloy Ti-6Al-2Sn-4Zr-2Mo has been gas nitrided in this work, in pure nitrogen atmosphere in order to improve its surface properties. The nitriding was performed at two different temperatures, 950 and 1050°C, and for different periods of time. The influence of the initial surface roughness on the diffusion process and on the surface properties of this material was studied. The influence of the processing parameters of gas nitriding on the surface roughness, phase modifications and the microstructure of the nitrided layers has been analyzed using atomic force microscopy (AFM), X-ray diffraction and optical microscopy. Microhardness profiles were obtained on cross-sections of the samples after gas nitriding applying a Knoop indenter.

Jan 1, 2004

By Ken Woloschuk

??Owners?Perspective ??Owners?Challenges ??EcoNomics?Delivery Model ??Projects ??Project Outcomes ??Questions ??Balancing the triple bottom line initiative: ?shareholders expectations of economic costs and benefit; ?stakeholders expectations of social and environmental costs and benefits; ?deciding what is sustainable and which design alternatives are the most sustainable. ?? Delivering required project outcomes

May 1, 2008

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By Z. Bibak, S. Banisi, A. Ghasemi, E. Nematollahi

"The major importance of liners in grinding is their role in providing an appropriate trajectory for the charge. Since it is not possible to study the charge movement by direct observation in operating industrial mills, this task is accomplished by physical (laboratory), and/or, mathematical (software) methods. Because of the high cost and a longer time required for a physical analysis, mathematical simulations have become more common. Simulation of the effect of liner shape on the charge movement has provided a means to select a proper design based on the operational objectives and conditions. Furthermore, the liner shape changes due to wear and impact during operation, which will influence the charge trajectory. This adds more of an incentive to use simulation. These changes in liner could be predicted through liner profile measurements during operation and/or simulation. In this research, an inhouse developed DEM software called KMPCDEM © was used to simulate the charge movement in industrial plant SAG mills. A geometrical method of implementing the shell liners on SAG mills at the Sarcheshmeh (9.75×4.87 m) and the Gole-E-Ghohar (9×2.05 m) operations facilitated the software simulation. Point by point implementation of the measurements of liner profiles of these mills enabled the study to trend the change in the charge movement as the liners wear. Comparison of the simulation to a laboratory mill (1 m diameter) showed that the difference between the measured and predicted charge impact point, shoulder angle and toe angle were 6, 4 and 3°, respectively. INTRODUCTIONComminution is the most energy intensive operation constituting the major portion of operating and capital costs of a mineral processing plant. In the last decade, a vast number of research was aimed at studying various aspects of grinding with the aim of performance improvements (Davis, 1919; Mishra & Rajamani, 1990; kalala, Breetzke, & Moys, 2008). Mill liners transfer the input power to the charge and play a significant role in affecting the motion of the charge (Mclvor, 1983; Mishra & Rajamani, 1990; Radziszewski, 1997; Van Nierop, Glover, Hinde, & Moys, 2001; kalala et al., 2008). Lifters are usually used with mill liners to extend their life and to enhance the grinding and impact breakage efficiency. Mill lifters are used to raise the grinding media and ore to transfer the energy from the mill to the load (Rezaeizadeh, Fooladi, Powell, & Weerasekara, 2010)."

Jan 1, 2016

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By A. Probst, J. A. Finch

"Solids concentration (weight % solids) profiles and the clear liquid/slurry interface level (mud-line) were determined from conductivity measurements in thickeners at Falconbridge&apos;s Strathcona mill (Ni concentrate and non-mag thickeners) and Kidd Creek Division (Cu, Zn concentrates and final tails in the concentrator and a jarosite thickener in the Zn plant).The conductivity measurement system consisted of a probe 1.5 m in length with 23 electrode cells, a 24-channel relay, a conductivity meter and a computer. A conductivity profile is collected which locates the mud-line by a sharp change in conductivity. The conductivity measurements are readily converted to solids concentration profiles using a model due to Maxwell.The results from conductivity measurements were compared with direct measurements on local samples obtained using a modified Noranda sampler.It is concluded that the conductivity technique is applicable to locate the mud-line and to estimate the solids concentration profiles in thickeners. This on-line informnation could improve the operational efficiency of industrial thickeners."

Jan 1, 1994

By Yongqiang Liu

Background For refractory gold ores with high carbonate contents ! Acid pressure oxidation ! High acid consumption (if low sulfur content) ! Low oxidation efficiency due to CO2 in autoclave ! Problems with slimy precipitates (gypsum, etc.) ! Alkaline pressure oxidation ! Difficulty in fixing arsenic ! Low gold dissolution due to iron hydroxides/oxides coating ! High reagent costs Summary ! Carbonate and sulfide minerals had similar floatability across the pH range tested (5 - 12) using sodium oleate as a collector; ! Thioglycollic acid or citric acid depressed the flotation of pyrite but could not depress chalcopyrite when used alone; ! Combination of thioglycollic acid and citric acid had a much stronger depressive effect, and the mixture depressed chalcopyrite as well as pyrite between pH 8 and 11 without affecting the flotation of calcite and dolomite; ! Calcite could be separated from chalcopyrite and pyrite; dolomite could be separated from pyrite but not from chalcopyrite under the tested conditions.

Apr 1, 2005

By W. D. Fogwill, P. J. Clarke

"The Dawn Lake uranium deposits are located 340 km north of La Ronge, Saskatchewan, in the Athabasca Basin between the Midwest Lake and Rabbit Lake deposits. Four zones of uranium mineralization, called the ""11, 14, 11A and 11B Zones,"" lie within the Athabasca Sandstone, at the sub-Athabasca unconformity and in the basement.At Dawn Lake, approximately 100 metres of Helikian Athabasca Group clastic sediments overlie Aphebian Wollaston Group pelitic and calcareous metasediments and pegmatites. Uranium with some nickel, cobalt and copper, occurs near the sheared stratigraphic contact between calc-silicate gneiss and graphitic, pyritic pelite. The mineralization lies in an area of low magnetic susceptibility which is thought to represent a rock sequence lying stratigraphically high within the Wollaston Group. There is no obvious vertical displacement of the unconformity by faulting, despite considerable brecciation, shearing and slickensides seen in the basement rocks. This suggests horizontal displacement on steeply dipping wrench faults as the main tectonic control along the 11, 11A and 11B trend.Below the Athabasca unconformity, the Wollaston Group rocks are altered to fine-grained mixtures of clays, chlorite and silica commonly called regolith. Along the mineralized trend post-Athabasca fracturing and (or) compaction have occurred through this clay-rich alteration zone, causing the steeply-dipping primary foliation to become contorted. This ""crenulated"" horizon can reach depths of 35 metres below the unconformity and is thickest along fault zones in the calc-silicate rocks. The ""crenulite"" is a distinctive unit which at Dawn Lake is commonly found above pods of ore located deep below the unconformity.Much of the mineralization in the 11A and 11B Zones occurs above, beside and below the thickest part of the crenulated zone, although the crenulated rock itself contains negligible amounts of carbonate, pyrite and uranium. Intense vuggy alteration and collapse breccias are found in calc-silicate rocks deeper and to the west of the 11A and 11B mineralization. There are at least two ages of uranium deposition in the basement zones, shown by small bright cubes of ""pitchblende /"" overgrown and replaced by duller botryoidal ""pitchblende II. ""Sooty pitchblende and yellow secondary minerals are the result of still younger reworking.The geological setting of mineralization, along the contact between carbonate-rich calc-silicate rock and pyritic pelite, suggests that the uranium was concentrated at a pH/Eh boundary located between deeply weathered, carbonate-rich and sulphide-rich basement rocks."

Jan 1, 1986

By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By K. E. Waters, N. Brodusch, R. Gauvin, C. Teng, H. Demers

Rare earth elements play an increasingly important role in renewable energy devices and high-end electronics. In this project, the composition and morphology of REEs-bearing minerals are characterized with a field-emission scanning electron microscope at high spatial resolution and high counts rate using an X-ray silicon drift detector system. High spatial resolution imaging and energy dispersive X-ray microanalysis were applied at low and high magnification to obtain the composition of each phase in the minerals. From the standardless quantitative analysis results, the amount of REEs in each phase was measured and the relationships between those phases were identified.

Jan 1, 2014

By A. I. Gorshkov, Y. A. Bogdanov, O. Y. Bogdanova

Abstract - Detailed crystal-chemical study of iron and manganese oxides and some other minerals from low-temperature hydrothermal deposits in a newly discovered inactive mound in the TAG hydrothermal field were used to determine the precipitation sequence of mineral phases during lowtemperature processes and their post-sedimentary transformations. Particles of primary sedimentary X-ray amorphous proto-ferrihydrite with high silica content were replaced in situ by nontronite, ferrihydrite, or goethite during alteration. Ferrihydrite is the only proto-hematite phase. The transformation of the iron minerals, related to change in the physicochemical environment, is an important characteristic of low-temperature hydrothermal processes. The occurrence of hydrogenetic Fe vernadite and Mn feroxyhyte in the uppermost part of low-temperature deposits and bottom sediments near the base of the mound is evidence for cessation of low-temperature hydrothermal processes. Among the investigated mineral phases, goethite, nontronite, and hematite are stable in reduced sediments only.

Jan 1, 1999

By Robert B. Parsons

"Draft income tax amendments aimed primarily at certain carve-out arrangements prevalent in the oil and gas industry could have devastating results for long standing royally arrangements in the mining industry . Whether or not this potentially damaging effect is intended is largely beside the points-the point is that the mining industry would be well advised to become familiar with the draft amendments and make sure that the potential damage to existing and future royalty agreements is minimized.The draft amendments fail to take into account the nature of mineral royalties and app ear to reflect a lack of understanding of the characteristics of the mining industry.IntroductionOn July 19, 1985 Finance Minister Michael Wilson released draft amendments to the Income Tax Act which are intended 10 effectively thwart the use of so called “carve-out arrangements"".Unfortunately, the proposed amendments are so broad and far- reaching that countless ""innocent"" royalty arrangements in the mining industry, and in the oil and gas industry, are threatened. The potential harshness of the new rules would be compounded by the retroactive application to the amendments to longstanding royalty and similar agreements."

Jan 1, 1985

By A. A. Ruitenberg, G. Ruitenberg, J. Chandra

"The Caledonian Belt is mainly underlain by Late Precambrian and possibly Early Palaeozoic rocks, which are in part overlain by younger strata. Most of these rocks are weakly deformed, except for those in some linear . zones, which have been intensely deformed by cataclasis. Mineral deposits related to two distinct metallization episodes have been recognized. The earliest are zinccopper- lead sulphide deposits, which have been concentrated in the axial regions of late-stage cross-folds within the main cataclastic zone. The host rocks are andesitic and dacitic tuffs which show effects of intense talcose alteration, silicification and chloritization. Deposits related to the second episode are mainly composed of copper sulphides with locally abundant tennantite and tetrahedrite, which occur in brecciated and fractured carbonate-quartz veins. These veins postdate the late-stage cross-folds. VLF-EM and high-sensitivity magnetics proved to be very effective in delineating the geology of these deposits."

Jan 1, 1972

By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By A. H. Duffield

"Forming part of the Prairie Evaporites, the sylvinite layer mined at Alwinsal underlies the Blairmore quicksands and the water-bearing Devonian formations. Production is achieved by a method of trackless, continuous mining of rooms, leaving pillars for natural support. The paper describes the development of the mine, and the equipment and organization employed in the operation and maintenance of the underground facilities."

Jan 1, 1972

By T. L. Tanton

Introduction Sturgeon River area, on the east side of lake Nipigon, Ontario, was the scene of a gold rush in 1934. According to press reports, the active staking during the latter part of the summer spread out rapidly from the early holdings until it embraced practically all of the lower basin of Sturgeon river in a belt up to ten miles wide extending west from Kinghorn for 35 miles to lake Nipigon. And, before winter set in, active prospecting and claim staking reached beyond lake Nipigon to areas where belts of ancient schists were known, notably west of Obonga lake. The writer&apos;s familiarity in past years with the areas to which attention has been directed admits of some observations on means of access in the field, the general geology, and the progress that has been made in identifying formations favourable for the occurrence of gold. Canoe Routes From the writer&apos;s observations in Sturgeon River area in 1917 and in the Obonga Lake area in 1933, it is recalled that there is, locally, a striking dif~ ference in the accessibility of the two areas by travel along canoe routes. Sturgeon River area is easily accessible from Kinghorn or Jellicoe stations on the Canadian National railways. Many small lakes, commonly of the linear type and with elongations east and west, occur among the forested rocky ridges near Jellicoe (Figure 1) and to the east and west along, or adjacent to, Sturgeon river. This stream has long stretches with gentle current between the falls and rapids. The drainage system provides excellent canoe routes (Figure 2), and the interruptions to travel (Figure 3) are remembered .as scenic features that were passed by portages with firm footing. West of Obonga lake, the streams flowing easterly to lake Nipigon may be followed through scenic canyons to a plateau of law relief characterized by extensive muskegs and shallow, brown-water lakes; and along small streams, where beaver dams have been destroyed, there are muck ponds where the usual alternatives of paddling or portaging can be dismissed in favour of the &apos;moosing&apos; method of progress with the canoe (Figure 4).

Jan 1, 1935

By B. D. H. Knights, M. A. W. Bryson

Flotation of PGM ores, specifically UG-2, presents a number of technical challenges. These centre on the prevalence of chromite. Subject to over-grinding, chromite is primarily recovered to the flotation product through entrainment. This is of unique concern as it must be kept below a threshold for downstream smelting, with significant operational and monetary penalties being imposed should it exceed this concentration. A number of strategies have been developed to maximise PGM recovery in the presence of this unwanted contaminant. Specialised flowsheets form a vital basis and advanced control algorithms further enhance PGM recovery while minimising the recovery of chromite. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists of CIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By G. R. Guillet

Salt is restricted to five major beds in south western Ontario, totalling as much as 200 m in thickness. These beds are located at depths ranging from 270 m to 750 m below the surface, fringing Lake Huron and the Detroit River from Windsor to Kincardine, and extending inland as far as London. Manitoulin Island, the Bruce Peninsula and the north part of the Niagara Escarpment form the northeastern rim of the Michigan Basin, a major structural depression in which the salt was deposited 400 million years ago when much of North America was covered by the Silurian sea. Salt is mined underground at Windsor and Goderich; it is also brought to surface as brine through deep wells at Windsor, Samia and Goderich. Artificially- created caverns in salt beds are extensively used for storage of liquid hydrocarbons at Windsor and Samia.

Jan 1, 1984

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016