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By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By R. C. Hartviksen, B. H. Boyum

"The Sherman Mine, Temagami, Ontario, is an iron ore pellet operation rated at one million tons per year capacity. Mining is done from three open pits in two bands of Keewatin iron-formation intercalated in a 'greenstone belt' thought to be part of the Archean 'Abitibi Belt'. The bands of iron-formation are tabular and steeply dipping, averaging 75 degrees. The principal ore mineral is magnetite.Blast holes, 1214 inches in diameter, are drilled on 28-foot centers, each hole being sampled and assayed for both total iron and magnetic iron. Concentration tests are made in the laboratory to determine the anticipated concentrate grade. Two classes of ore are recognized -'liberating' or 'refractory'. Blending is done on iron con-.tent, degree of ease of liberation (i.e. grain size) and chunkiness. The latter is important, as primary milling is done in autogenous mills. Actual daily mill results are compared with predicted grade from blast holes, exploration diamond drill holes and pit inspection. Hourly mill samples are analyzed by the X-Ray Fluorescent Analyzer, with emphasis on silica grade. In 1969, the pellet grade was improved from 7 .01 per cent silica natural to 5.50 per cent silica natural."

Jan 1, 1970

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By Robert B. Parsons

"For the fourth time in five years, residents of northern Canada have seen a change in the tax treatment of housing and travel costs. The latest changes announced in December 1990 by the Minister of Finance are to become effective in 1991. When will the tinkering stop?IntroductionFor man y years prior to 1987, certain travel and housing allowances received by employees in remote areas were generally considered by Revenue Canada to be tax-free, even though some observers suspected that such generous treatment was contrary to the provisions of the tax legislation. In the mid-eighties, Revenue Canada decided to reconsider the tax treatment of the mining industry's long standing practice of providing housing and travel assistance to these employees. The tax- free treatment was continued by virtue of annual remission orders, but only pending the enactment of legislation which would tackle the issue head-on and layout the rules in black and white to be seen by all. The sequence of events since then may be chronicled as follows:February 26, 1986-Finance Minister Wilson's budget present s the framework for the future tax treatment of travel and housing benefits provided to residents in remote regions of Canada.December 22, 1986-The Minister of Finance announces detailed rules to fill in the earlier announced framework.January 1, 1987-The new tax rules come into effect.April 29, 1988-The Minister of Finance announces the establishment of a Task Force to examine the existing criteria for determining the eligibility of residents of northern and isolated areas for tax benefits.October 27, 1989-The Task Force presents its report.December 7, 1990-Finance Minister Wilson announces a new system of tax benefits for residents of Canada's northern and isolatedregions.January 1, 1991-The new rules become effective."

Jan 1, 1991

By L. Gasser, N. Bellinger, H. Awatta, A. Merati

As aircraft age, the extent of interactions between fatigue and other damage mechanisms, such as corrosion and fretting, increases. At present, however, there is no generally accepted methodology within the Aircraft Structural Integrity Program (ASIP) framework to account for the effects of these interactions on life and the residual strength of aging aircraft components. A comprehensive program is being carried out by the National Research Council Canada in collaboration with Analytical Processes/Engineered Solutions, using the Holistic Structural Integrity Process (HOLSIP) to address time and cyclic load issues. This approach predicts the evolution of a discontinuity state in a material from production to retirement. This paper summarizes the results of a study on the 2024-T3 aluminium alloy in different forms (clad and unclad), thickness, and specimen geometry. This study consisted of identifying the microstructural features associated with crack nucleation sites and relating them to the testing parameters and fatigue life. Several coupons were fabricated and fatigue-tested. The fracture surfaces were carefully examined, and the physical characteristics of the microstructural features found near the crack nucleation sites were analyzed. Effect of stress level, loading direction, coupon geometry and surface condition on the number of crack nucleation sites, and fracture origin size has been discussed. Four distinctive mechanisms were found to be responsible for crack nucleation: for unclad materials constituent particles, oxide residue, surface irregularities and for clad samples the clad layer was the sole fracture origin.

Jan 1, 2006

By Michael Bauer

Increases in productivity and improvements in mining occupational safety and health are intrinsically linked. Over the past years, the German Hard Coal Mining Industry has been able to accomplish both: an increase in coal production and, at the same time, a significantly reduction of accidents. This success has been achieved by advances in technology, better organization and investment in people. Since 1990 productivity has more than doubled, while the total number of accidents has been reduced by more than 90%. Further development started initially with the mechanisation of the winning and drivage technology. Innovative technology and standardisation of the mining equipment were one reason for the increase in productivity and reduction of the accident rate. Therefore this technical development was not only one important pillar of the TOM model explicated later but also the requirement for the successful development of the other pillars. In addition to further developing this innovative technology it was possible to realise procedural and organisational improvements. As a result, the above achievement is based on implementing the three pillars of the so-called "TOM" model (technology, organization, ?Mensch? = human). To increase safety, improve performance, raise awareness and change of employees? attitude, the following technical and organizational requirements have been introduced: ??New innovative technology and procedures, standardized techniques and better equipment. ??Measures to revise or redefine the organizational structure, processes and systems of work, which were then integrated into the company policy and procedures as a company management tool. ??Personnel measures (investment in people). These include, improving motivation and behaviour, training, communication to raise and to change awareness of safety issues. Success in Occupational Health and Safety is not an automatic or self-regulating process. It needs hard work to make improvements and it must be treated as a recurring cyclic process. As a result of the above, occupational health and safety has become a natural part of daily work in the German Hard Coal Mining Industry. This could only be achieved by the unconditional "commitment" of all managers and employees to the issues, coupled with discipline and responsible action. Further improvements towards the ultimate aim of "zero" accidents are only possible by mutual involvement in implementing the ?TOM? (technology, organization and ?Mensch? human) model.

Aug 1, 2013

By J. E. Dutrizac

Canada is currently the world's largest supplier of zinc concentrates and is also a major producer of zinc metal. This dominant position in the world's zinc market is a fairly recent circumstance and, in fact, the country's zinc industry was founded only in the early part of the twentieth century. By contrast, the American zinc industry was well established by the mid-nineteenth century, largely based on technology originally imported from the still older European practice. Initial attempts to create a viable Canadian zinc smelter were based on the traditional practice and were unsuccessful; success came only with new electrolytic technology, much of which was developed domestically. The purpose of this paper is to outline the early attempts to produce metallic zinc in Canada and to trace the gradual development of these first efforts into a viable zinc industry based on modern science and technology.

Jan 1, 1999

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By Y. Wang

In this study, homogeneous (unseeded) precipitation of nesquehonite (MgCO3.3H20) by the reaction of MgC12 with (NH4)2CO3 in supersaturated solutions at 30 °C was investigated. Factors which influence the precipitation of MgCO3.3H20, such as initial concentration, temperature, stirring speed, titration speed, equilibration time, have been studied. SEM images show that the initial concentration and titration speed have significant effect on nesquehonite's crystal morphology and particle size. In addition, stirring speed and equilibration time also have some influence on its properties. With the optimization of operating conditions, the crystals can grow up to a length of about 40µm and a width of 5µm, indicating good filtration properties. High purity nesquehonite obtained in this study was calcined to produce highly pure MgO at 800 °C as shown by XRD results. The novel process may be used to separate Mg and Li from high Mg/Li ratio brines in Qinghai, China.

Jan 1, 2007

By G. W. Poling

"Construction, equipping and planned operation of a new laboratory for engineering-teaching and research in coal and mineral processing is described. This facility will provide approximately 1860 m2 (20,000 ft. 2 ) of laboratory space with nearly half devoted to a new venture in coal preparation. Two high-bay, overhead crane-accessed areas will accommodate major unit operations for each of the ""coal"" and ""mineral"" laboratories. COAL PREPARATION FACILITIES:The coal facility provides three main functional areas:(1) Sample preparation (drying, blending, crushing, screening) and sink-float washability testing.(2) Unit operations U1igh-bay, serviced by crane).(3) Analytical laboratories.(l) Sample Preparation and Sink-Float TestingBreaking or comminution of coal will be accomplished using a rolls crusher, a hammer mill, a jaw crusher, or a pulverizer. Capacity to prepare coal at rates of up to approximately 4 tph will be provided by some of these units. Large diameter (~0.5m) baths of heavy organic liquids will be available for sink-float washability tests on coal samples of several kg. Particle sizes of up to 25 mm can be tested in these baths. Smaller scale washability tests on finer samples will be accelerated by centrifuges."

Jan 1, 1980

By B. R. Neufeld, M. G. Heximer, S. J. Roach, W. G. Van Luven, D. G. Reynolds

"Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. In the zinc plant, zinc concentrates are roasted to produce calcine, which is then processed in the leaching circuit for zinc recovery. Calcine is first dissolved at pH <2.0. This is followed by a precipitation stage using additional calcine that removes iron as a ferric hydroxide precipitate which is recycled to the lead operations. It is during this pH adjustment that impurities, notably arsenic, antimony and germanium, are co-precipitated with ferric hydroxide which is the primary removal phase for these elements. Recent processing conditions have resulted in lower iron inputs to the leaching circuit and this has resulted in insufficient co-precipitation of key impurities. This paper summarizes the influence of iron concentrations on impurity removal using laboratory and plant scale surveys, and emphasizes key specification limits for the primary iron removal circuit.INTRODUCTIONThe Sulphide Leach Plant (SLP) at Teck Metals Ltd., Trail Operations produces a zinc sulphate electrolyte from three different zinc bearing streams:1. Calcine, primarily containing zinc oxide, from the roasters2. Zinc electrolyte from the Oxide Leach Plant (OLP) is produced by leaching zinc oxide fume from the pyrometallurgical lead smelting operations3. Zinc slurry from the Zinc Pressure Leach (ZPL) autoclaveThe feed sources are blended and introduced to the iron removal process to precipitate iron in the form of a hydrolyzed iron precipitate which is recycled to the lead smelting operation. Along with iron, impurities, namely arsenic, antimony, germanium and silica, also co-precipitate; this process acts as the primary removal step for these elements. Following iron removal, the electrolyte is further processed in the zinc dust purification circuits. Cadmium and copper are removed in the cold stage circuit via zinc dust cementation, followed by cobalt cementation in the hot stage circuit."

Jan 1, 2016

By R. Bruce Graham

The formation, evolution and classification of peat bogs is discussed. Factors resulting in the internal and external morphological changes in a bog are described. The fibrous, absorptive and sterile properties of peat moss account for its widespread use in horticulture and related fields. These properties also account for its usefulness as a binder in pelletizing, as an insulating material in bat tons and in panel construction. Peat, the humijied product of peat moss is used in market gardening and sod growing. It is utilized in Europe as fuel. It is a source of activated carbon and gas. Potentially peat can be used to produce waxes, resins, tannins, cellulose, hemicellu/ ose, humic acids, lignin and hymatomelanic acid. At present other cheaper sources are available.

Jan 1, 1984

By Narasimha Mangadoddy, Balraju Vadlakonda

"Bubble size distribution, bubble rise velocity and gas and solids hold-up are the key major hydrodynamic parameters that are extensively used for column flotation design and performance evaluation. The distribution characteristics of mean gas hold-up is studied using electrical resistance tomography (ERT) coupled with pressure transducers (PT) in column flotation. The ERT technique facilitates non-invasive and nonintrusive visualization of different flow regimes even in the presence of particles in a column flotation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas hold-up and its radial distribution has been analysed for both two-phase and three phase flows. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the three-phase flow hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, are employed to explore the influence of parameters in two phase flow in column flotation. Mean gas and solids hold-up values extracted from ERT have been critically analysed for the column operating in various flow regimes. Gas hold-ups and solid hold-ups results using ERT are in very good agreement with conventional estimation and correlations obtained using pressure transmitter methods. Meanwhile, the results show that the gas hold-ups in the centre region increase constantly with an increase in the superficial gas velocity, whereas solid hold-ups distribution is very heterogeneous for high gas velocity. Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the 'inside' flow behaviour of gas –liquid–solid three phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is perhaps the most significant technological innovation in flotation machinery and its successful introduction in mineral processing plants. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker & Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena, Biswal, Das, & Reddy, 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on performance of column flotation (Finch, J.A.;Dobby, 1991). Many techniques have been developed that could be used to experimentally analyse the hydrodynamics of column flotation. Tomography techniques are well sound to investigate the hydrodynamics for process equipment. Among that, Electrical resistance tomography (ERT) has been used in various industrial investigations for visualization of the concentration profiles and characteristics of the fluid dynamics in gas–liquid two-phase systems (Wang, Dickin, & Mann, 1999; Williams, R.A; Wang, 2000). ERT is an imaging technique to analyse the internal flow behavior non-intrusively. ERT provide very useful tools for measuring and monitoring of column flotation process on line. Due to its high speed capability, low cost measurement, robust sensors, ERT is considered to be the most powerful tool among other tomography techniques such as positron emission tomography (PET), magnetic resonance imaging (MRI), optical and infrared tomography. Application of ERT has extended in process systems due to its improved speed of data acquisition, sensitivity, flexibility and noise immunity. In multiphase flow of bubble columns, gas hold-up and solid hold-up are explored by using the coupling of ERT and difference pressure method (Jin, Han, Yang, & He, 2010)."

Jan 1, 2016

By Sergio Bustos

A significant expansion project is under way at KATCO?s Torkuduk In Situ Leaching (ISL) operation to increase uranium production up to about 4000 tU/year. Higher flows and lower uranium concentration are expected in the rich solutions coming from the well fields. Therefore, extra adsorption and elution columns and modified operating conditions are required to deal with the increased demand for uranium transfer from the ISL solutions to the eluate solution, which goes to the uranium precipitation section. Resin adsorption and elution performance have been interpreted and projected by using Mac Cabe-Thiele equilibrium diagrams. The resin load, the adsorption mass transfer coefficient, the adsorption zone height and the eluate concentration have been estimated for the expected changing operating conditions associated to the future mine plan. This information has allowed to improve the present operation results and to define the main process design criteria for the expansion project.

Aug 1, 2010

By Normand Champigny

The Forces of Change ? The current business environment ? What can we expect for the future on management of physical assets ? The impact of maintenance on production costs ? What is RCM is doing is improving business performance ? The beginnings of RCM The RCM II Process ? RCM II is a structured process that involves employees in determining the best failure management tactics for systems and equipment in their operating context ? The method is an effective approach to risk and cost reduction as well as failure management

May 1, 2002

By S. Xu

Magnesium alloy AM50 is of interest to automotive cradle application because of it excellent castability and good ductility. In this work, microstructure and mechanical properties of both low pressure die cast (LPDC) and high pressure die cast (HPDC) AM50 test bars are characterized. Microstructure was examined using optical microscope, scanning electron microscope (SEM) and transmission electron microscope (TEM). Phase identifications were performed using energy dispersive x-ray spectrometer (EDS) and TEM diffraction. It has been found that LPDC produces much coarser microstructure than HPDC. At the same time, the HPDC samples are more heterogeneous in microstructure and composition close to grain boundaries. Particles with various dimensions and morphologies of two different intermetallic phases, Mg17A112 and A18Mn5, were found in all the samples. Mechanical tests were performed under conditions similar to those related to an engine cradle application. LPDC samples show lower strength but better creep resistance than HPDC mainly due to the difference in grain sizes and grain boundary microstructure between LPDC and HPDC. Creep curves are well described by the empirical Andrade equation. Tensile-compressive yield and creep asymmetries were found in AM50, i.e. better deformation resistance in tension than in compression. The average yield asymmetry ratio for all the samples is 0.87. Microstructural examinations on the samples tested in tension, compression and creep showed that the deformation mechanisms in AM50 were slip plus twining at temperatures up to 125°C. The examinations indicate the important role of twining in the asymmetry phenomenon. The creep results indicate that dynamic precipitation of the Mg17A112 phase during testing is not the mechanism directly responsible for the creep asymmetry in AM50.

Jan 1, 2004

By Y. W. Pan, Y. R. Liu

The disturbed natural rock mass tends to equilibrium state accompanying with non-equilibrium evolution process which has significant influence on the long-term stability of engineering structure. The deformation development in the non-equilibrium evolution is determined by two intrinsic processes, trend to equilibrium and damage development, which can be illustrated by evolution of excavated tunnel. Thus the creep and damage must be taken into account in study of non-equilibrium evolution process. Within Rice’s irreversible thermodynamics with internal state variable (ISV), the conjugate force function which equals to zero is a convex surface which divide the stress space into two parts, called equilibrium and nonequilibrium stress space respectively. The concept of effective stress of non-equilibrium has been proposed, in which the stress difference (d - d ) are the effective driving forces of non-equilibrium evolution process with hardening and damage effective. The formulations of inelastic strain rate and energy dissipation rate have been recast in the form of effective stresses. The inelastic complementary energy (ICE) is proposed to measure intensity of non-equilibrium evolution of material system. The specific equations of conjugated forces and kinetic equations of internal state variables are presented. The ICE and rate of energy dissipation are all calculated to be used to evaluate long-term stability of geo-engineering. The results show that rate of energy dissipation may be more convenience and flexible than ICE for internal state variable constitutive equation of rock mass.

Jan 1, 2015

By Mosquera. J.

Tailings Storage Facilities (TSFs) are vast structures that respond to site-specific characteristics, rate of production, placement techniques, and the physical and mechanical properties of tailings. As a common denominator, TSFs are in some degree vulnerable to failure due to liquefaction, poor management, slope instability and/or unusual climatic events. In practice, stability of TSFS is determined by calculating a minimum Factor of Safety (FOS) using the Limit Equilibrium Method (LEM). However, it has been proven that relying exclusively on the limit equilibrium approach is not accurate because it is basically a static method that does not take into account the stress-strain distribution and displacement experienced by the constitutive materials of a TSF. In order to overcome these limitations of the LEM, the finite element method - Shear Reduction Technique (SRT) has been used as a more reliable tool for TSFs stability assessment. This paper presents a comparative stability analysis between an upstream tailings storage facility (UTSF), and a water retention tailings dam (WRTD) under static and pseudo-static states using simplified and rigorous LEMs and the SRT. Additionally, and taking into consideration the intrinsic uncertainty of tailings properties, sensitivity and probabilistic analyses in the form of Monte Carlo Simulation (MCS) and the Point Estimate Method (PEM) are applied to determine the Probability of Failure (Pf) and Reliability Index (ß) of each TSF. It is shown that the friction angle of UTSF?s foundation and the core?s cohesion of the WRTD are the main variables that govern stability. Further analysis shows that the WRTD has a higher reliability index and a lower probability of failure than the UTSF.

Aug 1, 2013

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By A. Zhecheva

A commercial titanium alloy Ti-6Al-2Sn-4Zr-2Mo has been gas nitrided in this work, in pure nitrogen atmosphere in order to improve its surface properties. The nitriding was performed at two different temperatures, 950 and 1050°C, and for different periods of time. The influence of the initial surface roughness on the diffusion process and on the surface properties of this material was studied. The influence of the processing parameters of gas nitriding on the surface roughness, phase modifications and the microstructure of the nitrided layers has been analyzed using atomic force microscopy (AFM), X-ray diffraction and optical microscopy. Microhardness profiles were obtained on cross-sections of the samples after gas nitriding applying a Knoop indenter.

Jan 1, 2004