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By Madgwick J. C

Bacterial leaching of museum grade chalcopyrite and chalcopyrite concentrates at low sorptive relative humidities (55-91 per cent rH) was demonstrated. Optimum release rates were 13 and 27 mg/gram/100 days copper (Cu++) at 91 per cent and 80 per cent rH and 12 and 33 mg/gram/100 days iron (Fe++) at 80 per cent and 73 per cent rH for concentrate and "pure" chalcopyrite respectively. The optimum copper release rates occurred between 73 per cent - 86 per cent rH and 30-40 mM acid concentrations. Bacterial copper leaching rates were some twenty times slower for emersed copper concentrates, at low relative humidity, compared with submerged cultures. Bacterial copper solubilization was almost quantitatively inhibited above 150 mM acid levels (< pHO.8).

Jan 1, 1984

By Roach C

Exploration on the Callide Coalfield by Thiess Bros. Pty. Limited had reached the stage in mid 1976 where there was a need for a comprehensive appraisal of the coalfield geology. Exploration strategy in 1977 - 1978 was defined by the selection of the most attractive targets. All available literature, reports and plans were reviewed and borehole records assessed. The geology of the coalfield was placed in its regional setting and the genesis of the Callide Coal Measures described in a structural and sedimentological context. Their general form and extent was then examined by the technique of stratigraphic analysis through the interpolation and extrapolation of the available data. A "localized" reserve classification was drawn up and reasonable estimates of the various geological reserves produced, in terms of their reliability and depth of overburden. Quality trend maps were also produced. The resultant "base map" was virtually a summation of all the information to June, 1977, and the basis for the exploration programme in the 1977 - 1978 financial year. The technique allowed for "base maps" to be produced at almost any stage, each one a refinement of its Predecessor.

Jan 1, 1978

The Kundana underground narrow vein gold mine had a recent history of large and damaging seismic events. Following a period of seismic events on 30 July 2001, in which nine miners were temporarily entrapped at depth due to falls of ground in several parts of the decline, the mine operation was required to develop a seismic management system to mitigate seismic risk to the operation. A micro seismic systems and boundary element modelling of mine sequence highlighted large-scale footwall faults and the mining of gold bearing shear veins to be focal structures for seismic energy release between depths of 300 m to the base of mining at 650 m. The integration of seismic data, identification of geological structures and mapping of zones of failed rockmass led to the successful generation of a non linear boundary element model and a seismic hazard strategy. This enabled mine sequences to be assessed daily, monthly and periodically for potential seismic hazards and therefore assigned both economic and personnel risks for the recovery of the ore reserve at the Kundana Underground Operation.

Jan 1, 2005

Two main aspects need to be considered when analysing a potential petroleum development project. Firstly, an estimate of the recoverable reserves must be made, and in many instances, these reserves must serve as collateral to finance development if outside capital is required. Secondly, the likely production profile and cash flow has to be established, and this cash flow then must meet debt service require- ments and in addition generate the required profits. In making these crucial deter- minations, the impact on the project of a wide variety of risks has to be analysed. A computer model, which represents the project in its entirety, is a great aid in determining project viability. Such a model requires imput from geologists, engineers and economists, and interpretation of the model must also be a joint effort. Communications, and inter react ion amongst individuals and disciplines is essential if the best answers are to be obtained

Jan 1, 1983

Suppression of the explosion of the world population and the surprising increase of waste and emissions are major targets confronting mankind in this century. Recycling and waste minimisation are key words for sustainable development in a highly industrial society. The argument is really whether or not recycling done well is the solution to the environment problem for the following generation. If energy is not necessary in the recycling, all materials have to be recycled. The greatest interest among the environmental issues is the regulation of CO2 gas emission. It must be recognised that it is not possible to completely renew expended energy. Some of the recycling systems currently used are thought to increase the load on the environment rather than to be beneficial. Although metal industries have consumed tremendous amount of energy and discharged a large quantity of CO2 and solid waste, the metals have supported a high quality of life. The metal production industries such as the iron and steel industry and the non-ferrous metals industry can work well recycling of not only metals but also other materials without consuming more energy. Waste plastics, for example, are use as a reductant in a blast furnace. The role of metallurgical industry in the recycling-based society is introduced in the present paper to recognise how the metal industries can contribute recycling and waste minimisation.

Jan 1, 2002

By M B. McKevitt, W J. Shaw

The main task of grade control on a daily basis is to define the material that should be mined to a destination under various categories. This can be determined by grade, lithology, quality and blending criteria. In the case of multi-element deposits or deposits with various blending or other processing criteria the optimum selection of ore block boundaries can be quite complex. In every case the balance between ore loss and dilution must be considered when designing the ore block boundaries and this becomes a risk-based decision when using the conditional simulation model. The use of such systems allows grade control to meet specific targets, such as budget tonnages and grades and blended product specifications. Two case studies are presented: the Prominent Hill copper/gold mine and the Rapu Rapu zinc/copper mine. Mining is based on a rational grade control strategy involving a number of factors, including strong geological control, advanced geostatistical approaches, such as conditional simulation, and optimisation of the ore blocking to meet production requirements. This provides an objective, transparent and repeatable grade control strategy.

Jan 1, 2009

By C M. Hill

This paper aims to provide a brief overview of the Australian Coal Bed Methane (CBM) industry and more importantly the challenges to sustainable management of the industryÆs by-product, groundwater. In a country where water is scarce and having gone through one of the worst recorded droughts it is vital that this important industry be seen to be managing water in a responsible manner with the greatest environmental and social benefit. Benefits of the water from CBM wells can be enhanced through treatment to produce potable water for domestic or stock purposes, water for irrigation or aquaculture or lower quality or untreated water for industrial or mining purposes. Other options are re-injection of raw water or waste from the treatment processes or discharge to surface waterways. The critical change and difference between CBM projects and traditional oil and gas operations should be that where possible water is no longer disposed of via evaporation ponds with the dual legacy of waste of the water resource and an environmental contamination problem with the remaining salt and brine product.

Jan 1, 2003

By D E. Langberg, J S. J va, D R. Swinbourne

Specifications on the types and levels of impurities tolerable in metals are becoming increasingly stringent, and are pushing the limits achievable with conventional refining technologies. Particularly difficult is the removal of electrochemically noble elements with low volatilities, such as copper, from more active host metals such as lead, iron and aluminium. Electrochemical refining, utilising the ability of certain solid electrolytes to selectively transport copper or other impurity cations away from the molten host metal into a separate refining phase, may provide an answer to this problem. Numerous studies on solid electrolytes used in concentration sensors have been reported, as well as a limited number on metal refining. Oxygen anion conducting solid electrolytes have been applied to the deoxidation of copper and steel while cation conductors, eg ¯ -alumina and Nasicon materials, have been used to remove lithium and sodium from aluminium. However, solid electrolytes have yet to be applied to the removal of noble elements. The behaviour of solid electrolytes under the extreme conditions of molten metal refining is not well understood. This paper will examine the potential use of solid electrolytes to remove noble metals such as copper from active host metals such as iron. The suitability, and selection criteria of available solid electrolytes for implementation in the metal refining industry in the future will be discussed. In particular, the stability of Cusicon, a copper superionic conductor potentially suitable for use in metal refining, has been assessed and the results of the experiments are presented.

Jan 1, 2000

By B Wiggins, M Russell

Off-gas handling systems are a critical component of modern metallurgical furnaces and typically represent as much as 50 per cent of the total installed smelter capital cost. Inadequate off-gas system performance, due to insufficient exhaust flow or excess maintenance downtime, can present a serious process bottleneck and limit smelter production rate. Therefore, it is essential that the relevant performance issues are fully understood and considered in the design of these systems, particularly when combustibles produced within the furnace must be combusted or handled in the off-gas system. This paper examines the requirements, design issues, and conceptual design process for state-of-the-art postcombustion off-gas systems. The relevant design considerations of safety, environment, energy consumption, and maintenance are presented, and the relative importance of these key issues are compared and discussed. The benefits of using computational fluid dynamic (CFD) modeling in the design process at the conceptual design stage are also demonstrated. Finally, the design basis and performance of a recent Hatch-engineered system currently in operation is evaluated.

Jan 1, 2002

The known coal resources of South Australia are either of poor quality, or expensive to extract, or both. Export quality coal occurs only at great depth in the remote north of the State; the balance of the State's coal resources are suitable only for local electricity generation. Currently there is only one coal mine in the State, at Leigh Creek. This provides fuel for approximately 34% of the State's electricity generation, the balance being fuelled by natural gas. In the near future, new fuel sources must be developed to augment diminishing supplies of natural gas, and to cater for increasing demands for electricity. The South Australian Government has determined that future electricity generation will be based on the combustion of local coals. The geological and geographical environment of the known coal deposits and the quality of these coals are such that the most up to date and innovative technology must be applied to both extraction and combustion processes. The Government, the Electricity Trust of South Australia, and several Australian and overseas companies have embarked on an extensive research and development programme to ensure that these otherwise useless resources can be developed to the benefit of the State.

Jan 1, 1987

By J Mauk

Water-rock reactions such as pyrite oxidation and calcite dissolution strongly influence the pH of pit lakes that develop in open-cast mines after mine closure. The Martha Mine, located in world-class epithermal Au-Ag deposit at the southern end of the Coromandel Peninsula, New Zealand, is scheduled to close in 2007, after which the pit excavation will be rehabilitated into a recreational lake; the first pit lake in New Zealand. Mineral distribution maps from XRD results of 130 andesite samples identify regions that could produce or consume acidity in the future pit lake. Maps show pyrite, calcite, adularia, albite, illite and chlorite distribution in the wall rocks. These data identify five alteration mineral associations: potassic, propylitic, weathered, oxidised and weakly-altered. Pyrite occurs in potassic, propylitic and weathered associations, whereas calcite is restricted to propylitic association in the northeast wall. Subaerial, epilimnion, and hypolimnion exposure zones describe the physical and chemical weathering processes that are likely to occur in regions of pit wall, and the potential effects on lake water chemistry. The pH of epilimnion water will depend on the relative abundance of pyrite and calcite in the propylitic association in the northeast wall, whereas hypolimnion pH will depend upon the frequency of whole-lake circulation events that distribute dissolved oxygen to deep lake layer. In mines with diverse alteration associations, mineral distribution maps are an essential precursor for accurately estimating water-rock reactions in pit lake environments. Data may be directly incorporated into a quantitative geochemical model of future pit lake water chemistry.

Jan 1, 2002

Blasting is known to be both an important and an easily quantified cost factor in rock breaking operations. However, the indirect costs and benefits of the blasting operation are not easily determined due to the irreversibility of the mechanisms involved and the multiplicity of influencing factors. A general conceptual model showing the relationship between blasting and mining costs is well known, but serious attempts to address the critical real relationships have all floundered on the fact that not enough is yet known about either detonation physics or blasting effects. This can only be remedied to the extent that blasting instrumentation enables researchers to pin down not only the relationship between the detonation process and its impact on a particular environment, but also the downhill costs of handling the rock, repairing any damage and building in "Safety Factors" to provide for imponderables. It is vital to standaraize on specifications for instrumentation and measurement techniques and there is a need to review what has been achieved in blasting expertise so as to focus on the most fruitful paths for future work.

Jan 1, 1990

The Closure Risk model was developed as a new tool to aid decision makers in the complex area of mine closure. It uses a simple analytical technique that allows the decision maker to simplify what is often a complex mine closure process into more easily managed sub components. This systematic approach ensures that critical factors in the closure process are not overlooked. It also allows the most important issues to be highlighted. The model can also be used to produce quantitative estimates of risk by weighting and prioritising the issues to produce the Closure Risk Factor (CRF). Field trials at several mine sites in the Northern Territory of Australia in 2001 tested the model. The trials confirmed that the model has significant potential as a tool for decision-makers to assess in a structured, systematic manner, the major closure risks at individual mine sites. The risks include not only environmental impacts but safety and health, community, legal, financial, technical and other issues. The trials confirmed the value of a team-based approach and the inputs of key staff including environmental, production, mine planning, and community liaison personnel as well as mine management. Although the usefulness of the qualitative component of the model was established, it was found that, due to the influence of subjectivity, the utility of the prototype model to determine quantitative risk was of limited value. Using a continuous improvement approach, improvements to the model were sought. A refined model, incorporating the Australian Standard 4360 definition of risk and facilitated in-house risk assessment sessions was developed and tested against the data obtained in the field trial. This model, while maintaining the qualitative strengths of the original, allows more accurate absolute and relative quantitative scores to be calculated. This in turn facilitates comparisons between the issues at a single site as well as between different mines.

Jan 1, 2003

By B G. Lottermoser

Phosphate induced stabilisation has been used to create passive iron phosphate coatings on pyrite and pyrrhotite. The formation of solid phosphate coatings on sulfide grains thereby inhibits sulfide oxidation. The aims of the study were to determine whether phosphate induced stabilisation could control sulfide oxidation and metal mobility in partly oxidised, polymineralic, sulfidic mine wastes. Waste materials were obtained from the acid mine drainage generating, abandoned Montalbion silver mine site, far north Queensland, Australia. The waste consists of quartz, kaolinite/illite, sulfide minerals (galena, chalcopyrite, tetrahedrite, sphalerite, pyrite, arsenopyrite), and pre- and post-mining oxidation products (hydrated Fe, Cu, Pb and alkali mineral salts). SEM observations of waste material treated with potassium orthophosphate showed that metal, metal-alkali and alkali phosphate coatings developed on all sulfides (with the exception of tetrahedrite). The abundance of phosphate phases was dependant on the availability of cations in solution for complexation with the phosphate anion. In turn, the release of cations was dependent on sulfide oxidation or the dissolution of efflorescent mineral salts. Experiments aiming to dissolve these phosphate coatings û using a strongly oxidising solution û showed that the phosphate coatings remained stable, preventing acid generation and metal release. The results of this study demonstrate that liquid phosphate stabilisers can suppress sulfide oxidation and immobilise metals in partly oxidised, polymineralic mine wastes.

Jan 1, 2003

Exploration risk increases with time, due to a general decrease in prospectivity as the more accessible deposits are found, and be- cause of rising costs and demands due to an improving standard of living. Risk is separated into financial risk, which increases sharply at the development stage, and the risk of failure which is at its peak at the outset of exploration. Risk is also divided into internal and external factors; some of the latter cannot be offset, viz. the systematic overall risk for any enterprise. The recently emergent risk embodied in withdrawal of large areas from exploration access is discussed. An appeal is made for objective multiple land-use policies to be applied so that land remains available at reasonable cost and with appropriate environ- mental safeguard conditions. Risks specific to gold exploration are discussed. As gold now accounts for over 50% of all mineral exploration, and most other metals are depressed, any sharp decline in gold will have grave effects on the ex- ploration industry. Gold exploration will become more difficult and expensive in about five years, after most of the readily accessible deposits in Australia are found. Government's role is important in pro- viding stability and basic data at reasonable cost. Exploration for specific minerals or of particular areas could be stimulated by extending the 150%.tax deductibility of R & D to aspects of exploration of strategic im- portance, particularly in the event of a downturn. Exploration is classic scientific research, at least through to the proving Stages.

Jan 1, 1987

Prior to 1975, most geochemical drainage surveys for gold were based on analyses for pathfinder elements, such as As and Cu, rather than direct analysis for gold, for two reasons. Firstly, analytical methods lacked the required sensitivity and precision to determine gold abundance at background levels in stream sediments (usually in the range 1 - 10 ppb). Direct analysis was also inhibited by concern about the potential for gross sampling error, brought about by the dispersion of gold as rare discrete particles of the extremely dense native metal. This sampling error, commonly termed the 'nugget effect' has two components: erratic distribution of the element within the stream environment, related to hydraulic factors, and the difficulty in taking representative samples, both in the field and later in sub-sampling for analysis. In more recent years the collection of very large samples was commonly advocated to overcome the sampling problem (Hams, 1982; Nichol, 1986).Two methods have been widely used to evaluate the gold content of bulk samples (Elliott and Towsey, 1989). The preparation and analysis of heavy mineral concentrates has in recent years been largely superseded by the leaching of gold contained in bulk samples by cyanide, commonly termed the BLEG (Bulk Leach Extractable Gold) or BCL (Bulk Cyanide Leach) methods. The terms BLEG and BCL are essentially interchangeable and the latter will be adopted for the remainder of this paper. The strengths and weaknesses of these two techniques were compared with conventional total gold analysis on fine fraction (

Jan 1, 1976

By A B. Richards

Time window analysis that limits the explosive mass fired within a specified time window (commonly eight milliseconds) has been used for many years in blast design by explosives engineers. Despite several warnings in the past that this technique has limited practical or scientific basis and, in many cases, does not effectively control vibration, almost every textbook and blasting manual refers to time window charge mass limits as a primary vibration control technique. It has become entrenched in some blast vibration management plans, despite being inappropriate for the particular situation. With the flexible initiation timing available with electronic detonation almost a practical reality, and the 8 ms constraints in-built into the signal tube initiation system thereby lifted, it is timely to review the significance of the 8 ms time window in controlling blast vibration. This paper re-visits the original research that led to the development of the 8 ms criteria and the non-supportive conclusion of the original researcher. Because airblast was not measured, the 8 ms time window was never intended to be applicable for airblast control. Examples of blast designs are given in this paper that comply with the 8 ms time window limit that result in substantially increased air and ground vibration, together with examples of blast design that does not satisfy time window considerations, which results in reduced air and ground vibration. Techniques that identify wavefront reinforcement, due to the combined effect of drilling pattern and delay sequence, can assist explosives engineers to avoid high blast vibration situations that result from the inappropriate application of time window techniques and other adverse delay combinations.

Jan 1, 2003

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

The explosion of a charge in a drillhole sets the surrounding rock mass into vibrating stress wave motion. Except in the immediate vicinity of the drillhole, the dynamic stresses associated with this motion do damage only to pre-existing joints, cracks, or other weak planes, not to the rock material in between these. The joints are weak in tension, therefore the damage occurs as a result of tensile stresses. The initial damage process in the rock mass that ultimately breaks loose in front of the hole is similar to that in the remaining rock behind the drillhole. Recorded or calculated values of the vibration velocity and frequency contain a wealth of information about the combination of stress and strain that causes the damage. This paper outlines a new technique by which the peak strain energy derived from measured or calculated vibration velocity records is used to determine the local fragment size distribution. It combines two previously known and well tested techniques, namely the Holmberg-Persson calculation of the peak vibration velocity generated by an extended charge and King's calculations of the fragment size distribution as a function of the strain energy in rock crushing. Both of these calculations are based on experimental data and have been tested and found to agree well with actual conditions in their respective fields. Holmberg-Persson's calculated peak vibration velocities have been used successfully to predict and control damage to the remaining rock in cautious blasting, while King's calculation successfully describes the comminution of rock in mechanical crushing. Preliminary predictions of fragmentation in two types of rock blasting, a large hole open pit mining blast and a tunnel round, indicate that the new technique for fragmentation prediction has the potential for predicting fragment size distributions within the rock removed by the Blast.

Jan 1, 1995

By D R. van der Meulen, P Ande, D J. Lunt

Pressure hydrometallurgy is becoming an increasingly common unit operation in the treatment of gold and base metal ores and concentrates. The design of an adequate and appropriate pilot-scale testwork program is, therefore, essential in order to minimise the risks associated with developing a project in which autoclaves form a key part of the operation. This paper identifies the approaches that have been taken in the piloting of oxidative and pressure acid leach operations. Particular emphasis is placed on the determination of scale-up ratios between the pilot and commercial plants and the pilot-plant run durations. The issues, both metallurgical and project-specific, that can impact these key parameters are reviewed.

Jan 1, 2004