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By S. G. Malghan, D. Santhiya, S. Subramanian, K. A. Natarajan

The adsorption of poly(vinyl alcohol) (PVA) of molecular weight 25,000 onto alumina was studied as a function of pH. The adsorption isotherms were also determined. The adsorption density increases with increasing pH, while the isotherms are rounded and of the low affinity type. Electrokinetic studies indicate that the electrophoretic mobilities are reduced in magnitude in proportion to the PVA concentration, without any shift in isoelectric-point (iep). This resembles the influence of an indifferent electrolyte. The calculated values of the free energy of adsorption between alumina and PVA are suggestive of hydrogen bonding. FTIR spectro-scopic data provide additional evidence in support of hydrogen bonding.

Jan 1, 2000

By Paul M. Godlewski, Roberto J. Guardia

Hundreds of highway and rail transportation tunnels in North America have been rehabilitated in the last two decades. Tunnel rehabilitation is usually dictated by an owner’s need to extend the working life of the structure, but typically has the added benefit of increasing capacity (greater speed or increased clearance) and enhancing safety. Not only has rehabilitation proven to be an economical alternative to new tunneling, but it can be safely accomplished by working during short work “windows” without taking the tunnel out of service. This paper presents methodology for planning and designing of tunnel rehabilitation projects, and case histories illustrate successful excavation and support technologies.

Jan 1, 2003

By Les T. Zoschke

Over ten years ago, Modular began development and implementation of its DISPATCH System for haulage optimization in open pit mines and now has over two dozen systems in operation worldwide. The so-called 'top down' approach used in system design and implementation was deliberate. This foresight now allows addition of features which would otherwise prove infeasible - without complete system redesign. Until recently, truck and shovel operator input provided timing data needed for optimal allocation. Now, addition of a high-speed, general purpose token ring loop controller and infrared (IR) transponders to each piece of mining equipment automates these important functions. Here, we discuss new devices, systems, and subsystems comprising mining's future.

Jan 1, 1992

By O. A. Paulson, D. D. Runnells, D. P. Dupon, K. J. Bruxvoort

Background groundwater quality is often used to drive remediation programs at sites with waters that have been affected by mining activities. In the past, these levels were sometimes chosen without rigorous statistical and geochemical analysis. A probability-distribution approach was used at the Sweetwater Uranium Project to separate a large set of geochemical data into populations that represent contribu¬tions from different sources. Natural background populations were identified for major ions, metals and radionuclides, and these were submitted to the US Nuclear Regulatory Commis¬sion (NRC) to modify the extent of a corrective-action pro¬gram and to establish control limits for future monitoring.

Jan 1, 2000

By Joseph C. Hirschi

Mine engineers have been interested in building models that simulate mining operations since computers were introduced to the industry in the 1960s. Computer models enable operational scenarios to be evaluated without the need for actual field experimentation. Virginia Tech’s FACESIM and CONSIM, Penn State’s UGMHS, and KETRON’s CPMINE are perhaps the best known early models. Recently, SIUC has modified a Microsoft® Excel version of Virginia Tech’s Mathematical Model, calling it the SSP Model. It is used to quantify the significance of various controllable parameters. Productivity increases approaching twenty percent may be achieved where recommendations suggested by the model are applied.

Jan 1, 2005

By A. Guan, K. N. Han, J. J. Kellar, D. A. Boyles

Metal ions associated with effluent streams pose an increasing environmental problem for the mineral industry. Various techniques currently in use to combat this problem including bioremediation, chemical precipitation, and ion exchange are reviewed, and their relative advantages and disadvantages discussed. An alternative technique for metal ion removal, adsorption on surface modified alumina substrates is presented. Alumina surfaces were modified by adsorption of organofunctional silanes, and metal ion removal occurs by chelation of the ion by the adsorbed silane molecules. Experimental data is presented for the removal of cupric ions by this method and is compared to cupric ion removal by adsorption on alumina without prior surface modification.

Jan 1, 1994

By S. K. Kawatra, T. C. Rao, J. P. Barnwal, Durga D. Patil

Coal macerals differ widely in their surface properties and in their hydrophobicities. Therefore, it is necessary to study the flotation time dependence of coal macerals using varying concentrations of various frothers and collectors. In the present study, froth flotation is used to explore the possibility of segregating coal macerals based on their relative rates of flotation. Petrographic analysis of the various macerals in the concentrate were carried out, and the results are expressed in terms of the recoveries of various maceral groups and mineral matter. Results show that it is possible to recover a good volume of the reactive macerals without mach loss of calorific value.

Jan 1, 2000

By A. Maréchal

It has been shown since a few years that the problem of estimating recoverable reserves should be solved by using specialized statistical techniques : whenever the selected blocks are chosen without any other constraint than a cut-off grade criterion, the problem of estimating the corresponding tonnage-grade curve is resolved by estimating the local histogram of block grades. Two major statistical techniques are currently used by geostatisticians to estimate local histograms : the "average conditional distribution" technique (Parker, Journel, Dixon 1979) and the disjunctive kriging technique. (Matheron, 1976, Jackson, Maréchal, 1979). Both have proved to be applicable in practice, with their pros and conconcerning their practibility and versatility.

Jan 1, 1982

By V. R. Manukonda, I. Iwasaki

Selective flocculation of iron ores is extremely sensitive to the type and amount of soluble salts in pulp solutions. Chemical precipitation of alkaline earth ions combined with ultrasonic treatment deactivates their adverse effects without using any environmentally ill-defined reagents. The manner in which ultrasonic treatment affects starch adsorption on hematite, dissolution of quartz, and the selective flocculation process was investigated. Selective flocculation tests were conducted in the presence of up to 400 ppm calcium ion on a quartz-hematite mixture by precipitation as calcium carbonate, and the role that silicate ion generated by ultrasonic treatment plays in achieving the selectivity of separation is discussed.

Jan 1, 1988

By Leslie S. Rubin, John C. Roberge, Mackenzie Burnett

A self regulating helical inducer has been developed and tested for dry injection of coarse or fine solids into a hydraulic pipeline. This centrifugal pumping device has also been modified and tested for use as a boost pump in medium and long distance pipeline haulage systems. The helical inducer has been operated as an integral component of a slurry injection vehicle. This compact, low profile vehicle also includes crushing and screening components, solids feeding components, a track drive system for mobility and is run by a single operator. The helical injector and boost pump operate without speed and flow controls allowing for the practical hydraulic transport of excavated materials.

Jan 1, 1983

By James A. Pappas, Francis L. Fong, Tracy K. Lundin

The impact of environmental regulations on the quality of tunnel groundwater discharges is examined in this paper. Tunnel contractors usually depend on specialty contractors or outside consultants to deal with this issue without carefully examining their activities to minimize the production of contaminants. This approach may not be adequate given increasingly more restrictive environmental requirements. This paper surveys the general practice of the tunneling industry and attempts to identify sources of contaminants which may affect the total suspended solids, oil and grease content, and pH of the discharges. Strategies for treating the discharges are included. Field data and observations from several tunneling projects are also presented.

Jan 1, 1995

By B. P. Atkin, D. W. Brown

A handleability monitor was designed to provide a simple, rapid, on-site assessment of the whole or part consignment of a coal blend in its "as-received" condition. The monitor was evaluated at a number of coalhandling plants, which handle both metallurgical and power station coals from a variety of sources worldwide. The results can be used to predict which coals could routinely pass through a handling plant at line capacity without causing blockage or delay. Despite extensive analysis of the data, it was not possible to correlate the handleability index to the regular sample analysis of moisture, ash and size analyses of the coal blends.

Jan 1, 2002

By N. L. Anderson, R. Ramananantoandro, F. Wirnkar

Six-fold, high-resolution, compressional-wave seismic data were acquired across a coal mining property in the Meigs County study area, southeastern Ohio, with a view to differentiating the Clarion Coal Member and a truncating channel sandstone prior to longwall mining without costly drilling. The seismic technique, as is illustrated by our example data, was successfully used to map those areas where the coal is present, as well as those places where it was eroded by incising fluvial streams. Our results demonstrate that the seismic reflection method, using an engineering seismograph, can be a cost-effective way to define discontinuities associated with coal seams.

Jan 1, 1992

By Harold Stocker

INTRODUCTION This presentation is concerned with the administrative and technical capability of the Atomic Energy Control Board (AECB) to assure compliance with the individual exposure limit for radon daughters (currently 4 WLM per year). It is not concerned with the epidemiological bases for setting the exposure limit. Moreover, the intent is to show how sophisticated methodologies and advanced technologies, applied to radon daughter concentration measurements in uranium mines, convey the spirit of compliance by providing better estimates than do the historical methods. These better estimates mean that more accurate and more precise estimates of each worker's exposure are determined using these more modern methods and devices. The estimates so derived should provide more convincing evidence to an individual worker that his assigned exposure is a valid indicator of his true exposure. In addition, a perspective on the exposure estimate in relation to the exposure limit is given as further evidence that an exposure limit is not the dividing line between "safe" and "unsafe" exposures. A brief description is given of the compliance aspects of the Atomic Energy Control Regulations and of the limitations of purely statistical non-compliance procedures. Most of the emphasis of the paper will be placed on the uncertainties associated with conventional radon daughter exposure determination and the means being employed (and anticipated) to reduce these uncertainties. NON-COMPLIANCE Under current Atomic Energy Control Regulations (1978), the annual individual exposure limit for radon daughters is given without reference to the possible methods of sampling and calculation of radon daughter exposure and without any reference to possible uncertainties or their magnitudes. This is common in such statutes, the details of sampling, calculation, error analysis, and so on, being left for licence conditions or provided as a specific guideline to the licensee on the matter of compliance with the Regulation. Since the exposure limit is contained in the Regulations, compliance with it is absolute, as with any other law. In Canada, a state of non-compliance with the radon daughter exposure limit exists when an exposure (attributed to an employee) is reported by the licensee to exceed the limit. No uncertainty in the measurements or in the overall determination of exposure is reported nor is any requested. Removal of the worker and the loss of his services are the immediate and direct penalty suffered by the licensee for failure to maintain the exposure at, or below, the limit. A worker may be re-instated to employment for the balance of the reporting period only if the licensee can assure the AECB that further significant exposure to the worker will not ensue. In other jurisdictions, such as the United States, non-compliance is defined on a statistical basis. For example, NIOSH, the National Institute for Occupational Safety and Health presents procedures for calculating the 95% Lower Confidence Limit (LCL) in order to "compare the results of occupational environmental sampling to an occupational health standard and make a decision with a known chance of making an incorrect decision that a state of non-compliance exists" (Leidel and Busch, 1975). (In the nomenclature of this presentation, exposure limit would be used in place of "standard", in the NIOSH sense). Furthermore, it is emphasized in the NIOSH document that such numerical comparisons "are necessary only if the sample mean is greater than the standard". The NIOSH document points out, quite correctly, that the "statistical procedures presented below will not detect and do not allow for analysis of highly inaccurate results, i.e., systematic (non-random) errors or mistakes ... If a systematic error is known to exist in an instrument or analytical procedure then correct the sample mean of the data before analyzing for non-compliance". It is certainly not the purpose of this paper to criticize the sophisticated statistical approach to non-compliance as given in the NIOSH document or in similar approaches used in other jurisdictions. Rather, the purpose is to approach, with some introspection, the question of the determination of exposure by the employer for his employee and especially the employee's understanding of, and confidence in, the accuracy of the exposure determination and its relation to the exposure limit. DETERMINATION OF EXPOSURE Historically, in uranium mines, exposure to radon daughters for an individual miner

Jan 1, 1981

By N. D. Jagger, I. M. Arbuthnot

Introduction Over the last five years, a large number of small- to medium-sized carbon-in-pulp treatment plants have been built in Australia, most designed to treat between 250,000 t/a and 1.5 Mt/a of ore. Because of the limited capital resources and tight cash-flow positions of these relatively small mining companies, the primary requirement was often to get a plant built and operating in a short period of time and at minimal capital cost. Therefore, since the inclusion of both pre-leach and tailings thickeners represents an obvious and significant capital cost, most of these plants were built without thickeners or even detailed, cost-benefit analyses on their inclusion. In some cases, the increasing use of High Rate Thickeners (HRTs) in the mineral processing industries has, however, resulted in a reassessment, because of their considerably lower cost. This reassessment was triggered primarily by the need to conserve water in arid mining areas where borefields are costly to install and water is limited. With the startup and operation of these installations, the resulting significant savings in cyanide consumption has been recognized, in many situations, as a primary justification for the installation of HRTs. Solution balances Degradation of cyanide occurs in the tailings water discharge to slime dams. The degree of degradation (cyanide loss) in the water recovered depends on a number of factors, but it is usually assumed to be about 90%. The most important mechanisms of CN loss are through HCN losses and oxidation by oxygen in the air, which also assists in the hydrolysis of CN. These mechanisms are supported by the large dam surface area and the long retention time of the tailings water in the dam. By thickening the CIP tailings at the plant and recovering as much tailings water as immediately possible, these losses are avoided. The retention time in an HRT is less than three hours, and the surface area is relatively small. Therefore, CN losses are negligible, which is not necessarily the case in conventionally-sized thickeners. Fig. I shows a block diagram of a 100-t/h gold plant without a thickener. In this example, 50% of the tailings water pumped to the tailings dam is recovered, and the CN concentration of the returned water is 10% of the tailings CN concentration of 150 ppm. Fig. 2 represents a plant with an HRT on tailings, thickening to 55% w/w solids. In this case, the thickened tailings are pumped to the dam, and 25% of the contained water is recovered. The recovered water and the mill make-up water are not sent directly to the mill; instead, they are added to the thickener feed and mixed with it prior to thickening. By doing this, the tailings are effectively washed, and the additional cyanide is recovered. Solution balances over these two circuits show cyanide recoveries of 5% and 65%, respectively. Thus, the thickener use increases cyanide recovery by 60%. Fig. 3 shows a two-stage HRT circuit in a countercurrent decantation (CCD) configuration. In this example, an additional 13% of cyanide is recovered through the use of the second-stage unit. This configuration can be justified when residual cyanide levels are high. Capital and operating costs - Case study 1 Illustrative cost figures are based on a CIP tailings thickener installed, in early 1988, as part of Dominion Mining's treatment plant at Paddy's Flat near Meekatharra. (All costs within this paper, unless stated otherwise, are in Australian dollars.) [Assumptions: Feed rate 150 t/h Ore moisture content 5% Leach density 40% solids Underflow density 55% solids Residual cyanide in tailings 150 g/m3 Flocculant dosage 15 g/t Consumable costs: Water $ 0.40/m3 Cyanide$ 2.00/kg Flocculant$ 4.50/kg Power$ 0.12/kWh Length of tailings pipeline2,500 m Capital costs of the major items involved in the thickener installation are given below: Thickener unit, 15-m diam $ 230,000 Water return pumps 12,000 Water recirculation pumps 28,000 Feed box 5,000 Flocculant make-up system 18,000 Flocculant storage tank and dosing pumps 11,000 Piping and valves 85,000 Electrics and instruments 47,000 Civil works 29,000 Installation 69,000 Total cost$ 534,000] Savings in capital costs that can be attributed to the

Jan 1, 1993

By George P. Demopoulos, Vladimiros G. Papangelakis, Dimitrios Filippou, A. J. Monhemius, G. W. Warren, E. Peters

A new method developed for the estimation of the activity of Ht in mixed sulfate solutions is described and examples of application of this method to the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3 from 298 to 473 K are offered. The method makes use of an "extended Debye-Hiickel" type of equation that was originally put forth by Das for pure H2SO4 solutions at ambient temperature. The treatment of mixed sulfate solutions was made possible by combining that equation of Das with a speciation algorithm which calculates the abundance of all species formed. The developed method, which also takes into account ionic strength and temperature effects, was used to generate hydrogen ion activity and speciation data for all possible acid/metal sulfate pairs of the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3. Finally, under the light of the reported data, specific examples of hydrometallurgical reaction systems are analyzed in terms of thermodynamics or kinetics. In particular, the systems discussed are: hydrometallurgical precipitation of hematite, solvent extraction of Fe(III), acid leaching of zinc ferrite, and oxidation of Fe(II) to Fe(III) by O2(aq).

Jan 1, 1993

By R. Du Plessis, J. D. Miller, D. G. Kotlyar

The low potential hydrophobic state of pyrite in amyl xanthate flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at Newmont’s Lone Tree Plant in Nevada. The N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Each of these issues is being studied in detail and research progress is discussed herein.

Jan 1, 2002

By Y. Wang, K. S. E. Forssberg, A. Johansson, X. Lu

This paper presents the desulphurisation of a fine graphite powder below 80 µm by high gradient magnetic separation. The removal of pyrite (FeS2) and pyrrhotite (Fe1-xS) from the fine graphite powder was carried out with a modified version of the Sala dry HGMS with vibration assistance. In addition, a comparative study with dry and wet HGMS systems has also been performed. In order to establish the performance of the desulphurisation, a test series of varying parameters such as magnetic induction, matrix type/configuration and vibration were performed. As an equipment/process for removing sulphurous impurities from the fine graphite powder, the dry HGMS is deemed useful and comparative with the wet HGMS.

Jan 1, 2002

Nuclear power currently produces about 20% of the electricity in the US, with 104 nuclear power plants located in 31 states. The commercial US nuclear industry contributes over $4 billion annually to US workers in salaries and wages. 25,000 new jobs need to be filled in the next 5 years. There are over 30 new power plants under consideration by US utilities. The operating reactors use uranium oxide fuel enriched to about 4% U235 and fission is the process used to generate heat to form steam to drive the turbine generators. Nuclear energy is an important element in the US generation portfolio and represents the largest producer of nearly emission-free electricity. Most, if not all, of the operating plants will secure an extended 20 years of operation or more. The last plant constructed was ordered in 1978. New smaller, modular reactors are under design to provide less expensive, expandable generation options.

Jan 1, 2011

By M. D. Scott

Lornex Mining Corporation operates an open pit porphyry copper mine in the Highland Valley southwest of Kamloops with a rated capacity of 43 500 TPD (48,000 TPD). It went into production in April 1972. Its concentrator consists of two grinding and flotation circuits in parallel each composed of a 6 000 KW (8,000 HP) 9,75 m (32 foot) diameter by 4,724 m (15'-6") semi-autogenous primary mill feeding two 3 000 KW (4,000 HP) 5,029 m (16.5 foot) diameter by 7,01 m (23 foot) secondary ball mills each feeding a bank of flotation cells. ,The original tailings system picked up the tailings from the flota¬tion circuits in a concrete collection box in the mill and carried the 36% solids density by weight slurry 488 m (1,600LF) through a 1100 mm (42 inch) diameter wood stave pipeline on a .46 percent slope to three 99,06 m (325 foot) diameter center drive thickeners. From the collection box under the thickeners the tailings line con¬sisted of three sections, carrying 50% solids density slurry. The first section consisted of 1460 m (4,800 LF) of 910 mm (36 inch) asbestos cement pipe for gravity flow from the thickener under flow elevation of 1252,4 m (4,109 feet) to the first pump station at elevation 1207,6 m (3,962 feet). Eight concrete drop boxes were used to limit the maximum slope on the pipeline to 0.5 percent.

Jan 1, 1976