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By Minghao Hu, Hongbo Zhao, Jun Wang, Wenqing Qin, Rui Liao, Central South University

"In the present work, X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS) analysis and electrochemical analysis were carried out to investigate the intermediate species and electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms. For bioleaching of chalcopyrite by the sulfur oxidizing microorganism Acidithiobacillus caldus, the redox potential was always lower than the appropriate value and chalcopyrite was mainly directly oxidized to polysulfide (Sn 2-), thus resulting in low copper extraction. As for bioleaching of chalcopyrite by the iron oxidizing microorganism Leptospirillum ferriphilum, chalcopyrite was mainly directly oxidized to polysulfide at the initial stage where redox potential was lower than the appropriate value and resulted in low dissolution rate. At the middle stage where redox potential was appropriate (about 350–480 mV vs. Ag/AgCl), chalcopyrite was mainly transformed to intermediate species of Cu2S rather than polysulfide, thus resulting in high dissolution rate. At the later stage where redox potential was higher than the appropriate value, chalcopyrite was mainly directly oxidized to polysulfide which caused the later passivation of chalcopyrite. Finally, a model of electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms was provided.INTRODUCTIONBiohydrometallurgy is considered as one promising mineral processing technique in processing low grade ores due to the advantages of simplicity, low cost and eco-friendly. Chalcopyrite (CuFeS2) is the most abundant copper-bearing resource, accounting for appropriately 70% of the known reserves in the world, while is recalcitrant to bio-hydrometallurgy mainly due to the coated passivation layer (Klauber, 2008; Li, Kawashima, Li, Chandra, & Gerson, 2013). However, the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching are still uncertain. The microorganisms assisting chalcopyrite dissolution can be mainly classified into three types, including mesophilic microorganisms (e.g., Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans), moderately thermophilic microorganisms (e.g., Acidithiobacillus caldus, Sulfobacillus thermosulfidooxidans and Leptospirillum ferriphilum), and extremely thermophilic microorganisms (e.g., Metallosphaera sedula, Sulfolobus sp., Acidianus sp., and Sulfurcoccus mirabilis). Moderately thermophilic microorganisms have a better prospect in the future industrial application of chalcopyrite bio-hydrometallurgy (Olson, Brierley, & Brierley, 2003; Rohwerder, Gehrke, Kinzler, & Sand, 2003). Hence, investigating the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching by moderately thermophilic microorganisms is of important significance, which will provide essential information for promoting chalcopyrite bioleaching by moderately thermophilic microorganisms in laboratory or industrial plant."

Jan 1, 2016

By D. Berkley

"Economic and environmental constraints drive more and more industrial organizations in using energy management as one of the means for addressing these issues. The recent increase in energy price could even make energy management a matter of “survival” in some cases.Experience shows that energy management is successful when the energy is managed like a resource, i.e. continuously, systematically, and in an organized manner, not like an expense, paying the bills once a month. This requires the development and implementation of an energy management program (EMP).This paper outlines some of the barriers, keys to success, components, and approaches to a successful energy management program, plant- or corporation-wide."

Jan 1, 2005

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By C. Fortin

The subject of gold flotation has been reviewed extensively in a number of publications. The focus in most of these reviews has been on the theories of gold flotation as well as the physical and chemical effects that may impact the efficacy of the gold flotation process. It is evident that the current status of gold flotation chemistry as it is being applied in industry has not been addressed widely. It is the intent of this paper to review current gold flotation practice and how these applications tie in with the current understanding of the chemistry of gold flotation.

Jan 1, 2011

By A. Hayatdavoudi, D. Chitila, F. Boukadi

"Shale oil and gas have provided a tremendous boost to energy production in the United States even though the characteristics and behavior of shale are yet to be fully understood. Hydraulic fracturing is often applied to horizontal shale wells to stimulate production. This experiment seeks to determine effects of cyclic variable temperature, water vapor and exposure time on shale micro fracture propagation. We used 22 small Pierre shale specimens and subjected them to aforementioned conditions. Fractures developed in 19 specimens. Combination of high temperature and high water vapor generated the largest number of micro fractures on the specimen surfaces.INTRODUCTIONShale oil and gas have contributed immensely to energy independence in the United States. Most if not all shales depending on their total organic content (TOC) and their clay content bear the promise of being a source rock. For example, the Eagle Ford shale play, located in south Texas, is one of the key contributors to the recent rise in oil and gas production in the United States. Data from the U.S. Energy Information Administration (EIA), published in 2014, states that monthly oil production from Eagle Ford wells increased from 340 barrels per day (bbl/d) in January 2009 to nearly 1 million bbl/d in June 2013. Natural gas production has also increased at a similar rate over the same period, from 5.8 million cubic feet per day (MMcf/d) to nearly 4,000 MMcf/d (EIA, 2014).According to the railroad commission of Texas (RRC) 2014 published information, the Eagle Ford shale play is an important play because it produces gas and more oil than other shale plays in the United States. It is an organic-rich play with carbonate shale percentage in the 70% range in south Texas and the shale content increases moving to the northwest. High carbonate proportion renders this play brittle and suitable for hydraulic fracturing treatments."

Jan 1, 2015

By K. Nagy

To support the implementation of its integrated SHEQ Policy, Cameco has undertaken an environmental leadership initiative with the goal of moving beyond regulatory compliance and significantly reducing environmental impacts in five key areas: air emissions, treated water quality and quantity, energy use and greenhouse gas emissions, and waste generation. To ensure environmental leadership becomes routine business practice, it was necessary to integrate the initiative into Cameco?s programs and management systems at the corporate and operational levels. Operations based environmental leadership strategies and action plans have since been developed, as well as a corporate reporting system to monitor Cameco?s environmental performance.

Aug 1, 2010

By C. A. D' Odorico

The zinc pressure leaching (ZPL) plant at Teck Cominco's Trail Operations was started up in 1981 and represented the world's first commercialization of the technology. From the outset, the process was designed to operate using iron-rich Sullivan Mine zinc concentrate. When the Sullivan Mine reached the end of its life in 2002, the ZPL plant underwent a significant process change with the treatment of 100% Red Dog zinc concentrate. Through careful improvements to existing plant processes, controlled changes to plant operating parameters and a rapid adjustment to the modified process by operations personnel, the plant has been successfully converted to processing a feed of 100% Red Dog zinc concentrate. This paper discusses the challenges faced during the conversion and describes the modifications to plant operating procedures, as well as changes to plant processes.

Jan 1, 2004

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By A. A. Brant

ONE of the reasons advanced for the decline in prospecting and discovery is that, as regards surficial examination, the law of diminishing returns is becoming applicable. Fewer surficially unprospected fields remain; therefore, fewer discoveries by such means result. Much in the nature of mineral resources remains to be unearthed, but even now, and more so in the future, will discovery depend on painstaking petrographic and structural mapping, aided, where necessary, by judicious applications of all the complementary scientific knowledge and devices (e.g., thin section microscopy, geophysics, and drilling) that experience proves effective in localizing a mineral deposit even beneath drift, lake, or muskeg. It is to be expected, then, that the rate of discovery will decrease, that the cost per discovery will greatly increase, and that the work of discovery will become more and more the careful, methodical assembling of field data, conscientiously interpreted on the basis of scientific knowledge by trained, experienced operatives. In view of these trends, the status of applied geophysics to Canadian mining exploration and development work might well be reviewed. The niche which geophysics may occupy relative to geological surveying and drilling has been clarified by the last twenty years' experience. The cloud of somewhat justifiable scepticism that followed the 'geophysical promotion' period of the late 1920's has lifted. Mining, exploration, and finance companies, in open-minded fashion, are seeking sound advice as to what are the scope and limitations of the geophysical methods at present practised. The purpose of this paper and the following one is, therefore, as far as lies within the author's power, to review briefly the geophysical methods at present in practice in Canada, and, at greater length, to joint out impartially and critically their scope, merits, shortcomings, an possible future development. The treatment will be non-technical, the hope being that an accurate statement of the present status of geophysics in Canada may do much to result in a sounder, saner growth of what, in the future, shall undoubted} y prove an increasingly useful tool in exploration and development work. ?

Jan 1, 1942

By R. A. Ford

The paper outlines: methods used for the determination of wear metals in motor and transmission oils; contaminents in motor, transmission and crusher lubricating oils; and viscosity determinations. Case histories and costs are presented to illustrate the value of an oil analysis program. Introduction NORANDA MINES LIMITED (BELL COPPER DIVISION) is located on the shores of Babine Lake, approximately 450 miles north of Vancouver, British Columbia. Access to the mine is by road from Topley, B.C., about 40 miles away. When a preventive maintenance analysis program was first considered, it was obvious that if samples were to be sent out for analysis, results would not be available for at least a week, due to the distance from any commercial laboratory. The assay laboratory was asked to investigate the possibility of determining wear metals on site. A limited program was started soon after production commenced, and this has now grown to include all large mobile equipment as well as crushers and grinding mills. The laboratory also now determines viscosity, fuel dilution, dirt and abrasives, glycol and water. All these results are ready within two days. This paper will outline the methods used, data interpretation, several case histories and the benefits from such a program.

Jan 1, 1977

By C J. Coveney

This paper, after a brief introduction to the mineralization and structure in the mine area, outlines the methods now being employed for grade control at Bethlehem Copper Corporation. Sampling, subgrade drilling, blasting and the actual outlining of the ore are among the topics covered. The paper concludes with a summary of the results obtained, showing a reduction in dilution and an improvement in the grade of the copper ore going to the mill. Introduction T HE Bethlehem property is located in southern British Columbia in the Highland Valley about 30 miles southeast of the town of Ashcroft. The property is located within the Guichon batholith. The rock comprising the batholith is a massive, coarse-textured diorite, which, at Bethlehem, has been intruded by a younger quartz diorite, porphyries and breccia, referred to as the "Younger Complex." Mineralization, consisting of chalcopyrite and bornite with minor pyrite and molybdenite, occurs as disseminations, fracture fillings and coarse blebs. The ore zone lies close to the Guichon -Younger Complex contact where, prior to the development of the breccia, the rocks were shattered and jointed. Subsequent mineral

Jan 1, 1965

By Kati Tschöpe

Cathode wear has become an increasing challenge in the aluminum industry due to the use of more graphitized materials. Today, there exist no standard laboratory methods for measuring cathode wear where different commercial materials can be ranked. The typical average wear rate in an electrolysis cell is quite small. The aim of this work was to design a test method where the wear could be accelerated compared to industrial cells. It was focused on polarized tests where the cathode is exposed to electrolyte, which gives higher aluminium carbide solubility. The cathode materials were characterized by microscopy and image analysis.

Jan 1, 2011

By J. B. Kwon

For improvement in the productivity of tall building projects, table formwork is one of the main methods that have been adopted for slab formwork. Because the table formwork method is an equipment-oriented construction method, the type of lifting equipment and method of operation considerably affects the productivity and cost of the table formwork. It is also important to make an equipment input plan for completing the table formwork within the time given, according to the structural construction cycle. For performing the table formwork, a tower crane or an independent lifting system, and shifting trolleys, are required. However, if an inefficient equipment input plan is made, exorbitant cost may be incurred. Therefore, the purpose of this study is to analyze the productivity of a table formwork, considering the type and number of lifting equipment and the number of trolleys inputted, and to suggest quantitative data for making a cost-efficient equipment input plan within the construction duration given. It is expected that the results of this research will be utilized as a basis for cost-efficient equipment input planning.

Aug 1, 2013

By Luke Meers

Roadway development rates in Australian underground coal mines are failing to keep pace with modern longwall systems and are unlikely to sustain further improvements in longwall productivity into the future unless step change improvements to roadway development equipment and practices are made. Bottlenecks which limit and constrain improved production and impact the safety of operators have been identified through a series of industry surveys, with the manual installation of strata support materials, consumables delivery, coal haulage and monorail installation being highlighted as major areas to improve development performance. This paper looks at research being carried out at the University of Wollongong in designing an integrated system approach for the fully automated handling and installing of development consumables, and the systems required to support these activities. A series of hard automation manipulation devices have been demonstrated in surface trials and the results indicate that rapid roadway development can be achieved.

Aug 1, 2013

By Robert A. Bosschart, Harold O. Seigel

"Most electromagnetic methods presently used in mining exploration are of the moving source type; i.e., the primary field source is moved simultaneously and in a fixed configuration with the receiver. Of the fixed-source methods, which employ a stationary primary field and a moving receiver, the Turam method is the most effective and has marked advantages over alternative electromagnetic methods. The results are little affected by topographic relief, and a high degree of resolution can be obtained because of the constant relation between source field and investigation area. Another inherent advantage of the Turam configuration is that it provides more favourable dimensional relations. Thus, the primary field attenuates at a much lower rate than in moving-source configurations and, secondly, the method is size sensitive; i.e., conductor size affects the strength of the response, which is not the case with moving-source methods. These factors result in a considerably better potential depth penetration."

Jan 1, 1966

By John Loui Porathur

Highwall Mining has been recently introduced in India. The first Continuous Highwall Mining extraction in India started operating at Ramagundem Opencast Project-II (OC-II) of Singareni Collieries Company Ltd. (SCCL) in December 2010. A new hybrid empirical and numerical modelling approach has been devised to design web pillars for the initial Highwall Mining sites in India, considering the complex geology, such as existence of thick seams and multiple seams in close proximity. This paper gives the scientific elucidation of a comprehensive design methodology adopted for the above mentioned Indian Highwall Mining sites. The design technology includes web pillar design for multiple seams using hybrid empirical and numerical methods, slope stability assessment, ground movement monitoring, and recommendations for conducting blasting operations in the vicinity of Highwall Mining extractions.

Aug 1, 2013

By S. Parent, J. -F. Lepage, S. Glover

"Goldcorp – Eleonore’s 7 000 tonnes per day gold mill was started up in October 2014 and achieved commercial production in April 2015. During the first year, operation has faced challenges from grinding, flotation, sulfide cyanidation and tailing filtration to achieve targeted throughput, availability and recovery.The optimization of non-sulfide tails filter cloth lifetime and filter press availability had the most significant impact on ramp-up of both mill throughput and availability. A change in steel ball addition size to the grinding circuit was made to meet the targeted p80 of 65 µm. Various optimization efforts were conducted on the flotation circuit, intended to recover all sulfide-bearing minerals. The goal is to attain the environmental target of 0.12% sulfur in flotation tails (to eliminate acid mine drainage or AMD), while an average of 0.31% sulfur was obtained over the first months of 2015. Collectors, frothers, activators and hydrodynamic parameters were tested to improve the circuit desulfurization efficiency. High sulfide reactivity in pre-oxidation and cyanidation severely impacted dissolved oxygen levels and cyanide consumption. Studies were undertaken to understand the effects of mineralogy, grind size and leach conditions on gold dissolution kinetics and cyanide consumption. Efforts were focused on pre-oxidation to restore dissolved oxygen levels as well as optimizing both lead nitrate addition and pre-oxidation time.INTRODUCTIONGoldcorp Eleonore’s mill commissioning started in September 2014. It was considered to operate the mill at 3 500 tpd during design, as the mine was planning to operate at this throughput for the first year. However, with the stockpile of ore and a higher throughput from the mine, the mill was able to run at higher tonnage than initially anticipated.While increasing tonnage, a few bottlenecks were discovered and overcome in areas such as filtration and cyanide destruction. There were also recovery issues which were addressed in areas such as grind and sulfide leach. This paper focusses on the first complete year of operation ending September 30th 2015. A process description and the flowsheet are presented below and it will then go into detail about operational, metallurgical, mechanical and design issues experienced during the year."

Jan 1, 2016

By Paul Toor

The operation of SAG mills is variable over time due to their continually changing liner shape, mass and subsequent load motion. However, this tends to be poorly accommodated in liner design and mill control, with only limited compensation made for this influence, usually in the first few weeks after a new liner is installed. With ever-increasing ore competency, increasing energy costs and decreasing ore grades, simplified design and operational approaches that compromise the achievable mill efficiency are no longer adequate. This paper presents a methodology that has been developed to measure and account for the changes in mill performance as the liner wears. This involves monitoring all liner profiles ? in other words the three-dimensional liner shape - over the life of the liner, then conducting controlled surveys at different stages of the liner wear life, and correlating the mill performance to the liner profiles. The measured liner mass is modelled to provide an ongoing meaningful load mass measure that excludes the liner mass.

Jan 1, 2012

By David A. Edgecombre

This paper discusses modern practices in the extrusion of steel. Particular emphasis is given to a description of the Ugine Sejournet method of extrusion, involving the use of glass as a hot work lubricant. Other methods are also mentioned. A brief history of extrusion is presented; present practices in the quality extrusion of tubing and solids are described; and the future potentials of the) process as a tonnage producer are briefly discussed. The advantages of extrusion and the reasons for the use of a glass lubricant, as well as the various methods of using glass, are given. The process, as described, is being used in the manufacture of large commercial quantities of stainless steel tubing and sections. This extrusion process is an essential and unique means of forming such atomic-age materials as titanium, zirconium, molybdenum and other super alloys all of which are materials required in the creation of nuclear installations.

Jan 1, 1963

By Patrick E. Cavanagh

"A pilot shaft furnace was operated for one year at Steep Rock to produce special high-grade products from coarse ore, using lignite as fuel. The furnace is 10 ft in diameter and 60 ft high. When operated to heat coarse Steep Rock ore to drive off combined water and give a 64-per-cent-Fe product, the fuel consomption was 900,000 Btu's per long ton of product. The furnace was run in this way from September 1966 to January 1967 to establish the technique of feeding and discharging the furnace and controlling the gas composition and temperature. The furnace is similar in operation to a lignite water gas producer containing a large proportion of catalytic iron oxide. Steam injection is used to control the temperature. The product was tumbled in a rotary trommel to stabilize it. The resulting fines could be fed to the conventional pellet plant at Steep Rock. The furnace was next operated to make 77-per-cent-Fe metallized coarse ore. Several major modifications in de-sign were made and the furnace was successfully operated for short periods to maintain the required conditions to remove 75 per cent of the oxygen from the ore to give a 75-per-cent-reduced product at a grade of 77 per cent iron. The furnace cooling zone was operated under positive pressure, with internai alkaline water sprays to cool the charge. The product was discharged from the open bottom of the furnace without serions reoxidation. The metallized ore was magnetically separated from the discharge. Most of the charred lignite discharged along with the ore is re-cycled. Fuel requirement was 11,000,000 Btu's per long ton of product. This metallized coarse ore is intended for blast furnace feed. A short test run was carried out to establish the conditions for making a highly reduced melting stock for steel furnaces. To achieve 90 per cent reduction and over 90 per cent Fe, the furnace must be slowed down so that the production rate is about one-half the rate when making a 75-per-cent-reduced metallized product. Fuel requirement is 15,000,000 Btu's per long ton of product. The simple shaft furnace developed is similar to the top half of a blast furnace, with some major modifications to allow discharging into the open air. This Low Temperature Blast Furnace program has been technically successful and has resulted in making data available for the design of a commercial plant. Study of the commercial feasibility of large-scale production of metallized coarse ore at Steep Rock is still continuing."

Jan 1, 1968