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By V. Rastogi

Surfactant-based bactericides are able to control acid formation in sulfidic materials such as pyrite and sulfidic ores, thereby helping to abate acid rock drainage. Bactericides are used in the following two ways: as periodic or continuous spray treatments for the prevention of acidification of material actively handled and moved and in controlled-release form for reclamation. Site-specific bactericide treatments are designed for active sites and reclamation. Results from two active coal refuse sites show that acid production can be reduced by 88% or more. Results from reclaimed sites show that bactericide treatment can be more effective than the addition of alkaline materials such as limestone and can reduce acid production from 3,500 to <30 ppm. The controlled-release-pellets treatment outlasts the life of the pellets, as shown by a study of a site now 10 years old A single treatment sets up a change in site microbiology to replace acid-producing Thiobacillus ferrooxidans bacteria with heterotrophic bacteria and creates a stable site without the need for further treatments. A secondary beneficial effect of bactericides is on revegetation, and biomass from treated areas is almost 10 times that from areas not treated with bactericide. Depending on the application, bactericide treatment can be cost effective upfront and certainly long-term, compared to the perpetual water treatment that could be required, even after productive use of the site is completed

Jan 1, 1997

By J. B. Hiskey, S. Chander, B. J. Scheiner

The use of selected iron complexing agents in preventing or ameliorating acid mine drainage was investigated. The experiments were conducted in weathering columns using refuse samples from a coal cleaning plant. It was observed that the treatment with iron complexing agents significantly altered the rate of oxidation. Some of the reagents tested reduced the rate of oxidation whereas the others even enhanced it. The results showed that a commercial reagent containing oleyl imidazoline was most effective in retarding the oxidation rate. In addition, a simple treatment with this reagent substantially decreased the rate of oxidation of pyrite in a column that was generating acid at a high rate. The effect of this reagent on the surface properties of pyrite was studied by cyclic voltammetry and zeta potential measurements. The decrease in the rate of oxidation resulted from suppression of both anodic and cathodic reactions at the surface of pyrite.

Jan 1, 1993

By W. E. Foreman, A. Hayatdavoudi, A. Ghalambor

The objective of this investigation was to determine the sensitivity of three selected input parameters in the operational control of continuous bottom fed thickeners used for the treatment of coal refuse slurries. The three variable parameters were "Feed Flow Rate," "Feed pH," and "Feed Solids Concentration." These three input parameters were studied under three cationic-anionic polymeric conditions. For each polymeric condition, two mathematical models were developed, one for overflow response and the other for underflow response. The combination polymers produced the best quality of overflow and underflow. For this polymeric condition, change in the feed solids concentration was the most sensitive factor in the maintenance of the overflow quality, and the feed pH was the most sensitive factor for the maintenance of underflow quality. The mathematical models generated a set of plots that would allow an operator to control and/or adjust any of the three variables to achieve optimum conditions.

Jan 1, 1991

By H. P. Schlanger, L. Paterson, B. H. G. Brady, B. E. Hobbs

A novel principle for a waste repository, based on a backfilled thermosyphon as the functional unit, is proposed. Such a unit reduces temperatures and temperature gradients in the vicinity of a waste package and in the repository near field, reducing leach rates from packages and thermomechanical disturbance of the rock mass. Preliminary analyses confirm the mode of performance of the system, and reveal some interesting features of material transport and sealing in backfill and rock fissures. The thermosyphon combines attractively with the prospect of developing a near-field geochemical trap with chemical specificity for radionuclides. It is proposed that a thermosyphon repository may provide superior performance of engineered and natural barriers compared with conventional designs. The achievement of the ability to predict accurately the performance of the thermosyphon, relative to other isolation schemes, will represent a benchmark in the understanding of the absolute performance of any repository.

Jan 1, 1986

By S. E. Phifer

The Haile gold mine was the largest gold producer east of the Mississippi River before 1942. It was the first gold mine in the Southeast to reopen following deregulation of the gold price by the United States Government. The Haile mine was also the first gold mine in the Southeast to use heap leaching and carbon recovery for gold production. Current production involves mining and heap leaching about 1.8 kt/d (1600 stpd). Carbon is used as a recovery medium. Due to the clay and excessive fines in the oxidized ore, agglomeration using portland cement is required before leaching. Agglomerated ore ranges in screen size from 50 mm (2 in.) to less than 75 µm (200 mesh). The agglomerating step combined with certain other conditions has enabled Piedmont Mining Co. to achieve recoveries of about 90% or better.

Jan 1, 1987

During the past decade, international mining companies have descended on South America. Countries like Chile, Brazil and Peru have seen billions of dollars in exploration and development funding turn their once meager mineral industries into mining giants that have become the envy of the world. Part of this outpouring of foreign investment in those countries has been because each has privatized its state-owned mining companies and has liberalized its foreign investment laws. In addition, they have rewritten their mining codes to encourage minerals development and passed new tax laws that have made natural resource development more attractive. Now these same international mining companies are turning their attention to Argentina. This a country that, like Chile, Brazil and Peru, has a wealth of largely un- tapped mineral resources. And Argentina wants its share of the foreign investment that its neighbors have enjoyed. With that in mind, ministers of Argentina&apos;s natural resource agencies came to Denver, CO to meet with mining executives and pitch their country&apos;s mining industry. The meeting, attended by about 200 people, was sponsored by the US Trade and Development Agency and organized by the World Trade Center Denver. Others involved were the Colorado Mining Association, the Colorado International Trade Office and the Secretariat of Industry, Commerce and Mining of Argentina. The following is a summary of a report on Argentina&apos;s mining industry. It was prepared by Anderson & Schwab Management Consultants and distributed to attendees as part of the meeting&apos;s program.

Jan 1, 1998

By John A. L. Dr. Campbell, James W. Haskew, F. Hoy Lee, Elliott P. Dr. Doane

Emissions of particulates, unburned hydrocarbons, nitrogen oxides (NO[ ]) and carbon monoxide (CO) from diesel engines are of concern in mines, particularly underground mines. All these undesirable products except NOx are the result of incomplete combustion in the cylinders. Various approaches to achieving more complete combustion in diesel engines have included different fuel compositions, use of catalysts, fuel additives, engine modifications, and oxygen-enriched intake air. The present study shows that injecting minute quantities of primarily platinum group metal catalysts into the intake air of a Deutz/MWM D916-6 mine diesel engine substantially reduces emissions in the exhaust. The catalyst injection system, which was developed by National Fuelsaver Corporation (Robin. 1981), transfers catalyst compounds in solution to a stream of air bubbles by a process called Bubble Fractionation (Lemlich et al.. 1966, 1968. 1970). The amounts are so minute that concentrations in the engine exhaust should be well below OSHA/NIOSH Time Weighted Average (TWA) exposure limits at steady state, a fact that was confirmed by analysis of collected particulates in the exhaust. When the catalyst injection was used along with a pleated paper filter to remove exhaust particulates, the filter operating life was shortened greatly. Therefore, this system is not recommended for use on diesel engines equipped with a water scrubber and a filter. It does offer a practical and relatively economical way of reducing exhaust emissions from other diesel engines, such as those in outby mine service

Jan 1, 1995

By B. Rao Pothini, Julio H. Thaler, W. L. Finlay

The White Pine room-and-pillar mine started in 1955 from a suboutcrop, down gentle dips, and with a competent sandstone roof. As mining depths increased, extraction decreased 1% every 35 feet. Moreover, roofs became shaly and less competent, and regions of high fault and joint densities, sometimes with and some- times without high lateral stresses, increased the tendencies towards roof falls. Instinctive reactions towards narrower openings did not alleviate the problem. Careful consideration of rock mechanics principles culminated in the development of two variants to the conventional room-and-pillar mining system based on the concept of stress relief through load deflection. The two systems-EquiAdvance Cave, and PressureArch Panel Mining-are complementary. The objective of the former system is to provide relief from lateral stresses through advance caving and in the process also to achieve higher extraction at depth. Where surface subsidence cannot be allowed, the alternative PressureArch Panel concept is utilized to provide stress relief and moderately high extraction ratio. Both systems have been under trial for over three years and, together, produced over three million tons of copper ore. These two systems, and their production test results to date, are described.

Jan 1, 1977

By Richard H. Gates

INTRODUCTION The U. S. Army Corps of Engineers is developing chemical explosive excavation as a construction technique for use on Civil Works projects. Large chemical charges are being used in multiple charge arrays in a variety of media and topographic situations to achieve actual construction projects. The target is the development of chemical and nuclear explosive excavation as an accepted cost-competitive construction technique. Military research using explosive excavation is also being conducted to apply this technique to military engineering for combat purposes and to military construction. The information gained from both the civil and military research is integrated into the overall development of explosive excavation. This research and development work is being conducted under the auspices of the U. S. Army Engineer Waterways Experiment Station Explosive Excavation Research Laboratory (EERL) located at Livermore, California. This organization was formed in 1962 as the Nuclear Cratering Group (NCG) to carry out the Corps of Engineers (OCE) portion of a joint agreement with the Atomic Energy Commission (AEC) to develop nuclear explosives for construction purposes. The AEC, through the Plowshare Division of the Lawrence Livermore Laboratory at Livermore, California, has been responsible for developing nuclear explosives, conducting nuclear cratering experiments, developing nuclear safety information, and developing methods for predicting the shape of the craters. The Army part of the program includes corollary chemical high-explosive cratering experiments, participation in the AEC&apos;s nuclear cratering experiments, and development of

Jan 1, 1997

By J. J. Moore, B. Mishra, D. L. Olson

The production of radioactive and reactive metals, such as plutonium, uses various pyrometallurgical techniques that generate significant quantities of waste salts contaminated with hazardous, reactive or radioactive materials. Health concerns, environmental regulations and economic considerations require proper mitigation processes to recover the valuable components and for recycling or unrestricted release of these salts. The Oxygen Sparging Process converts soluble metal halides, such as chromium-, plutonium-, cerium chlorides, into insoluble oxides and/or oxychlorides which can be consolidated and separated for long-term storage or further processing. The matrix salt phase, viz. calcium and/or alkali chlorides, are clean after oxygen sparging and fit for recycling. This method has been described and its optimized parameters discussed to show that RCRA regulated elements, such as, chromium, lead, cadmium, etc. report to the consolidated phase making the salt recyclable. Salt Scrub Reduction Process for the recovery of radioactive and RCRA metals from the waste salts has been developed. The process uses a Ca-Ga intermetallic alloy which recovers over 98 percent of the reactive metals. The matrix salt phase in this process, viz. calcium or alkali metal chlorides, are clean after salt scrub reduction.

Jan 1, 1995

By R. S. Sheeta, C. J. Bise

The search for a more effective means of coping with methane liberation has resulted in the expanded use of seam degasification. Its advantages are measured not only in reducing the hazards due to methane, but also in producing a marketable commodity, the gas itself. However, the success of a methane drainage system is the culmination of many complex factors, the most important being the coal seam permeability. The two most popular drainage techniques used in mining today are the vertically stimulated borehole method and the in-seam horizontal borehole method. The objective of this paper is to determine the permeability range in which the selection of the degasification technique is based primarily on equipment and economic analysis. A discussion of the equipment involved will be incorporated into examples evaluated by the Pennsylvania State University coal methane simulation model.

Jan 1, 1990

By Richard A. Williams

The design, modelling and simulation of solid-liquid mixers remains one of the least advanced aspects of minerals processing, due to difficulties in quantifying complex slurry hydrodynamics from first principles, and in acquiring reliable experimental data for model verification and development. This contribution describes the application of electrical resistance tomography (ERT) for three dimensional imaging of the concentration of mineral particulates in a slurry mixer as a function of key process variables (particle size, impeller type, agitation speed). It is demonstrated how ERT can provide a wealth of detailed data to allow model development, which ultimately will lead to much improved design capabilities and the generation of mixing models which could reside within Particle Process Simulators. This principle is illustrated using descriptions of mixer behaviour based on an empirical approach, although the measurement methodology described is equally suited to development of computational fluid dynamics models, cellular models or design approaches based on artificial intelligence. The experimental data can be built into a visualisation data bank, which acts as a "process toolkit" by allowing a library of process responses to be catalogued. Hence these data can be accessed for the purposes of model development, equipment selection, optimisation of operating conditions or testing on-line control strategies.

Jan 1, 1995

By D. S. Young

The random variable transformation technique was introduced to make probabilistic structural analysis simple for such structures as slopes, dams, foundations, or retaining walls, where two shear strength parameters are required to analyze their stability by deterministic engineering methods. The Gaussian transformation was performed by using the Hermite orthogonal polynomial function. This transforms the experimental histogram into the standard normal distribution, whose mean is zero with a variance of one. Then, the transformed standard Gaussian variable was used for the bivariate normal probability analysis on the structure. The Gaussian transformation technique and the Hermite polynomial functions were chosen because the bivariate joint normal distribution is well-known and easily available for engineers. The binormal probability analysis was made on the probability region of a certain confidence level by superposing the critical line on the same probability region that divides the region into two zones: stable and unstable zones. The critical line was determined from the back calculation of the deterministic engineering method of the structural design. Finally, the probability of structural failure at a desired confidence level was calculated by simply integrating the volume of the binormal density surface above the unstable zone in the probability region. A simple case of slope analysis is introduced to illustrate this probabilistic approach, and its effectiveness and simplicity is demonstrated.

Jan 1, 1987

By J. A. Organiscak

Data on dust-control practices, mining conditions and occupational exposures were gathered for approximately 80 underground continuous mining units. Despite silica contents on dust samples in excess of 5%, nearly forty units successfully maintained silica concentrations at or below 100 µg/m3 on a majority of occupational dust samples, while the remainder had difficulty maintaining this level. These two sample sets were termed Group A operations and Group B operations, respectively. This data was compared to identify causes of high occupational silica dust exposures. Analyses of dust-control parameters and geologies revealed only minor differences between these two groups. However, subsequent comparisons of face ventilation design showed considerable differences in silica exposure and silica content between Group A and Group B at the continuous mining machine and roof bolter operator occupations. These differences were minimal when using exhaust curtain ventilation with a dust scrubber. This face ventilation system can benefit operations having difficulty controlling silica dust exposure and silica dust content. The collected data also showed that occupational samples from Group B operations possessed generally higher silica exposures and silica content than similar samples from Group A. The single head roof bolter (helper) possessed among the highest silica exposures and silica contents in both groups.

Jan 1, 2002

By J. A. Chermak, D. D. Runnells

Sulfide-bearing waste rock, ore and tailings have the potential for generating acid rock drainage (ARD) when exposed to an oxidizing environment. The possibility exists of utilizing the acid produced to react with lime and/or limestone to form a self-sealing cap on the reactive waste rock and tailings. Laboratory column experiments were conducted using acid-generating waste rock with a surface amendment of limestone and/or lime. Artificial rainwater was introduced and allowed to drain through the columns. Results demonstrated that the limestone and lime reacted with the acidic rock, resulting in the precipitation of a hardpan layer of gypsum and amorphous iron oxyhydroxide at the surface. The hardpan layer significantly reduced the effective permeability of the column. Based on the results of this study, it should be possible to create hardpan layers as chemical caps to significantly reduce the infiltration of rainwater and snowmelt into acidic waste rock or tailings material in the field. Unlike traditional capping methods, e.g., clay and high-density polyethylene (HDPE) covers, chemical caps should be self-healing.

Jan 1, 1998

By A. A. Odunaike, E. G. Okafor, M. H. Mokwe

Microscopic Studies were performed on ore samples from the Muro banded iron ore deposit in Nigeria and the Marampa iron ore deposit in Sierra Leone. Ore characteristics that affect processing of both ores were compared with a view toward assisting mineral processing engineers in choosing the most suitable methods for upgrading the ore. The Nigerian ore contains 30% to 37% (by weight) Fe and the Sierra Leonean ore contains 34% to 51% (by weight) Fe. Hematite is the main iron mineral in both ores. The Sierra Leonean ore is relatively coarse grained (typically around 250 µm) and can be upgraded by conventional gravitational methods. In contrast, the Nigerian iron ore is fine grained and must be ground to -74 µm to liberate the hematite for recovery by flotation. Both ores contain high percentages of phosphorus and sulfur, which are above the required specifications for direct reduction and blast-furnace practice. These deleterious elements can be rejected by grinding and flotation.

Jan 1, 1999

By S. Bassignani, D. Ippolito

In Italy at the moment there is a program which involves for the future the exploitation of two uranium mines which are now in the research stage. About one hundred and fifty workers are at present employed in those facilities. An health physics surveillance program is under way and has been designed to fulfill the requirements due to the future exploitation of the two mines. A complete evaluation of the total dose (external + internal) received by the workers will be given together with a detailed analyses of the technical methods employed for such evaluations. The external doses are evaluated on the basis of individual TLD dosimeters, while the evaluation of the internal doses is mainly due to an enviromental survillance program of the radon and radon daughter air concentration inside the mines. The criteria established for the assessment of the sampling procedures, sampling intervals and dose evaluation related to the radon doughter exposure are reported. The external dose received by the workers are lower than 0.2 m Sv~month and the internal exposure less than 6.4 IO-3 J.h.m-3 /year or using the old units 2 WLM/year.

Jan 1, 1981

By A. Uribe-Salas, J. A. Finch, B. J. Huls

Gas holdup profiles in the collection zones of a pilot flotation column (0.91 m x 13.5 m) and a laboratory flotation column (0.057 m x 9.5 m) operated with air and water only were determined from pressure measurements. The profiles were determined discretely and continuously. For the pilot column, a minimum distance between pressure measurements was necessary to give reliable results. For the laboratory column, a third-degree polynomial fit to the pressure vs. height data was required. Water manometers proved to be less sensitive to sensor and process noise than pressure transducers. The profiles showed that gas holdup approximately doubled over a height of 8 to 10 m. The profiles were not linear, and the gradient increased towards the top of the column, especially for gas rates greater than 1 cm/s. The profiles cannot be predicted by a simple bubble expansion model. The implications of this new finding of a significant gas holdup increase with height in the collection zone on various aspects of flotation column design and operation are discussed.

Jan 1, 1996

By J. Y. Hwang, M. L. Jeong, R. C. Greenlund

Various aluminum-smelting by-products from three production sources were received and characterized. The waste materials were tested for compound identification and environmental acceptance. A coarse metallic aluminum recovery test using an Eddy Current separator (ECS) was performed using two different Circuit configurations. White dross performed equally well with either Circuit, while black dross processing shows significant difference on the separation results. It was found that ECS technology was effective for particle sizes down to 6-10 mesh.

Jan 1, 2001

By J. Y. Kim, S. L. Chryssoulis

Lead ions that originate from galena during the processing of complex sulfide ores migrate onto the surfaces of sphalerite and iron sulfide minerals. This results in poor selectivity during differential flotation. Generally, in sulfide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. The surface lead complicates the zinc flotation circuit by lowering the concentrate grade. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zu and Pb-Zu ores is discussed. Plant and laboratory-test data are interpreted by determining the surface compositions of individual grains of sphalerite and iron sulfide particles. For the first time, surface compositions were determined by using laser-ionization mass spectrometry (LIMS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Cationic and cationic species on the surface were analyzed to elucidate the phenomena. It was proven that these new techniques are very useful in understanding the basic mechanisms of a sulfide mineral-flotation system.

Jan 1, 1997