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By K. E. Waters, N. Brodusch, R. Gauvin, C. Teng, H. Demers

Rare earth elements play an increasingly important role in renewable energy devices and high-end electronics. In this project, the composition and morphology of REEs-bearing minerals are characterized with a field-emission scanning electron microscope at high spatial resolution and high counts rate using an X-ray silicon drift detector system. High spatial resolution imaging and energy dispersive X-ray microanalysis were applied at low and high magnification to obtain the composition of each phase in the minerals. From the standardless quantitative analysis results, the amount of REEs in each phase was measured and the relationships between those phases were identified.

Jan 1, 2014

By Laxman M. Amaratunga, Glen G. Hein

"Most mining operations utilize the tailings coarse fraction for backfilling while the fines have been traditionally disposed on surface in tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10-30% w/w of <45 µm) in the fill (Brummer and Moss, 1991). This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMO) from these ponds has proven to be a costly environmental problem and a long term liability.One practical method to reduce the environmental impacts associated with the tailings pond is to modify the physical and chemical prope1ties of the fine tailings so that they can be utilized in an environmentally safe manner. This was accomplished by agglomerating the tailings into pellets and using theses pellets as a coarse aggregate in a total tailings paste fill. This technology does not require any supplemental sand or gravel to be added to the fill.This paper presents the ongoing research into utilizing these tailings agglomerates as a coarse aggregate fraction, in order to create a total tailings paste fill which has supe1ior strength characteristics.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. The waste rock is usually returned underground for use as rock fill in underground support with the tailings remaining to be disposed of in tailings ponds. Tailings consist of a coarse and fine fraction, and can be either reactive (acid generating) or non-reactive. In an effort to minimize tailings disposal, the coarse fraction has been used underground in backfill along with alluvial sands. This diversion of the coarse fraction, however still requires that the fine fraction be disposed of in tailings ponds. This disposal creates the potential for acid mine drainage (AMO), since in the presence of air and water, reactive sulphide tailings can generate acid. It is therefore an important goal in the mining industry to minimize the disposal of fine tailings into tailings ponds since the treatment of AMO is a costly and long-te1m environmental liability."

Jan 1, 1997

By K. Wongpreedee

Recovery and recrystallization of Au wire can degrade strength and alter conductivity properties during exposure to elevated temperature. Au Deformation Processed Metal Metal Composites (Au DMMC&apos;s) are being developed for electronic applications requiring high conductivity and high strength. This paper discusses the relationships between microstructure, strength, and resistivity of Au DMMC&apos;s. It also presents the results of a recent study on the elevated temperature stability of Au DMMC&apos;s of several compositions. Au-7 vol %Ag, Au-14 vol %Ag, and Au-vol 7%Pt DMMC samples were prepared by a powder metallurgy technique. All specimens were processed into wire by extrusion, swaging, and drawing. The smallest final diameter of these wires was 120 ?m. Thermal stability was analyzed by electrical resistivity measurements to determine the relation between transformation rates and time at elevated temperature. The extensive deformation used to produce these composites reshaped the initially equi-axed powder into filaments that are 30 to 100 nm in diameter and 16 to 180 mm in length. The small filament diameter confers high strength on the composite. The high conductivity can be explained by electrons flowing parallel to the filamentary microstructure aligned with the wire axis. Using the Avrami and Arrhenius equation relationships, it is possible to predict the times and temperatures needed to achieve various degrees of homogenization. The Au DMMC&apos;s were found to have good thermal stability compared to conventional coldworked Au interconnection wires. Although these composites will revert to solid solutions if exposed to high temperatures for prolonged time periods, their relative stability is sufficient to allow them to maintain their twophase microstructure during the anticipated lifetime temperature profiles of many products.

Oct 1, 2003

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By L Thompson, R C. West, T S. Kho

In 1978, the Outotec direct to blister flash (DBF) smelting process was commercialized with the commissioning of the Glogow 2 smelting facility in Poland. Since then four further DBF facilities have been constructed, two at Olympic Dam, one in Zambia and most recently one at Glogow 1 in Poland. The DBF smelting process differs considerably from conventional smelting process in both chemistry and unit operations, presenting opportunities for flowsheet capital and operating cost savings particularly when the concentrate copper grade is high. WorleyParsons has amassed considerable expertise in the Direct to Blister process and in this paper the process is compared to the modern two stage Double Flash process. The processes are modeled, and the key operating parameters, consumables and production metrics are directly compared. Subsequent flowsheets, key equipment lists and capital costs are also presented for comparison and discussion. The results show the range of concentrates which are most economically treated by the DBF process relative to those best treated in conventional processes along with those concentrates which could be treated by either process. INTRODUCTION The Outotec Direct to Blister (DBF) process was developed and installed at Glogow in 1978 (Czernecki et al., 2006). Currently there are a total of five DBFs built on three sites: Glogow No.2, Olympic Dam No.1, Olympic Dam No.2, KCM Zambia and Glogow No.1, being the most recently constructed. The DBF process was the first flash furnace process to produce blister copper and paved the way for the subsequent development of the flash converter and other continuous converting processes. Today four flash converters are in operation taking the total number of flash furnaces producing blister copper to eight. In all DBF operations it is the unique ore and concentrate composition which made selection of the DBF process the most attractive. In all cases, the concentrate is relatively high in copper but low in iron because chalcopyrite is not the major constituent. When considering smelting options for high copper, low iron concentrates a key question is then often asked, “At what point does it become economic to switch from two stage smelting and converting process to the DBF process?”

Jan 1, 2019

By Wouter Bleeker, Isabelle Cadieux

"Abstracts of theses related to mineral deposit studies and exploration, completed at geology or earth science departments of Canadian universities, have been compiled for the period 1991 to mid-l993. Part I, presented in the June 1994 issue of the CIM Bulletin, gave a listing of thesis titles. Part II, which consists of edited abstracts of these considered to be of direct application to mineral deposit studies and exploration, is presented under various themes as follows;A. Kimberlites, Other Alkaline Intrusions and Related Studies;B. Volcanogenic Massive Sulphide Deposits and Related Studies;C. Mineral Economics;D. Mesothennal Gold Deposits, Other Gold Deposits and Related Studies;E. Magmatic Nickel-Copper, Platinum Group Element, and Chromite Deposits and Miscellaneous Platinum Group-related Studies;F. Granite and Pegmatite-related Deposits and Porphyry Deposits;0G. Diverse Hydrothermal Deposits, Sediment-hosted Copper Deposits and Mississippi Valley Type Lead-Zinc Deposits; andH. Uranium-related studies, Evaporites and Exploration GeophysicsAbstracts related to themes A. B and C are presented in this issue; the remaining abstracts will be presented in future issues."

Jan 1, 1994

By D. Naden, D. J. King

"The high capital and operating cost of liquid-solid separation circuits in hydrometallurgical plants has led to an increased focus on the use of in-pulp systems for metals recovery in order to eliminate the need for solids washing and to reduce the need for liquid-solid separation.Carbon-in-pulp (CIP) has now been accepted in Canada and around the world as the leading process for recovery of gold and silver, replacing the Merrill-Crowe process and thus removing the need for CCD thickeners or belt and drum filters. The overall design of conventional CIP adsorption circuits was established in the late 1970s and it has remained substantially unchanged until now. Most of the development work since 'hen has been concentrated on improving methods of separating pulp and carbon and on reducing carbon losses during transportation and agitation.Resin-in-pulp (RIP) has been used for many years in uranium mills in the USA. However, most of the plants were built in the 1960°s and RIP was only chosen when liquid-solid separation of leach pulps proved very difficult. The plants are far from ideal as they have high resin losses and high maintenance costs. Consequently, there is room for improvement.Davy McKee has taken a fresh look at the engineering development of in-pulp contactors leading to a fundamental redesign of the adsorption units. The improved in-pulp technology uses a modification of the proven air-swept screen techno1ogy together with a new technique of process operation. The new contactor operates at high pulp throughput rates with high concentrations of carbon or resin in the recovery stages, resulting in a significant reduction in the contactor size over conventional design. As a result of this reduction in the size of the contactor by up to 80%, significant savings can be made in equipment and building costs. In addition, the plant 1s easier to operate than a conventional CIP plant."

Jan 1, 1987

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By M. Remillard, M. Garon, M. Thérien, D. Hodouin

"Nineteen streams in the copper and zinc flotation units of the concentrator of the Matagami division of Noranda Inc. have been sampled for particle size distributions chemical assays, and gold and silver contents in each particle size interval. The data are upgraded by the mass balance package BILMAT. These results, in conjunction with microprobe analyses, are used to quantify the silver losses in the copper clean¬ing flotation stages and to determine how overall silver and three silver-bearing minerals are recovered in the plant final products.RESUME Dix-neuf produits des circuits de flottation du cuivre et du zinc de la division Matagami de Noranda Inc. ont été échantillonnés pour leur distribution granulométrique, analyses chimiques et le contenu d'argent et d'or des fractions granulométriques. Le bilan métallurgique a été obtenu à l'aide du programme BILMAT. Ces résultats couples avec une etude minéralogique à la microsonde sont utilises pour quantifier les pertes argentifères aux diverses étapes de nettoyage du circuit de cuivre et pour de¬terminer la repartition de l'argent et des trois minéraux argentifères dans les produitsfinals de l'usine.INTRODUCTION The Matagami division of NORANDA INC. produces copper and zinc concentrates from a sulphide ore which contains a small amount of gold (0.34 g/t) and silver (20 g/t). Only a small part of the silver (~-30%) is presently recovered in the copper concentrate. The objective of this study is to evaluate the metallurgical behaviour of silver, and secondarily of gold, in the flotation circuit for a possible increase of its recovery in the copper concentrate to improve its economic value. For that purpose it is worthwhile to study the minerals which bear silver and to determine the critical flotation stages where they are lost in the tails. The methodology proposed here is based on a coupling of a mineralogical study and a detailed mass balance calculation in the flotation circuit."

Jan 1, 1986

By S. N. Rossovsky

"A new method for the hydrometalfurgical treatment of refractory gold arsenosulphide concentrates is presented. Themethod involves a combination of&apos; finegrinding, intensive agitation, flotation, and cyanidation, and consists of leaching of -10u pyrite and arsenopyrite particles in alkaline solution under intensive agitation without the application of costly high-pressure and roasting techniques. Consistent extractions of gold, in excess of 96%, are achieved.IntroductionConventional methods of alkaline leaching of gold arsenosulphide concentrates in an autoclave» and under electrochemical oxidation( 2) require expensive equipment as well as high-cost energy and reagents. In other cases, processing of gold concentrates inelude: ultra-fme grinding, calcination at 200°C to 250°C with the addition of an oxidant (NH4NOJ followed by alkaline leaching of the resulting calcine with hydrogen peroxide, the latter being a complicated method yielding poor extractions of gold (89% to 90%). In this paper, a hydrometallurgical method is described for processing refractory gold arsenosulphide concentrates in which alkaline leaching is followed by cyanidation of the residue."

Jan 1, 1993

By Francisca San Martin, Tomas Vargas, Willy Kracht

"In Cu-Mo deposits it is usual to find considerable amounts of pyrite (FeS2). When processing this kind of ore by flotation, pyrite is rejected using lime to increase the pH to alkaline conditions (pH ~10.5). In the case of using seawater without pre-processing, i.e., raw seawater, the lime consumption increases dramatically and the recovery of molybdenite drops due to the precipitation of magnesium hydroxide on its surface. In order to avoid these negative effects, alternative ways of depressing pyrite should be considered.The current work introduces the use of Acidithiobacillus ferrooxidans, bacteria commonly used in bioleaching, as an alternative to depress pyrite in seawater flotation. The paper presents the results of biodepression in three systems: fresh water, water with added sodium chloride at 35 g/L (which corresponds to the salt concentration in seawater ) and seawater. The results show that it is possible to bio-depress pyrite with A. ferrooxidans in natural seawater pH (7.8-8.2). A similar behaviour is observed when running the experiments in fresh water, and in water with sodium chloride added.INTRODUCTIONWater is a scarce but essential resource for human development. The main reason for this scarcity is that, although 70% of the earth's surface is covered with water, only 3% of the total is fresh water and an important part of this water is frozen, so that only 1% of fresh surface water can be used for human activities. In Chile, most of the mining activity is concentrated in the north of the country, located in the Atacama Desert, considered the world's driest desert. That is why some mining companies have chosen to use seawater in their processes. For example, Esperanza (Antofagasta Minerals), and Sierra Gorda (KGHM International) use raw seawater in their flotation processes."

Jan 1, 2016

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"This paper briefly summaries the status of a recent program aimed at identifying new chemistry for use as sulfide mineral frothers and collectors. The background motivation and planning behind this work is given along with the general families of chemical structures synthesied and studied in detail followed by typical flotation application results in various laboratory and plant scale tests. Flotation testing to date has been very encouraging with often improved recoveries of certain minerals and improved pyrite selectivity being observed over commercially available reagents. In addition, in some cases, the dosage and lime requirements of these new collectors are significantly less than that associated with standard sulfide mineral collectors. INTRODUCTIONFroth flotation is one of the most widely used and economic means of concentrating metal sulfide ores. There are numerous reference books that have been published on the chemical aspects of flotation [e.g., ref. 1-7] which are based on studying the influence on selected minerals of chemical structures that have been used commercially for many years. In fact, almost 98% of the volume of flotation collector and frother reagents used at the industrial level today were known and manufactured in some form 25 years ago [8]. There are many reasons for this lack of significant new flotation reagent development [9] including the general utility and relative cheapness of existing collectors such as xanthates and existing frothers such as the alcohols and glycol ethers. Another reason is the inherent complexity of the flotation process itself coupled with highly variable and difficult to standardize feed materials. This environment makes reliable reagent comparisons difficult and seriously limits the use of theoretically based chemical structure studies to predict new or optimal reagents. In addition, the higher cost of specialty flotation reagents demands that their performance attributes be significantly greater than that achieved with existing all-purpose commercial reagents - something often difficult to prove in practice."

Jan 1, 1988

By Ali Roshanfekr

Linear mine-waste dumps at open-pit mine sites essentially represent expedient places to deposit large quantities of waste rock. Being in valleys in most cases, the effect of the water flowing through and out of the deposit often raises questions about their hydraulic behaviour and geotechnical stability, especially the zone of the downstream toe. In order to provide better tools to assess the behaviour of these dumps a laboratory and analytical study was conducted. Firstly, physical models were built to assess the flow capacity and hydraulics associated with the linear growth of such dumps. It was found that the elevation of the point of first-emergence on the downstream side becomes constant after the dump grows to a certain length, but that the upstream depth concurrently increases. The limits of applicability of the theories of Hansen et al. (1995, 2005) are discussed in this regard. Secondly, in analysing the seepageface downstream, two approaches for solving this spatially varied flow (SVF) problem were undertaken. Under one of the approaches links to SVF depths were merely made to the hydraulic heads of the body (interior) and flux was calculated using conventional surficial nodes after the fact, Under the other approach flux nodes were used to link the SVF algorithm to the hydraulic heads further ?inside? the body of the rockfill. Although there are inherent uncertainties, it was found that these two methods can be made to perform equally well. Research continues but it appears that a linear variation in depth can be assumed without inducing any unrealistic exit gradients in the zone of primary concern with respect to unravelling.

May 1, 2011

By L. J. Surges, C. Bazin, D. Hodouin

"A kinetic model was developed for the conditioning and flotation processes of an industrial lead concentrate dezincing circuit. The models were incorporated into a flowsheet simulator. Simulation results demonstrate the advantages of split conditioning of coarse and fine particles and the potential of this approach for the production of the heuristics required for the development of intelligent control strategies.The conditioning model relates the proportions of activated and hydrophobic surfaces and residual reagent concentrations to activator and collector reagent flowrates. The model accounts for the solids and water flowrates, and for the solids grade and size distribution. The flotation model uses the predicted proportion of hydrophobic mineral surface, the aeration rate and the froth depth to estimate cell, bank and circuit performances. IntroductionFlotation has been the object of modelling and simulation studies for more than two decades. The process is usually modelled as a kinetic one in which the particle flotation rate constants are key parameters. Rate constants are related to the operating variables (pH, reagent flowrates, aeration rate, etc), however these relationships are seldom established in the literature.In spite of the large amount of literature on flotation modelling and simulation, few papers deal with the interaction between flotation rate constants and operating variables. This important gap, which was identified in the early seventies by Woodburn (l970), still exists. One of the first attempts to include operating conditions in a flotation simulator was made by King (l973), who explicitly introduced the aeration rate into an air bubble loading model. Lynch et al. (1981) used an empirical model to relate the proportion of slow floating particles to the ratio of collector per ton of ore. Such empirical relationships are difficult to calibrate and cumbersome to use when an activator and a collector are added to slurries in which particle size distribution and surface characteristics are changing. Eascur and Herbst (l982) relate in a fundamental way the mineral flotation rate constants to the aeration rate, froth depth, agitation and frother concentration, however the model does not account for reagent flowrates. Niemi et al. (1982) have proposed a model for the conditioning of minerals and included it into a conventional flotation simulator."

Jan 1, 1988

By Mike Anderson

The annual budget for the repair and maintenance of equipment at Syncrude Canada Ltd is in excess of 450 million dollars. Of this amount, a significant portion can be attributed to the loss of material on various pieces of equipment throughout the operation. In order to effectively battle the different wear and corrosion mechanisms that lead to material loss, it is important to understand how materials behave in the environments in which they are used. Through the work carried out at Syncrude, and work conducted with various external collaborators, significant improvements in both equipment reliability and productivity have been achieved. This paper will review some recent field trails where materials research has demonstrated the potential for significant improvements in equipment run life and reduced maintenance costs. These field trails will demonstrate the need for understanding the interaction between various damage mechanisms and the materials used in different services. The paper will also discuss current areas of focus along with future directions for further work.

May 1, 2003

Flotation of a mineral bearing particle is the result of successful completion of a chain of events, such as, producing particles with sufficient exposure of the valuable mineral on the surface, reagent adsorption, suspension of the particle in the pulp, collision of particle with air bubbles and subsequent attachment, ascending to the froth column and transport to the concentrate stream, among others. These sub-processes in turn are affected by the feed properties such as size and density, and process variables such as size of air bubbles, degree of turbulence in the cell, particle/particle interactions etc.. Thus, inefficiencies occurring in any one or more of the above processes will result in inefficient flotation performance. In spite of its dependency on a wide variety of sub-processes, flotation performance is commonly modelled based on first order kinetics using two or three parameter models. As the model parameters may be affected by several of the sub-processes mentioned above, interpretation of their variations and identifying the specific causes is extremely difficult. Of the many factors that influence the flotation performance, liberation information of the particles such as the grade distribution and surface exposure are considered vitally important. In this paper, it has been demonstrated a) how a predictive liberation model may be derived and used in quantifying the liberation information of the particles produced at various grind sizes and b) how the flotation process may be modelled by explicitly incorporating the liberation information, thereby improving the accuracy of the model. Comparisons of the observed data with the proposed model and those of published liberation/flotation models have also been made.

Jan 1, 2016

By F. S. Su, P. Z. Pan, X. T. Feng, F. Yan, W. W. Ji

"This paper aims to simulate the spalling failure behavior in hard rock based on a self-developed numerical model, i.e. a rock discontinuous cellular automaton (RDCA). A crack initiation and propagation criterion is proposed based on the plastic strain, which is used to link the continuity and discontinuity during the failure process. The discontinuities of rock, such as cracks and other internal boundaries, are represented by discontinuous displacement functions, i.e. tip enrichment and step enrichment. The partition of unity is used to improve integral precision of the elements intersected internal boundaries, which is traced by a level set method. Arbitrary crack geometries can be conveniently represented and it does not require any remeshing in the modeling of crack initiation, propagation and coalescence. Numerical modeling of excavation in hard rock using RDCA is conducted. The spalling failure process of hard rock induced by excavation is well simulated. The depth and shape of hard rock spalling failure are good agreement with in situ observation.INTRODUCTIONThe excavation in rock mass is more and more popular. At the same time, the disasters, such as rock burst, rock spalling and falling etc, induced by excavation are quite prominent. Numerical modeling is an important way to help us understand the failure mechanism of rocks. Many numerical methods have been used to simulate the excavation of rock mass. For example, the finite element method (FEM) (Karakus and Fowell, 2003), the discrete element method (DEM)(Cundall and Strack, 1979, Labra et al., 2008), Finite difference method (FDM)(Zhu et al., 2009), Element Free Galerkin Method (Belytschko et al., 1994), Discontinuous displacement analysis (DDA) (Shi, 1988) and Boundary element method (BEM) (Katsikadelis, 2002, Chen and Hong, 1992) are commonly found in the stability analysis of excavation in rocks. In the modeling of crack propagation or excavation, most of these methods are tedious since the internal boundaries have to be consistent with the element boundaries. And in many cases, the remesh has to be conducted. In recent years, people are interested in particular types of FEMs, such as the extended finite-element method (XFEM), the particle discretization scheme finite-element method(PDS-FEM(Hori et al., 2005, Oguni et al., 2009)), the combined finite-discrete element method (FEM/DEM) (Munjiza and Wiley, 2004, Cai, 2008) and spectral-element method(Gharti et al., 2012) etc."

Jan 1, 2015

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract—Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O signature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By R. A. McIvor, R. S. Rafuse

"INCO Limited purchased a custom designed mobile hoist rope winder/tensioner in 1988 from TimberLand Equipment Limited to handle Large hoist ropes and serve as an emergency hoist. This paper describes the operation of the winder/tensioner and some of the different applications that the machine has been used to handle large loads.IntroductionINCO Limited operates 24 mine hoists in the Ontario Division and has approximately 50 miles of mine hoist rope hanging in the shaft plus an equal amount on spare reels. The mine hoist ropes range in size from )( inch to 2.305 inches in diameter with the majority being 1 3/4 inches and above. Prior to the procurement of a new high powered winder/tensioner in 1988, the mine hoist ropes were handled with a variety of methods and equipment using hydraulic or pneumatic powered reel winders. The largest such reel winder has a pull rating of 8000 Ibs and travels approximately 40 ft/min. Head ropes for the tower mounted friction hoists were installed and removed using a magazine on the hoist drum to wind and unwind the rope because the loads were greater than the capacity of the existing machinery. It was recognized that a large high capacity machine would improve the productivity for handling the larger hoist ropes and a feasibility study was undertaken to determine the parameters for such a machine."

Jan 1, 1995