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By Sönke Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

By M. Gholinejad

Applying non-explosive expansion material (NEEM) is one of the safest methods for rock fracturing, especially in a hard rock quarry. An experimental study was conducted to determine the pressure exerted by NEEM in a hole, which is necessary for analysing rock fracturing, particularly in a numerical modelling. Stress distribution was developed in a thick-wall cylinder in order to measure the tangential strain on the external boundary. In the experiments, nine pipes of different materials and varying diameters were selected and then loaded internally with a general type of NEEM. Through electrical strain gauges, the tangential strains were recorded on the external boundary of the pipes. The results obtained from these tests and existing data from previous researchers were utilized for the statistical analysis. A new experimentally-derived formula is proposed for determining the pressure exerted by NEEM by multiple parameter regression with a high correlation coefficient. The proposed model has a nonlinear form with three independent parameters i.e. the hole diameter, the time, and the modulus of elasticity of the material.

Jan 1, 2012

Material transfer in underground mines often relies on ore and waste pass systems. Over the years the authors have investigated the design and performance of orepass systems in several Canadian and South African mines. It has been recognized that while most mining operations have either implicitly or explicitly clearly defined objectives, in the design and successfully operate orepass systems there seems to be an absence of a strategy on how to best attain these goals. Consequently, it is not surprising that the majority of operations reviewed by the authors experience a number of problems of varying degrees of severity and economic consequences. This is illustrated by reference to both South African and Canadian operations. The second part of this paper focuses on a review of tactical interventions to rectify orepass problems or mitigate their impact. The paper closes with a framework for a flexible strategy for the design and operation of orepass systems. Keywords orepass; orepass design; orepass stability; orepass rehabilitation; orepass operation; orepass strategy.

Oct 1, 2013

By W. P. Nel

A fuel cell is an electrochemical engine that converts the chemical energy of a fuel, such as hydrogen, and an oxidant, such as oxygen, directly into electricity. The emerging fuel cell industry may represent a major opportunity for the global platinum mining industry. This is because low temperature fuel cell systems use platinum group metals as catalysts. Fuel cell vehicles may become the most important driver of future platinum demand within years of their commercialization. A great number of factors impact on and drive the diffusion of fuel cell vehicle innovation. Such drivers range from energy security to environmental concerns and the technological development of fuel cells and systems. Such factors and drivers of fuel cell vehicle diffusion are combined with the generic ?body of knowledge? on ?technology forecasting? and ?diffusion of innovation? to design a framework that provides a holistic approach to the analysis of this complex enterprise. An attempt is made in this paper to address the following questions: Which types of fuel cells require platinum group metals? Which types of fuel cells will achieve dominant design status? Will fuel cell vehicles diffuse successfully? How big will the impact of successful fuel cell vehicle diffusion be on future platinum demand? How well do fuel cell vehicles compete with incumbent technologies such as spark-ignited and compression-ignited internal combustion engine-driven vehicles? How soon will oil depletion start to drive the diffusion of fuel cell vehicles? How important is hydrogen as a fuel? What impact does the inadequate hydrogen fuelling infrastructure have on fuel cell vehicle diffusion? The paper contains some initial results of a research project that has the aim of producing a schedule of future platinum demand generated from fuel cell vehicles. Keywords: diffusion of fuel cell vehicles, technology forecasting, platinum demand forecasting.

Jan 1, 2004

Bougainville Copper Limited (BCL) operates a 50 Mtpy copper/gold/silver mine and concentrator on Bougainville Island, Papua New Guinea. BCL has installed an in-house developed data logging and supervisory process control system using a DEC PDP 11/73 mini-computer in the mill and has recently installed a similar system in the crushing plant. Together with the central DEC VAX 11/780 computer, they form part of a high speed, fibre optic, local area network in the concentrator. The in-house developed software, known as BIAS (Bougainville Copper Information and Automation System), was developed as a low cost option to interface to a number of different existing plant input/output systems while providing the capability to make maximum use of computer networking facilities. The package includes the more usual control system colour displays and data logging features, but also makes provision for two novel features: (a) Any user connected to the computer network can access the system displays. This allows metallurgists and management to monitor (but not control) plant operation from their offices. (b) Specialized application programs for performing advisory and supervisory control, dynamic simulation, and data analysis are easily incorporated into the system. The mill process system currently runs rougher/scavenger flotation stabilizing control and general data logging. The crushing plant system currently performs data logging only; however it will soon be augmented with the facility to run dynamic crushing plant simulations. Future developments will concentrate on making greater use of the detailed information available from the mine's fully automatic truck dispatch system which runs on a VAX 11/780 computer. Milling process control will be expanded to examine possible economic control of the operation of regrind and cleaner flotation circuits. An advisory water management system to optimize water supply within powerhouse generating capacity constraint will also be investigated.

Jan 1, 1987

By C. F. Vos, J. D. Miller, J. C. Davidtz

"This work presents the potential for improving the flotation recovery of slow-floating sulphide minerals with the use of starvation dosages of a normal dodecyl (n-C12) trithiocarbonate (TTC) co-collector, together with a sodium isobutyl xanthate (SiBX) and dithiophosphate (DTP) collector mixture.At potentials below –150 mV (SHE), addition of nC12-TTC with SiBX improves the hydrophobicity of pyrrhotite, yielding captive bubble contact angles greater than those measured for SiBX or nC12-TTC alone, suggesting a low potential synergistic effect. This synergistic effect is further studied using Fourier transform infrared (FTIR) spectroscopy, the results indicating an increase in the surface concentration of the collector species when in a mixture. Thus, nC12-TTC with SiBX may act as an immobile surface anchor to which SiBX/SiBX2 molecules bond, increasing the localized concentration of collector species.Bench-scale flotation tests using mixtures of SiBX/DTP/nC12-TTC on a platinum group element (PGE)-bearing ore from the Bushveld Complex in South Africa confirm an improved metallurgical performance at very low substitutions (approx. 5 molar per cent) of SiBX. The improved recoveries for PGE, Cu, and Ni are correlated with improvements in the flotation kinetics of their slow-floating components. IntroductionShort-chain (less than C6) xanthates are very effective for the bulk flotation of sulphides (Fuerstenau, 1982), and early work (Leja, 1968; Gaudin, 1957; Plaksin and Bessonov, 1957; Taggart, Giudice, and Ziehl, 1934) indicated that the presence of oxygen in flotation slurries is necessary for the oxidation of the xanthate collector at the sulphide mineral surface to induce hydrophobicity. Fundamental research into the chemistry and adsorption mechanisms of xanthates over the years (Finkelstein and Poling, 1977; Woods, 1976; Winter and Woods, 1973) has revealed that for iron-bearing sulphide minerals, adsorption occurs predominantly through a charge transfer process. Oxidation of the adsorbed collector to the corresponding dimer takes place if the mixed potential of the system is greater than the reversible potential for dimer formation. In oxygenated slurries the rate of adsorption and oxidation of the collector depends greatly on the substrate surfaces. For chalcopyrite (Guler et al., 2005; Leppinen, 1990; Roos, Celis, and Sudrassono, 1990) and pentlandite (Hodgson and Agar, 1989) a two-step interaction with xanthate is proposed in which the chemisorbed xanthate is further oxidized to the dimer. The initial interaction of xanthate with pyrrhotite is through physisorption where xanthate physisorbs onto positive surface sites followed by oxidation to dixanthogen (Khan and Kellebek, 2004; Bozkurt, Xu, and Finch., 1998). This process is, however, slow and increased reaction time is needed to improve flotation recovery (Buswell and Nicol, 2002)."

Oct 1, 2018

By T. P. Katakwa

The utilization of software is now inherent to virtually every activity along the mining value chain. However, apart from the software survey done by Gibbs in the 1990s and work on the extent of diffusion of information and communication technology (ICT) in the South African platinum sector by Mugodi and Fleming in 2003, the nature and extent of software utilization in the South African mining industry has never been evaluated. The Mine Planning, Optimisation and Valuation (MPOV) Research Group in the School of Mining Engineering, University of Witwatersrand, therefore initiated a project to collate and analyse the current utilization of software in the South African mining industry. This was done through the development of a web-based database of the relevant software. Snowball sampling was used to collect the data because the South African mining industry is diverse and software utilization is fragmented across and within the sectors of the industry. The data was then organized into distinct categories so that the information from a variety of sources could be evaluated on the same basis. A beta version of the database can be accessed online through a user-friendly front-end platform at http://db.mining.wits.ac.za. The database is expected to help at least 13 educational institutions with decisions on facilities and training that are vital to the education of mining and mining-related professionals. Exploration, mining, and consulting companies will also benefit from information in the database relating to availability and useful combinations of software solutions. The database is also strategic to software providers by providing a better understanding of their respective relative market share along the mining value chain. An analysis of the data collated in this research shows that about 77% of the software users are mining companies, 17% are consulting companies, 3% are mineral exploration companies, and the rest are software providers and educational institutions. The software used in the South African mining industry is largely provided by Gemcom Software International, MineRP Solutions, and MRM Mining Services. CAE Mining, who in 2010 acquired the Datamine Group providing Datamine software, is also widely acknowledged as a major software supplier in South Africa, but data from them had not been obtained at the time of producing the beta version of the database due to proprietary constraints. The work reported in this paper is part of an MSc research study in the School of Mining Engineering at the University of the Witwatersrand. Keywords mine planning, mining, value chain, software, database, South African mining industry, utilization.

Jun 1, 2013

By M. J. Kanda

"The design of rock slopes in the planning and operation of open pit mines and for road and rail cuttings requires the evaluation of their stability. This is commonly done using two well-established methods – limit equilibrium and numerical modelling. The research described in this paper compares the outputs of analyses using these two methods with regard to factor of safety and probability of failure, taking into account technical factors associated with each method and other factors such as material parameters and their variabilities. Results show that technical factors such as number of slices and slip circles, number and type of finite elements, and the stress reduction factor can all affect the results of stability analyses. Factors not taken into account in limit equilibrium analyses, such as dilation, in situ stress, and locked-in stresses can affect the outputs significantly. The research has focused particularly on the predicted location of the failure surface, the resulting volume of failure and, most significantly dependent on this volume, the predicted risk associated with slope failure. The results presented show that there is good agreement between the outputs of the two methods regarding factor of safety and probability of failure. However, the same is not the case with regard to volume of failure and hence risk, which can be very dependent on the methods of analysis and their input parameters. The research is not exhaustive, and there are many other factors that could affect the results of slope stability analyses that were not investigated. Some such factors are mentioned in the paper.IntroductionThe design of rock slopes in the planning and operation of open pit mines and for road and rail cuttings requires the evaluation of their stability. The traditional method of stability analysis used limit equilibrium (LE) methods, and this approach continues to be used. Numerical modelling (NM) packages are now also commonly used in slope stability analyses. The outputs from these analyses provide the factor of safety (FOS) and probability of failure (POF) of the slope. Since the capabilities of the two approaches are different, there can be some variations in FOS and POF outputs and in the predicted location of the failure surface. These variations can affect the predicted volume of failure, and this could in turn have a significant effect on the risk associated with the potential failure (Read and Stacey, 2009). Researchers such as Chiwaye and Stacey (2010) have found that LE analyses underestimate the predicted failure volume, unlike NM methods."

Jan 1, 2016

By Peter N. Calder, Alan Bauer

The complexity of modem open pit load-haul-dump systems is described, and the need for realistic working models is pointed out. Both standard and probabilistic simulation procedures are discussed, probabilistic simulation being indicated as the more powerful and practical technique. Acquisition of the necessary pit operating data required for simulator construction and general modelling procedures are described. Finally, results from a typical open pit simulator are used to indicate the scope of the technique.

Jan 1, 2014

By A. S. Macfarlane

"SynopsisMetal accounting and reconciliation is an increasingly important governance issue in all mining operations, in that it is required, from a risk management perspective, that the company is in control of its product throughout the whole mining value chain. Reconciliation is a grossly misunderstood term. It means different things to different people, and therefore one of the purposes of this paper is to ensure a holistic and integrated understanding of ‘reconciliation’.Previously, where reconciliation was done, it was often for internal control purposes and loosely applied, sometimes with a low degree of confidence and understanding of the underlying parameters and their natural variability.In most mining operations, issues such as dilution, stope performance, and recovery are critical to profitability and long-term value, and thus understanding and control of these key value drivers is essential, not only from the governance perspective, but also from the perspective of maximizing shareholder returns. In order to implement a system for metal accounting and reconciliation, it is important that the cause and effect of these value drivers is understood, and that a systematic control system be established.While a number of off-the-shelf solutions exist for this work, it is the contention of this paper that a full understanding of the metal flow, its variability, its underlying loss potential, and its control points is necessary before a systematic approach to reconciliation can be undertaken.The paper also advocates that this approach should ensure that the reconciliation system clearly addresses the reconciliation needs, within a consistent framework. Such a framework has been developed by AMIRA, in terms of a metal accounting code. However, up until now, this code has been aimed at plant processes, whereas this paper shows how the concept can be extended to cover the full reconciliation requirements for a base metal mine.IntroductionReconciliation is defined as ‘the process of finding a way to make two different ideas, facts, etc., exist or be true at the same time’. In terms of a mining process, this refers to the comparison of measures and estimates along the value chain, and at different points in time, in order to track and optimize metal recovery. This leads to the notion of having a system in place for accounting for the metal. The University of Cape Town defines metal accounting as ‘… the estimation of (saleable) metal in a mine and subsequent process streams over a defined time period. Comparisons of estimates, from different sources over a specific time period, are called reconciliation.’Traditionally, metal accounting has consisted of geological reconciliations of mineral resource to mineral reserve conversion, mine planning reconciliation related to the reconciliation of long-term plans to short-term plans, grade control reconciliation of head grades to sampled or block grades, and mine survey reconciliation of tonnage discrepancies and mine call factors. In addition, metallurgical reconciliation has tended to be based on metal balancing, followed by some commercial metal accounting that links dispatched product to sales quality, quantities, and revenues. Miners disparagingly refer to this plant process as ‘millmatics’."

Jan 1, 2015

By H. Brüggemann

The exploration of deposits generates geological data which are suitable for creating a preliminary tectonic and stratigraphic model. Linked with the topographical map and analysis data from exploration drillings, this information forms a numeric representation of the deposit. The following example demonstrates an expert system which connects chemical quality requirements and quarrying criteria, and develops a quarrying strategy based on the calculated model. Additional constraining factors like process technology, quarrying methods, landscape protection regulations, etc. are included. The goal is to guarantee a long-term, homogeneous material flow from the quarry at acceptable production costs - even in the case of an extraordinarily inhomogeneous deposit. In order to fulfil this requirement it is necessary to consider a large number of rules, criteria and instructions which can be structured as an expert system and programmed with LISP at a comparably low cost. The chosen strategy is not necessarily final, but can be changed any time by altering or varying the framework of conditions. The output consists of a block-working sequence which best satisfies the set requirements for appropriate points of quarry opening.

Jan 1, 1987

By S. Konetschnik, E. Dreyer, A. Filzwieser

"More intense furnace operations require effective cooling in order to achieve low refractory wear and good furnace lifetimes, making cooling technology an important aspect of furnace operations. However, the use of water - today’s standard cooling medium - has some disadvantages, as it can cause problems both during furnace start-up and operation, namely hydration problems, corrosion, and explosions. Apart from these aspects, the energy that is removed by extensive cooling cannot be recovered and is normally lost in the cooling towers.With METTOP’s new patented cooling technology it is possible to overcome the disadvantages of water by using an alternative cooling medium, namely ionic liquids (ILs). The main advantage of ILs is the fact that there is no risk of explosion should this liquid come in contact with molten metal. Furthermore, ILs can be used at higher temperatures than water - up to 200°C. This relatively high cooling medium temperature avoids hydration and corrosion problems and allows recovery of the energy by combining the ILTEC system and the organic Rankine Cycle (ORC) technology, for example.Due to the removal of the explosion risk, much higher safety standards can be achieved, particularly in critical areas such as tap-holes"

Jan 1, 2014

By B. Steyn

AngloGold Ashanti?s Obuasi Mine, in Ashanti Province, Ghana, operates a plant utilizing bacterial oxidation technology. The mineralization consists predominately of arsenopyrite with gold associated in the sulphides. The plant was commissioned in 1994, at that time was the largest BIOX® plant in the world, and has been operated by AngloGold Ashanti since 2004. The constraints identified in the plantwere the flotation capacity, BIOX® feed size and disruptions to the BIOX® process. This paper focuses on the practical steps that were followed in order to increase the recovery of the plant. The original plant design was based on a head grade of 10 g/t and an overall recovery of 86.5%. In 2007 the plant was operating at an overall recovery of 79.2% at a head grade of 5.6 g/t and this has improved to 80.6% at a head grade of 5.8 g/t during the last quarter of 2008. Additional improvement to 81.5% are expected by the end of April 2009. Improvements that have been implemented include: ?Replacement of the regrind mill ?Installation of additional float capacity ?Installation of a scavenging circuit ?Installation of a complete water treatment plant. In addition we have focused on the effect of the water circuit on the BIOX® process and the steps involved in correcting this problem. The water circuit was originally designed as an open circuit and through environmental considerations the circuit was closed towards the end of 2007. The bacteria in the BIOX® are particularly sensitive to cyanide and cannot tolerate levels above 0.05ppm (free cyanide), this required extensive modifications to the water circuit. The plant improvement project is ongoing and the current scope of work should be complete by the end of April 2009. Further research and development work is being planned, which includes a ?white rot bacteria? that can consume the preg-robbing carbon and oxidize the sulphide in a single pass.

Jan 1, 2009

By D. A. Phillips

A procedure for designing an optimum pit to yield maximum profit is described. The volume in which a possible pit is considered is divided into discrete blocks, each of which is assigned an economic value equivalent to its worth as a block of mineable material. The profitability of a pit can then be generated by summing the blocks within the pit. The optimizing procedure starts at the surface level and proceeds downwards level by level, to obtain the optimum pit at each level. The method makes use of the fact that an optimum pit at a particular level must be completely contained in any optimum pit at a lower level. Procedures for generating block costs, and pits with various slope angles under the restriction of complete block removal are considered briefly. The main description is of the theory of the method and the computer program based on this. The method is applicable to any type of mineral deposit, the only requirement being that the orebody should be represented accurately by a block model.

Jan 1, 2014

By P. Ramphisa

In South Africa reprocessing used oil into industrial fuel is commercially attractive. The reprocessed product is sold as a substitute for heavy fuel oil that is derived from crude oil (Rose Foundation, 2008). The objective of this investigation is to evaluate the use of petroleum products such as oil, petrol and diesel in Driefontein Gold Mine. The recovery of oil through recycling has costs implications to the mine while the release of petroleum hydrocarbons due to the poor management of the use of petroleum products has potential to cause pollution and negatively affect soil and water. Environmental legislation such as the Minerals and Petroleum Resources Development Act (Act 28, 2002) requires that such negative impacts to the environment be rehabilitated. The rehabilitation cost of pollution caused by petroleum products to the environment increases operational costs in business. Field assessment is conducted to identify the main sources of petroleum product contamination such as leaks in piping, overfills and petroleum spills. The areas that require mitigation would be mapped in the study. Recommendations for mitigation measures will focus on using the best practicable environmental option (BPEO) as well as the best available technology not exceeding excessive cost (BATNEEC). The recovery of oil from the mining industry is generally low and very poor. In this study, the effect of proper management of petroleum products to the mine?s operational costs is investigated and compared to there mediation costs of the impacts caused due to poor management of these products. The study investigates the financial benefit that could be obtained from proper environmental practices and efficient usage of petroleum products in the mining.

Jan 1, 2009

By H. Lieberwirth, M. Klichowicz

The comminution at grain size level for the liberation of valuable minerals usually requires the highest size-specific energy. Therefore, the full understanding of the comminution process at this level is essential. Models based on the Discrete Element Method (DEM) could be a helpful tool for this purpose. In those, the mineral microstructure, which has a dominant influence on the fracture behaviour, can be described in great detail. One major concern, however, is the missing representativeness of simulated models. In this study, a method to overcome this limitation is presented. The authors show how a realistic microstructure can be implemented into a particle bed comminution simulation using a two-dimensional Bonded Particle Model (BPM). The improved algorithm based modelling approach is exemplarily compared to an equivalent real experiment. Thereby, the focus is set on the analysis of the interfacial breakage and the capability of the simulation to reproduce the experimental results. The comparison of the results shows that simulations at grain size level allow a more detailed evaluation of the fracturing behaviour. This is of special interest as the aim of comminution in mineral processing is not only the size reduction of coarse particles, but an efficient liberation of the valuable components. Hence, simulations with automatically generated real mineral microstructures will help to further improve the efficiency of ore processing. Keywords: Discrete Element Method, grain modelling, particle bed comminution, realistic synthetic

Jan 1, 2020

By J. Petersen, K. Shaik1, H. Kolev, Z. Cherkezova-Zheleva

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.

Mar 6, 2026

By P. L. Crouse

"SynopsisFluorine – in the form of hydrofluoric acid, anhydrous hydrogen fluoride, elemental gaseous fluorine, fluoropolymers, volatile inorganic fluorides, and more – has played, and still plays, a major role in the nuclear industry. In order to enrich uranium, the metal has to be in the gaseous state. While more exotic methods are known, the standard and most cost-competitive way of achieving this is by means of uranium hexafluoride (UF6). This compound sublimates at low temperatures, and the vapour is enriched using centrifugal processes. The industrial preparation of uranium hexafluoride requires both elemental fluorine gas and anhydrous hydrogen fluoride (HF). HF is prepared by the reaction of sulphuric acid with fluorspar (CaF2). Fluorine gas in turn is prepared by the electrolysis of HF. Yellowcake is first converted to uranium tetrafluoride (UF4), using HF, after which the compound is treated with fluorine to yield UF6. After enrichment, the UF6 is reduced to UO2 for use in fuel elements in pellet form.South Africa has the largest reserves of fluorspar internationally, and is the third largest producer after Mexico and China. Fluorine technology has many associated difficulties, because of the reactivity of fluorine and the toxicity of HF. The main barriers to entry into the fluorochemical industry are thus the abilities to produce both HF and F2. Both these substances are produced locally, at the industrial scale, at Pelchem SOC Ltd. Should South Africa contemplate developing its own nuclear fuel cycle as part of the awaited new-build nuclear project, it will be imperative to leverage the existing skills with respect to fluorine technology, resident at both Pelchem and Necsa, for this purpose. This paper summarizes the fluorochemical skills developed locally over the past several decades, and suggests strategies for maintaining the technology base and developing it for the next generation of scientists and engineers.IntroductionFluorine chemistry has always had a very close relationship with the nuclear industry. Although the first mention of fluorspar was recorded in the sixteenth century, and the fundamentals had been well-developed by the Second World War, it was only during the Manhattan Project (Banks et al., 1994), when almost unlimited funds were made available for the large-scale industrialization of fluorine and related compounds, that the technology took off. Expertise in both the chemistry and the engineering aspects of fluorine is essential for the design and running of several of the unit processes in the nuclear fuel cycle."

Jan 1, 2015

The key functions of project evaluation are to assess potential profitability and to develop an effective operational design. For mining projects, design aspects include mining methodology, ore treatment methodology and production rates. All of these characteristics impact on project economics and overall value. Resource models, which form the ultimate basis of project evaluation, typically consist of tonnes above cut-off, grade above cut-off and the spatial distribution (connectivity) of tonnes/grade above cut-off, for one or more variables. Dilution, ore loss and metallurgical recovery are all modifying factors applied to the resource model during evaluation and determination of profitability. A key issue is: how is the value determined? In addition to traditional combination of in situ tonnes/grade, the following merit serious consideration: the concentration of deleterious elements, throughput rates, mining/processing costs and - importantly - metallurgical recovery. Geometallurgy is an emerging field targeted at integrating these issues by identifying either direct measures or proxies for throughput (hardness, grindability), recovery (liberation, mineral shape/texture, etc) and concentrate quality from easily collected macro-, meso- and microscopic data. These 'geometallurgical variables' drive project costs and revenues in a fundamental way. For geometallurgical characterisation to have a real impact on business design, it must enable improved mine planning. When creating spatial estimates for such variables, it is preferable to find proxies that can be measured as close to the intact rock mass as possible. However, spatial estimation of proxies for geometallurgical properties and responses is complex and requires special consideration. Unlike grades, both proxies and absolute measures of geometallurgical variables are not necessarily linear or additive and therefore require very careful geostatistical consideration. In some cases, models must predict extreme values of geometallurgical attributes rather than averages. Incorrect characterisation of metallurgical recovery/throughput can (and has) led to misspecification of the scale of projects, and thus can be seriously value destructive. Aspects of geometallurgy have long been important in iron, bauxite, manganese and coal deposits and are increasingly on the radar for base and precious metal miners. However, as more metallurgically complex deposits are developed and mining of large-scale, low-grade deposits becomes more commonplace, the importance of characterising the metallurgical response in order to generate properly optimised projects will rapidly increase. It is possible that in many `traditional' (ie grades and tonnes) reserve models, the variables that drive the project are missing!

Jan 1, 2007

By L. E. Salinas-Farran, S. J. Neethling

Key variables in heap leaching include permeability, mechanical stability and mass transport. All of these properties can be manipulated by agglomerating and curing the ore before stacking it into heaps. The chemical and structural evolution of the agglomerates during curing is key to improving agglomerate properties and, ultimately, heap performance. It is possible to image the internal structure of agglomerates using SEM/EDX (e.g. QEMSCAN or MLA), although these methods are destructive and do not represent the 3D structure of the agglomerates. A non-destructive alternative is to image the agglomerates using X-ray Microtomography (XMT). Not only does this provide 3D information, it also allows the same samples to be repeatedly scanned, allowing the time evolution of the agglomerate structure and chemical composition to be tracked. In this paper we compared the behaviour of ores agglomerated using a combination of sulphuric acid and ferric sulphate with ones in which chloride ions are added to the recipe, since chloride leaching is gaining in popularity as a chemical alternative to bioleaching for sulphide ores. We tracked the curing process beyond the typical time scales to see the impact that this has on both the agglomerate structure and the subsequent leaching behaviour. Keywords: Heap leaching, curing extent impact, leaching kinetics, ferric-chloride leaching

Jan 1, 2020