Search Documents

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2004

By M. Tadayonsaidi

The effect of alloying elements on the mechanical properties and thermal expansion of 336 casting alloy usually used as piston alloy which has low thermal expansion and very good high-temperature mechanical properties and good wear resistance was investigated. The mechanical properties and thermal expansion characteristic of samples with different combination of alloying elements, which enhance to reduce the cost of products, have been studies, The results show remarkable increase in the mechanical properties with increasing the amount of Cu and Mg, while are reduced with increasing amount of Ni, On the other hand, the use of eutectic aluminum alloy as 336 alloy with higher percent of Cu and Mg and lower percent of Ni are recommended for industry, due to economical viewpoint and satisfactory properties.

Jan 1, 2005

By C. H. G. Bushell, G. Brown, C. J. Krauss

1N FLOTATION, copper sulphate is used universally for the activation of sphalerite and marmatite and, to some extent, for the activation of other minerals. The copper activated surface readily adsorbs standard collectors such as the xanthates and dialkyl dithiophosphates whereas untreated zir~ sulphide does not. With the host of reagents available, making a mineral float is seldom difficult. The problem is to achieve selective flotation. In zinc flotation, the great value of copper sulphate results from its ability to activate zinc sulphide preferentially to gangue minerals. At the Sullivan Concentrator of The Consolidated Mining and Smelting Company of Canada Limited, the most abundant gangue mineral in the lead-zinc ore is pyrrhotite, and the zinc mineral is marmatite of somewhat variable zinc to iron ratio. For this Cominco study, selectivity between marmatite and pyrrhotite was therefore the most interesting aspect of copper sulphate activation.

Jan 1, 1961

"The outlook for Eastern Canada is decreasing coal production over the next few years; however, a reappraisal of the long-term requirements and increased prices of coal could lead to a revitalizing of the industry. The market for Western coal is expanding and is expected to exceed 50 million tons per year in the metallurgical and thermal power fields. Western coal reserves are currently estimated at 119 billion tons. Technical developments in Eastern Canada include a shearer and gate-end support system to mechanically cut the stall and brushing at the tail-end of a longwall. In Western Canada, the most modern equipment is used in mining, beneficiating and shipping coal. Results to date on the underground hydraulic experiments exceed expectations. The importance of reclamation is recognized and plans have been made to restore and re-vegetate disturbed areas and mine dumps. In Eastern Canada, experiments were started to determine the feasibility of coal reclamation from mine dumps, including one dump that is on fire. The Mining Research Centre, Mines Branch, continued to conduct research work oriented toward solving Canadian mining problems The Western office of the Centre, opened in 1970, was set up primarily to study problems associated with a resurgent coal industry."

Jan 1, 1971

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By Jin Liu, Torstein A. Utigard

At its Copper Cliff Smelter, Vale Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. Coke supplies a minor proportion of the process heat requirements, limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Extensive experiments were conducted in a miniplant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. The introduction and description of the experimental set up were given in Part 1 of this paper and an early paper published in Yazawa symposium1 together with the results and some in depth discussion on metallurgy. This paper intends to discuss the kinetics of the miniplant flash furnace testwork.

Jan 1, 2015

By Herbert D. Drechsler, James B. Stephenson

"AbstractThe paper identifies the major components of price change which affect the determination of the internal rate of return of a mining project. It illustrates several price indexes which may be used to measure general price increases, identifying techniques which might incorporate them into mine valuation procedures. The ""hurdle rate"" for new investment is discussed.IntroductionDECISIONS regarding the value of an orebody and whether or when to mine an orebody are based on an estimate of the cash flows which would be associated with its exploitation. These pro-forma cash flows represent cash in or out of a possible mineable deposit and include exploration and construction costs, sales revenues, operating expenses, taxes, debt borrowings, interest and debt repayment. It has long been recognized that when combining the cash flows occurring over the life of the mine, dollars received or paid out early have greater value than those received or paid out later. This time value of money has been incorporated into mine evaluation calculations through the use of present-value or discounting techniques. Another factor affecting mine valuation, inflation, is not accounted for by valuation techniques now in use. In recent years, price changes have become more volatile. In the past, price change could easily be ignored when evaluating potential mines. Today, the combination of larger investments and greater price volatility leads to great concern about the effects of price change on mine valuation."

Jan 1, 1977

By M. R. Hegge

The Jabiluka One and Two uranium deposits occur in Lower Proterozoic metasediments of the Cahill Formation, which is part of the Pine Creek Geosyncline in the East Alligator River area, Nothern Territory. The Jabiluka One deposit coincides with a "window" through unconformably overlying Middle Proterozoic sandstone of the Kombolgie Formation; Jabiluka Two is completely covered by that sandstone. The observed part of the Cahill Formation exhibits four horizons which are favourable hosts for uranium mineralization. These have been folded into an east-southeast-striking, gently plunging, open asymmetric syncline-anticline structure. The host rocks are mainly chlorite and/or graphite schists and their brecciated equivalents which have undergone initial regional prograde metamorphism to the amphibolite facies, then retrograde metamorphism to the greenschist facies. Mineralization consists of pitchblende, mainly filling open spaces and to a lesser extent in disseminated form. Chlorite, pyrite and quartz are commonly associated with the uranium mineralization. A portion of the Jabiluka Two deposit contains economic concentrations of gold. Structural preparation with low-pressure conditions at these sites appears to be the most significant ore control. Genetic hypotheses favour initial deposition in Lower Proterozoic sediments, followed by remobilization during later orogenic events. The deposits bear a marked similarity to some pitchblende deposits in central Canada.

Jan 1, 1977

By F. K. McKean

Abstract A discussion of the difficulties involved in the production of a clean molybdenite concentrate introduces the paper. There is a brief description of the various methods for producing molybdenite that will fit marketing specifications, and it is shown how these methods are nor suited to the milling of ores containing small quantities of bismuth and copper. A process that was developed in the ore testing laboratories of the Bureau of Mines at Ottawa for the La Corne mill of the Molybdenite Corporation of Canada is described in derail and some results from pilot plant operation of this milling scheme are tabulated. A description of the La Corne mill, where the writer supervised the introduction of the process on a commercial scale, adds to the interest of the paper. In conclusion, there is a review of the conditions necessary for proper operation of the flowsheet. An attempt is made to show how the process might be satisfactory in other problems similar to that at the La Corne mill. Introduction The production of a molybdenite concentrate, free from impurities and high in grade, has been a difficult task when milling some types of ore. Whereas ordinary flotation techniques will produce acceptable concentrates of the baser sulphides, in many cases they will not serve in the treatment of molybdenite, for this mineral must be of optimum grade and purity to bring the best prices, or to find a market at all . Faced with the necessity of meeting stringent specifications, the mill operator has been forced to employ expensive processing methods, and to be satisfied with low recoveries, in order to make grade with his product. The most objectionable and common impurities found with molybdenite are: (a) gangue minerals and iron sulphides, which lower the grade; and (b) copper, bismuth, or antimony, which are deleterious in the final uses of the molybdenite products. It is difficult, and sometimes impossible, to market a concentrate with over 0.5 per cent of any of the latter impurities, or with a grade much below 90 per cent MoS2. Various methods, which have been highly successful in specific applications, have been developed to meet the problem of producing a suitable concentrate. All of them, however, have certain defects precluding their use when treating ores of a nature different from the one for which they ? were designed. The writer has developed a process for molybdenite ores having an objectionable impurity content. A description of the procedure involved, and of the La Corne mill of the Molybdenite Corporation of Canada, where the process has been adopted, should be of interest to flotation operators.

Jan 1, 1947

By G. Chahal, L. C. So, S. Faucher, S. Mostaghel, S. -Y. Oh, S. K. Lee

Slag dumping and water granulation are the most commonly used slag treatment methods in the metallurgical industries. In both processes, water is present (by desire for cooling and dispersion or as a result of rain accumulation) and thus equipment and operations are designed to minimize and mitigate the risk of steam explosions resulting from the inappropriate contact of slag with water. Slag handling practices have, therefore, never been inherently safe; even good design, operation, and maintenance are not sufficient to prevent explosions or other related injuries from occurring. For slag handling to become inherently safe, our industry must eliminate the potential contact of water with molten slag. This is today feasible with the advent of dry granulation technologies, a review of which is presented, and it thus falls to us, in the metallurgical sector, to lead the way in their final stages of development and adoption. Furthermore, while slag dumping and water granulation offer some metallurgists the means of valorizing their slag as a by-product, for most, this is not the case. The energy in slag is lost through dumping and water granulation processes, and where slag is sold as a by-product, it is for its chemical content only. Here, dry granulation processes also offer advantages including the production of by-products which hold value in both their chemical content and physical properties and heat recovery. Dry granulation, therefore, augments the methods by which slag may be valorized over traditional processing methods.

Jan 1, 2015

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Testwork was conducted in order to compare the effectiveness of carbon based catalysts while oxidizing a gold-bearing pyrite concentrate under atmospheric conditions. Without the use of a catalyst the oxidation of pyrite was incomplete after 96 hours, resulting in roughly 60% pyrite oxidation. Furthermore the resulting sulphate yield from unassisted pyrite oxidation ranged between 72 and 84%. It is evident that atmospheric oxidation of pyrite is not viable due to slow oxidation kinetics and high sulphuric acid production when using a ferric sulphate media without a catalyst. The effect of two different carbon based catalysts, one Lewatit® AF 5 a new microporous carbonaceous bead, and the second a granular coconut shell based activated carbon, were tested under the same oxidation conditions as the unassisted pyrite tests. After 96 hours, Lewatit® AF 5 assisted oxidation showed approximately 96% pyrite oxidation with a sulphate yield ranging between 26 and 35%, while the activated carbon assisted oxidation reached approximately 100% pyrite oxidation with a sulphate yield between 36 and 37%. Testwork indicated that not only does the addition of a carbon based catalyst greatly improve the oxidation kinetics and lead to almost complete oxidation, the sulphate yield is also drastically reduced, resulting in very high elemental sulphur yields.INTRODUCTION Pyrite is an important sulphide mineral due to its ability to contain invisible gold concentrations up to 132 g/t (Chryssoulis & Cabri, 1990). As a result, ores composed of only a small amount of pyrite still have the ability to contain high gold grades. This refractory gold cannot be accessed via conventional gold leaching processes, such as cyanidation, and additional oxidative pre-treatment is required to liberate the gold, making it more amenable to extraction (Marsden & House, 2006). Current oxidative pre-treatments do exist consisting of both pyrometallurgical and hydrometallurgical processes including high temperature and high pressure leaching within autoclaves, biological atmospheric leaching and roasting. Autoclaves are a proven process reaching desirable recoveries within approximately a 1–2 hour retention time, due to the increased temperatures and pressures, allowing for an increase in dissolved oxygen (Marsden & House, 2006). The typical reaction for pyrite oxidation within autoclaves is presented in Equations 1, 2 and 3."

Jan 1, 2017

By A. Mosqueda Martinez, L. C. Trytten, R. P. Kofluk, J. J. Budac

The Corefco ammonia leach nickel refinery treats Ni-Co mixed sulphides from the high-pressure acid leaching of Moa Bay nickel laterite. Due to the low iron content of the feed, the ammonia leach process generates a leach residue with ~10% Ni+Co. Since commissioning a leach residue pressure filtration circuit in 2002, this residue has been stockpiled, dried, and sold commercially. For several years, the residue was sold to nickel smelters overseas. In 2014, re-processing of the residue in the high-pressure acid leach was tested. Lab test work was completed showing excellent extraction of the contained nickel and cobalt, and additional beneficial effects in the high-pressure acid leach circuit. A plant test in Moa confirmed the results, and preparation for shipment of the valuable leach residue for re-processing has begun. This paper outlines the test work and results, and some commercial considerations.

Jan 1, 2015

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015

By Sergio Cattalanl, Francis Chartrand

"The geology and origins of volcanogenic massive sulfide (VMS) deposits in the Abitibi belt of northwestern Quebec have been the subject of discussion since the discovery of the Horne orebodies in Noranda in 1923.The present Noranda version of the VMS model characterizes the ideal deposit as a stratabound, base-metal accumulation that is in close spatial relationship with hydrothermal alteration and stockwork zones, felsic lava domes, coarse phreatic-pyroclastic breccias, and subvolcanic intrusions that characterize vent- and proximal{acies submarine volcanic environments. Deposits tend to occur in a favorable stratigraphic interval within a mining camp, and this is well-documented in the Rouyn-Noranda and Matagami camps.However, in recent years many VMS deposits have been shown to deviate from the ideal Noranda-type. For example, the Ansi/ deposit is characterized by sulphide-bearing alteration zones that extend far above the massive sulfide lenses, and by abundant magnetite immediately underlying massive sulfide. The Horne deposit appears to lack the typical chloritic alteration pipe underlying the massive sulfide lenses, as well as laterally-equivalent exhalite horizons. The Horne and Quemont deposits, besides being the two giants of the camp, are particularly rich in gold, whereas others, such as WaiteAmulet and Millenbach, have low gold values. Finally, some deposits in the Noranda camp, such as the Ansil, Corbet and Mobrun mines, are outside the favorable stratigraphic interval. Therefore, it would appear that part of the key to renewing base metal reserves in northwestern Quebec is the use of evolving descriptive-genetic models that incorporate geological variations like those cited above."

Jan 1, 1990

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977

By A Frydrychewicz, J. Mirza, J. Lipkowski

The objective of this work was to understand the mechanisms of action of additives, such as thiourea, that enhance gold leaching in thiosulfate solution. The leaching reaction and surface passivation were investigated using linear sweep voltammetry. Leaching currents were determined using analysis of current-potential curves and the mixed potential theory. The gold-electrolyte interface was further characterized with surface enhanced Raman spectroscopy. The results show how thiourea prevents formation of oxysulfur compounds, which passivate the gold surface. Other molecules such as 3- m ercaptopropionic acid and L-cysteine were also studied as possible additives to prevent passive layer formation.

Jan 1, 2011

By Euler De Souza, J. Daniel Stinnette, Julian Varaschin

"This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and of electric equipment and examines how they can be applied in determining reasonable ventilation rates for Tier IV compliant diesel equipment and for electric equipment operating in mining environments. Airflow calculations for modern diesel-powered equipment and for electric equipment are more complex and must be based on a combination of factors that are unique to each mine. Methodologies for ventilation rate determinations for each case are proposed in this paper.INTRODUCTIONTraditionally, airflow requirements for production and support equipment operating in underground mines have been determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations or determined empirically from known quantities. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is still a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. The question remains, what ventilation rates should the ventilation system designer apply for modern diesel equipment?Also, given the ongoing development of grid/battery-electric equipment and active construction of fully electric mines, it has become critical to determine adequate airflow rates per brake kilowatt of electric engine power. One of the most important criteria for determining ventilation rates for electric equipment is the amount of heat they generate, as this is the most significant emission produced by electric equipment (which do not produce exhaust gases or particulates). Therefore, ventilation rates required to dissipate heat from electric equipment must be suitably determined for all electric vehicle fleets operating in underground mines."

Jan 1, 2019

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By J. Asfahani

"The inverse slope method (ISM) was applied to reinterpret vertical electrical soundings (VES) data from pits at the Al-Sharquieh phosphate mine, in order to demonstrate applicability and suitability of the ISM for interpreting VES data from sedimentary phosphatic environments. The ISM overcomes limitations of the curve matching method and the complexity of lithological sections. The ISM geo-electrical interpretation results correlated well with lithologies of the pits. This method characterized resistivity and thickness of the phosphatic layer, and identified favourable phosphate-prospecting areas using the newly developed thickness/depth parameter. The ISM is recommended for interpreting VES measurements in similar sedimentary phosphatic regions.RÉSUMÉ La méthode d’inversion de la pente (ISM) a été utilisée pour réinterpréter les données de sondages électriques verticaux (VES) effectués dans des puits de la mine de phosphate Al-Sharquieh, afin de démontrer l’applicabilité et la pertinence de cette méthode pour interpréter les données VES dans des environnements de sédimentation de phosphates. Cette méthode (ISM) surmonte les limitations de la méthode de comparaison de courbes et la complexité des sections lithologiques. Les résultats de l’interprétation géoélectrique ISM correspondaient bien aux lithologies des puits. Elle a permis de caractériser la résistivité et l’épaisseur de la couche phosphatique et d’identifier les secteurs favorables à la prospection pour le phosphate en utilisant le paramètre nouvellement développé épaisseur/profondeur. ISM est recommandée pour l’interprétation des mesures VES dans des régions semblables où se trouve du phosphate sédimentaire."

Jan 1, 2016