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By S. Markstrom

The Boliden AITIK copper mine is located 100 kilometres north of the Arctic Circle in northern Sweden. A pre-feasibility study was conducted in 2005 with the aim of increasing the capacity of the existing processing plant. After analysis, options to upgrade the existing plant were abandoned in favour of building a new processing plant, with higher capacity and therefore greater profitability. A new plant could be designed with greater flexibility to make potential future expansions easier. A feasibility study for a new 36 Mt/y processing plant including fully AG grinding circuits and flotation was completed in 2006. The project was approved by the Boliden board shortly thereafter. Construction started in the beginning of 2007 and was completed during 2009. Commissioning of the new plant was undertaken in the first half of 2010. The grinding circuit consists of two lines with each line consisting of a 22.5 MW AG mill and a 10 MW Pebble mill in closed circuit with a spiral classifier. The nominal production level is 2 200 t/h for each grinding line. This paper presents the start-up and operation of the grinding circuit.

Jan 1, 2012

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By Steven Aiken

The East Boulder Mine located in Montana, U.S.A. utilizes snowmaking to assist with mine water treatment for nitrogen removal. Nitrogen species, including ammonia, are common contaminants in mine water from underground mining operations. Snowmaking provides secondary treatment of nitrogen during the winter due to the chemical and physical processes that occur during snowmaking, in the snow pack and in the snowmelt. The primary processes include atomization, evaporation, sublimation and volatilization. The snowmakers also provide secondary treatment for nitrogen removal when used as evaporators and/or land application units during the summer. In 2002, the snowmaking process was successful at reducing total nitrogen in the mine water by up to 87%. If additional losses due to soil and root zone processes are included, total nitrogen reduction would increase to between 87 and 97%. Snowmaking is an effective nitrogen reducing treatment method during the winter when other treatment methods such as land application cannot be used.

May 1, 2004

By Jörgen Appelgren

Atlas Copco, a leading supplier of equipment and services to the mining and construction industries, is consistently pursuing its strategy to offer the most productive and economical solutions by continuously offering new innovative products. These are in most cases developed and tested in close cooperation with demanding end users before being officially launched on the international market. The demands for higher productivity and improved overall economy have resulted in systems for automation of the drilling cycle and also tools for integrating the Drilling equipment to the production control system used by the customer. In terms of improving the blasted material quality, Atlas Copco has placed emphasis on hole straightness and the need for hole logging and positioning. By applying state of the art technology to today?s computerized drilling rigs, major steps in improving overall drilling and blasting performance have been achieved. This paper will give some examples derived from the latest development of solutions for the Rotary drilling product line.

Oct 1, 2009

By Ning Yu

There are about 1.341 trillion tons (t) of proven coal reserves in China, of which 279.58 billion t are available for mine well construction basis. Thick coal seams are 44% of the reserves. The production of thick coal seams exploitation is over 45% of the total coal production. Full-seam mining and fully-mechanized mining for large mining height is the technology development direction of thick and extra thick seam mining. It is also the important way to achieve efficient and intensive mining with the characteristics of high production, high mechanization, high efficiency and low energy consumption, etc. Complete set of technology and equipment of fully-mechanized top caving for large mining height of full-seam (7m) mining and extra thick seam ( 14-20m) has been gradually mature and for demonstration application by the joint research of government, enterprises, universities, scientific research organizations and users. It has solved some technical problems of coal face for large mining height (over 7m) such as the coal wall spalling control, stability of support, wall rock coupling, cooperation work of mining and caving, full roadway support for super large section, end support, equipment matching of coal shearers, hydraulic support and scraper conveyor. It has developed key equipments including powerful hydraulic support of fully-mechanized mining and fully-mechanized top caving for large mining height, electrically-driven coal shearer with high speed and reliability, scraper and belt conveyer with big capacity, soft-start and high reliability, automatic control system of coal face with the core of electric-hydraulic control, bolting drill boom large section coal roadway shearer, heavy auxiliary transport equipment. The operation rates of fully-mechanized top caving equipment for full-seam and large mining height are 94% and 92.1%, and recovery ratios are 93.6% and 88.9% respectively. The annual raw coal production of single work face is over 10 Mt. The automation and intelligentization level have been clearly improved. The exploitation of thick and extra thick coal seam that is safe and efficient has been achieved in China.

Aug 1, 2013

By William C. Boggis

EKATI? Diamond mine is located 300km northwest of Yellowknife and 200 km south of the Arctic Circle in the Northwest Territories of Canada. The site is a remote tundra area with continuous permafrost and is in the Canadian Shield. EKATI? is the first diamond mine in Canada and is operated by BHP Diamonds Inc., which is a part of BHP Minerals. BHP Diamonds Inc. is an incorporated company based in Vancouver, BC. The mine is a joint venture of BHP Diamonds Inc. (51%), Dia Met Minerals Ltd. (29%), Charles E. Fipke (10%) and Dr. Stewart L. Blusson (10%). The mining area lies within the 10,960 ha land leases held by the joint venture. The total claim block covers 344,000 ha. To date over 136 kimberlite structures have been identified within the claim. Five of these provide the basis for the present mine plan with three others identified for future inclusion. At full capacity the mine will produce 4.5 million carats per year, approximately 4 % of world production and employ approximately 600 people, with over 33% being Aboriginal from the Northwest Territories.

May 1, 2001

By C. Sartain

In recent years market pressures have been building on companies to develop the next era of mining projects to follow the previous boom in copper projects of the mid 90's. However the response from the industry has been slow in coming, and somewhat muted. It is clear that there simply have not been the obvious quality projects waiting to be rapidly developed. Many of the known undeveloped copper projects have particular characteristics that have previously prevented their development, including mineralogical complexity in the ore bodies, environmental challenges or particularly difficult geographic locations. This paper describes how the Copper Division of an international mining company, Xstrata plc, is preparing to progressively develop an impressive pipeline of projects, armed with an array of proprietary technologies and with a strong approach towards sustainable development and community engagement. The approach being taken is enabling Xstrata to complement its acquisitive corporate philosophy with a management emphasis on project development and operational optimization and enhancement.

Jan 1, 2007

By W. D. Gould, F. Goodazi, W. F. A. Duncan, A. G. Mattes

A biological treatment system designed to passively remove high concentrations of metals from leachate collected from a landfill near a large integrated zinc lead smelter has been in operation intermittently for the past five years including winter time operations. High metal removal efficiencies in the system were achieved. After 729 days of operation and treating over 8 million L of water the original anaerobic bioreactor constructed in 1997 was taken apart and rebuilt. The deconstruction of the bioreactor allowed systematic sampling at all depths of the biological matrix. Samples were analyzed for metal, S and TOC concentrations; as well bacterial populations were determined. Results of this sampling procedure are examined and compared at various depths within layers and between layers using one-way ANOVA and linear regressions. Metal concentrations were positively correlated with sulphur and negatively with total organic carbon. This is in concurrence with a model of biogenic precipitation of metal sulphides.

Jan 1, 2004

By M. Wittke

"In the course of the extension of the railway network in Israel, currently the two 4.6 km long tubes of the Gilon Tunnels on the line from Akko to Carmiel are being constructed. The tunnels run through the limestones of the Bina- and Yirka-formations, which locally are karstified. The maximum overburden amounts to 160 m.The limestones are mostly horizontally bedded and vertically jointed. Occasionally also inclined joints exist. The tunnels cross various fault zones, which mostly strike at an acute angle to the tunnel axis and are steeply inclined. The karstic cavities which were encountered during tunneling have partially been filled by clay. In the vicinity of the fault zones, the rock has often been strongly jointed and weathered respectively. The two single-track tubes have a cross section with vertical walls and an open invert. The tubes are connected by cross cuts with a spacing of approx. 250 m.During the tender phase, WBI has elaborated the tender design for a joint venture of a Chinese and an Israeli construction company. After the joint venture had been awarded the contract, the preliminary and the detailed design have been elaborated by WBI and the construction works have been guided. On the basis of the geological description, rock mechanical models have been elaborated, followed by stability analyses on the basis of the Finite Element method. The tunnels have been excavated according to the shotcrete method. The support in most areas only consisted of a very thin shotcrete lining and radial bolts in the area of the roof. Depending on the degree of jointing and weathering, locally advancing support by means of spiles has been applied.The internal lining of reinforced concrete has been constructed in parallel to the heading of the tubes. Mucking and delivery of materials was carried out through the cross cuts.The breakthrough was achieved in April 2014 and thus within schedule. The predicted distribution of the excavation and support classes along the tunnel has been in good agreement with reality."

Jan 1, 2015

By Abdurrahman Tosun

It is very important for after blasting processes that muck pile fragmentation is predicted and controlled during blasting. Therefore, a significant research effort has been devoted to the development of mathematical equations that predict the value of average muck pile fragmentation. The specific charge parameter used in all of these equations is determined as the ratio of the total mass of explosives used to break a volume of rock. The length of blast surface and the row number of the blasthole are ignored in the calculation of the specific charge. However, in a blasting operation, blasthole geometry may result in additional material being impacted by a blasthole. This is due to effect shares of in both end sides of blastholes and the back region of blasting surface. In this study, a total of 14 blast tests, 8 at the first quarry and 6 at the second quarry of the Bati Anadolu (Western Anatolia) Cement Factory, were performed. In each study area blast tests were designed in the same direction continuously to provide stable structural properties of the rock. Therefore muck pile fragmentation depended on only specific charge values for each blast tests. Specific charge values were calculated according to both an average blasthole and also the total volume of material occurred as a result of blasting for each blast tests. During loading until the end of blasted material the front, the back, the arm off and the bucket off pump hydraulic pressure values occurred in hydraulic pistons of the loader were determined with a lot of data received for each blast tests. After that the relationships between specific charges values obtained according to two different methods and hydraulic pressure values of the loader were established with two correlations. The relationships between specific charges values obtained according to the total volume of material occurred as a result of blasting and hydraulic pressure values of the loader occurred as the best results especially the blasting operations that have the total length of blasting surfaces are short.

Aug 1, 2013

By A. A. Nourbakhsha

The main application of refractories based on andalusite in ferrous metallurgy are in air heaters of blast furnaces, mobile mixers, and hot-metal transfer, pig iron ladle, steel-casting, and intermediate ladles. Three specific properties of andalusite are very interesting for the production of high-quality shaped and unshaped mullite refractories: being free of water, its crystal a remains stable without changing its density or volume after firing and therefore has no internal porosity .Graphite additives due to its great wetting ability play an important role in raising the property of refractory bodies. In order to improve properties of andalusite graphite bodies, oxidant agent for increasing in hot strength and oxidation resistance can not be avoided. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time, undischarged pig iron ,penetrated pig iron are the main ones.Literature studies showed that the graphite addition help to thermal shock resistance and liquid penetration(steel,pig iron) effect. In this research particle size distribution of aggregates containing andalusite and graphite determined by andreazen equation. Then different mixes with different percentage of graphite,Si, FeSi, SiC prepared by uniaxially pressing under 1500kgf/cm2 pressure by adding 4%wt novalak resin and 0.4%wt HMTA as hardner. Samples fired at 1100-1500oC under reduction atmosphere. According to specific standards density, porosity and CCS measured. Analytical tests such as XRD, SEM were carried out on sample selected from point of view of mechanical properties at different temperatures. Results showed that optimized amount of Si and Fe-Si for _-SiC formation in body is 4 and 6 %wt respectively at 1500OC. XRD and SEM analysis on sample with Fe-Si additives showed no destructive phase through the matrix, also SiC additives not only increase oxidation resistance but also no effect on thermo-mechanical properties.

Oct 1, 2011

By W. R. Dodge

THE growth and development of the assay department of the Hollinger Consolidated Gold Mines, Limited, is a similar story to that of the mine itself. As the mine developed and enlarged, so also increased the demands upon this department, necessitating an increase of capacity for fire assaying and a widening of the scope of work to include chemical analysis, metallurgical tests, research, and screen analysis. The yearly total of determinations, taking an average for the past six years, is approximately 350,000. The major portion of this figure represents fire assaying for gold and silver, being approximately 950 fire assays per day. The assay department occupies the ground floor of the administration building and covers approximately 4,000 square feet of floor space. Ready access is had by motor truck and electric railway for the delivery of samples and the removal of crushed rock and rubbish. The combined weight of all sample rejects amounts to about 5,000 lb. per day, which is sent to the mill bins. There are six departments, each occupying a separate room-grinder room, fluxing room, furnace room, parting room, weighing room, and flux-mixing and storage room.

Jan 1, 1931

By C. W. Hancher, B. D. Patton, W. W. Pitt

"There are a number of nitrate-containing wastewater sources, as concentrated as 30 wt % NO3 and as large as 2000 m3/day, in the nuclear fuel cycle. The biological reduction of nitrate in waste water to gaseous nitrogen, accompanied by the oxidation of a nutrient carbon source to gaseous carbon dioxide, is an ecologically sound and cost-effective method of nitrate waste disposal. These nitrate-containing wastewater sources can be successfully biologically denitrified to meet discharge standards in the range of 10 to 20 g N(NO3-)/m3 by the use of a fluidized bed bioreactor. The denitrification bacteria are a mixed culture derived from garden soil; the major strain is Pseudomonas. In the fluidized-bed bioreactor, the bacteria are allowed to attach to 0.25- to 0.50-mm-diam. coal fluidization particles, which are then fluidized by the upward flow of influent wastewater. Maintaining the bacteria-to-coal weight ratio at approximately 1:10 results in a bioreactor bacteria loading of greater than 20,000 g/m3,This paper describes the results of a bio denitrification R&D program based on the use of fluidized bioreactors capable of operating at nitrate levels of up to 7000 g/m3 and achieving denitrification rates as high as 80 g N(N03-) per day per litre of empty bioreactor volume. IntroductionThe discharge of wastewater containing nitrate at concentrations greater than stipulated by the Environmental Protection Agency (EPA) creates an environmental hazard and constitutes a civil and/ or criminal legal liability.(I.2) At present, we have three options: (1) recycle and reuse of nitrate streams the total economic and technical balance should be Closely examined; (2) use of an alternative acid, which may pose an entirely different set of problems ; or (3) disposal of nonreusable nitrate sources by an environmentally acceptable procedure."

Jan 1, 1980

By J. G. Schofield, R. C. Francki, K. M. Donaldson, F. E. Ham

"Developments in pyrometallurgical technology have led to larger furnaces operating under more intense process conditions. In order to maintain the reliability of these furnaces, which are frequently single-line units, the design of the refractories, cooling systems and bindings has become more critical. Traditional thermal and chemical requirements for the refractory to resist slag attack must still be carefully determined. The larger, modem furnaces have placed a new emphasis on the structural properties of the refractories as well as their thermal properties to suit the extensive cooling systems. Based on operating experience, supported by computer models, the refractories and bindings are designed to work together to accommodate the thermal expansions and contractions in order to minimize permanent furnace growth and the risks of leaks. IntroductionElectric furnaces are used extensively in smelting copper and nickel ores and concentrates. Laterite nickel ores and high-magnesia copper, nickel and platinum sulphide concentrates are smelted virtually exclusively in electric furnaces to accommodate the high melting point of the slags produced. Although a number of smelting processes using oxygen-enriched and/or preheated air have been developed to replace reverberatory furnace smelting of conventional copper and copper-nickel concentrates, (lnco, Noranda, Outokumpu, Mitsubishi) electric matte furnaces remain a strong process alternative for these concentrates, either as the primary smelting vessel or for cleaning the slags produced from these processes.The development of large, high-powered furnaces has been an important factor in the growth of electric smelting technology, as evidenced by the list of operating matte and ferronickel furnaces shown in Table I. Because the compressive forces required to maintain a tight, leak-free furnace increase with furnace dimensions, the selection and design of the furnace refractories, cooling systems and bindings require increased attention."

Jan 1, 1993

By J. R. Morris, A. E. Ball, G. W. Kuzyk

"AECL Research has constructed an underground laboratory for the research and development required for the Canadian Nuclear Fuel Waste Management Program. The experimental program in the laboratory will contribute to the assessment of the feasibility and safety of nuclear fuel waste disposal deep in stable plutonic rock.In 1988, AECL extended the shaft of the Underground Research Laboratory (URL) from the existing 255 m depth to a depth of 443 m in cooperation with the United States Department of Energy (USDOE). The project, which involved carrying out research activities while excavation and construction work was in progress, required careful planning. To accommodate the research programs, full-face blasting with a burn cut was used to advance the shaft. Existing facilities at the URL had to be modified to accommodate an expanded underground facility at a new depth. This paper discusses the design criteria, shaft-sinking methods and approaches used to accommodate the research work during this shaft extension project.IntroductionThe Underground Research Laboratory (URL), a major geotechnical research facility, has been developed by AECL Research, 120 km northeast of Winnipeg, Manitoba. The URL is part of the Canadian Nuclear Fuel Waste Management Program (CNFWMP), which is assessing the concept of nuclear fuel waste disposal in a vault deep in stable plutonic rock of the Canadian Shield (Hancox, 1986). The URL provides a representative environment to conduct a wide variety of geotechnical research relevant to nuclear waste disposal. Extensive characterization and monitoring programs were carried out prior to construction and will continue during operation. The operating phase experiments began in 1989 and will continue until the year 2CXXl (Simmons, 1990). Figure I shows the present extent of the URL facilities and the proposed future development."

Jan 1, 1991

By R. C. Lo, M. D. Scott

"This paper reviews tailings management at Highland Valley Copper, and outlines main features of its tailings storage facility enclosed between the H-H and L-L dams. Key management focusses are: energy efficiency, cost effectiveness, safety and integrity of the tailings impoundment, environmental protection, and reclamation after decommissioning. Main features of the tailings facility include: high international standards for seismic and flood design criteria, water management and water quality monitoring, operations and construction optimization, reclamation and decommissioning plan, and geotechnical challenges associated with the complex geology of the L-L tailings dam foundation.IntroductionHighland Valley Copper stores its tailings mainly in the Highland Valley tailings facility (ultimate capacity: 1.8 billion tonnes). Smaller tailings storage facilities were operated by predecessor companies: the Number One Pond, the Trojan Pond at Bethlehem and the Highmont Pond at the Highmont operation as well as backfilling the Heustis and Jersey lona Pits at Bethlehem. These areas are currently not in use, and are in the reclamation phase prior to decommissioning. This paper focusses on tailings management in the main facility. As indicated in Figure I, the facility includes three tailings dams: these are, going from east to west, the H-H, J-J and L-L Dam, named after the alignment alternatives in the initial feasibility studies. From 1970 to 1977 Canadian Bechtel Ltd. advised Highland Valley Copper's predecessor company Lornex, on tailings storage at the H-H and J-J Dams and on the L-L Dam. Since the completion of the L-L Starter Dam in 1977, Klohn Leonoff Ltd. has provided ongoing consultation and construction monitoring of the raising of the L-L and the H-H Dams. The J-J Dams is currently buried by deposited tailings. This paper reviews key tailings management focusses and main features of the tailings facility."

Jan 1, 1992

By M. Gauthier, A. C. Brown

"Monometallic zinc mineralization associated with marbles of the Grenville Supergroup in the Mont-Laurier Basin of Quebec is found to be stratiform and to occur (1) within limited zones of dolomitic marble and (2) more precisely along contacts between these marbles and adjacent metaclastic units. Massive sphalerite with accompanying pyrrhotite and pyrite is the prime exploration target, and commonly gives rise to good geochemical anomalies, but generally weak and ambiguous geophysical responses. Disseminated sphalerite in dolomitic marbles may signal proximity to interesting massive mineralization, although, due to weathering, this broadly disseminated mineralization may not be detected easily on outcrops. It is concluded that the western and possibly the eastern margin of the Mont-Laurier Basin constitute favourable areas for continued exploration.IntroductionThe Grenville Supergroup marbles of Ontario, Quebec and New York State host numerous occurrences of zinc mineralization (Fig. I) , several of which have been periodically mined since the beginning of this century (Fig. 2). The Balmat Edwards district of New York is the giant of this depo sit-type, with the production since 1915 of some 20 million tons of ore grading 10% zinc, and acknowledged current reserves of approximately equal tonnage and grade. At present, there is renewed interest in the potential for similar mineralization throughout the Grenville Supergroup, and this paper outlines some of the geological, geochemical and geophysical guidelines that may be employed in the search for new ore. The geologic guidelines are derived especially from lithologic and stratigraphic features which survived intense, multiphase deformation and metamorphism.Although major portions of the extensive Grenville Supergroup hold potential for zinc mineralization, the present study is confined to a known zone of mineralization in the Mont-Laurier Basin of Quebec. Concurrently, we are compiling information on the regional metallogeny of the basin so that our conclusions can be applied to areas of similar Grenville Supergroup host-rocks elsewhere."

Jan 1, 1980

By G. A. Buckland

"The development, in Ontario, of a common industry-wide program for the development of skills for employees in underground hard-rock mining is described. This program is designed to increase the productivity of individual workers by improving their skill levels, while at the same time ensuring that employees are instructed in the requisite safety and health aspects of performing various underground tasks. The program's development through a management-labour-government tripartite approach is described. How this program was coordinated with new Government Regulations on Occupational Health and Safety dealing with mandatory training of underground employees is also outlined. IntroductionThis paper will describe briefly what modular training is all about and outline why, and how, it was developed in Ontario on an industry-wide basis. Simply stated, what's been accomplished to date is an industry-wide program for developing the mining skills of underground production employees.The basic objective of this program is to improve the productivity of underground workers. It involves developing an employee's skills to improve his productivity and, because working productively involves knowing how to do a job safely, the program includes instructing an employee in the various safety and health aspects of underground work. An important and, I believe, distinguishing point about the development of this program is that it has been done with the full participation, cooperation and commitment of management, labour and government.It's of considerable interest to note that companies in Ontario who are now using this program are finding that new employees are approximately six months further advanced in productivity than was the case before its use, and in some cases the frequency of accidents has shown a reduction among those employees who have taken this program as compared to those who haven't"

Jan 1, 1980

By Gerald H. Luttrell, Lance Christodoulou, Jaisen N. Kohmuench, Michael J. Mankosa

The efficiency of the froth flotation process has long been known to be strongly dependent on particle size. For sulfide minerals, good recoveries are typically achieved in industrial flotation circuits for particles in the 30 to 200 µm size range. Particles outside this critical size are typically lost in industrial operations and rejected to tailings streams due to inherent constraints associated with the physical interactions that occur in the pulp and froth phases of conventional flotation equipment. In response to these limitations, a series of experimental studies were conducted to determine whether particles previously lost as tailings could be economically recovered using a suite of novel flotation technologies developed for upgrading ultra-coarse and ultra-fine particles in the industrial minerals industry. For the case of ultracoarse particles, a fluidized-bed flotation system called the HydroFloatTM separator was tested. The data obtained using this novel flotation device in both laboratory- and pilot-scale trials showed that good recovery of previously lost sulfide values up to 850 µm diameter could be achieved. Similarly, for ultrafine particles, a high-intensity cavitation-based column cell was tested. This technology, which utilizes highshear contacting of slurry and gas, was capable of recovering valuable ultra-fine sulfide that were previously lost due to the low capture efficiency of conventional flotation processes. The objectives of this article are (i) to describe the unique operating principles of these two advanced flotation technologies and associated ancillary classification equipment, (ii) to present laboratory- and pilot-scale experimental test data showing the metallurgical benefits of the proposed novel flowsheet for sulfide tailings processing, and (iii) to provide a generic cost-benefit analysis of the proposed system for recovering lost values in existing sulfide tailing streams.

Jan 1, 2016

By H. Deveci, E. Y. Yazici, A. D. Bas

The leach solutions of waste of printed circuit boards (WPCB) may contain a wide range of base and precious metals with different concentrations due to heterogeneity of these wastes in composition. Therefore, selection of a suitable metal recovery method is of practical importance for downstream processing of pregnant leach solutions of WPCB. Sulphuric acid leaching of WPCB in the presence of a suitable oxidant is capable of dissolving base metals as well as precious metals such as silver. In this study, cementation of silver from sulphuric acid leach solutions of WPCB using metallic copper, aluminum and zinc was studied. The WPCB sample was assayed to have a silver content of 694 g/t. A synthetic leach solution containing 20 mg/L Ag in sulphuric acid solution (0.51 M H2SO4) was prepared based on the silver concentration in pregnant leach solutions of oxidative sulphuric acid leaching tests. Total sulphate concentration ([SO4 2-]T) was kept constant using sodium sulphate at 1 M. Metallic powders of copper (-850 +600 µm), aluminum (-425 +45 µm) and zinc (-45 µm) were used in the cementation tests. The effects of metal type (Cu, Al or Zn), dosage of metal powders (above the stoichiometric ratio by up to 2000-fold) and temperature (20-80°C) on the rate and extent of silver extraction from the solution was investigated. The effect of presence of copper on the cementation performance was also tested. Under suitable conditions high silver recoveries (>90%) was achieved using metallic copper and zinc while aluminum yielded the lowest silver recovery (i.e. 40% Ag). The kinetics of cementation by zinc was comparatively higher than that of other metals. Increasing the temperature was observed to significantly enhance both the rate and extent of silver cementation. SEM-EDS studies were performed to characterise the metallic powders after cementation.

Jan 1, 2016