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By Pervez Patel, Martin G. Frohberg, Demetrios Papamantellos

Model experiments were carried out on the mass transfer of iodine between n-hexane and a 4 2 X 10-3 M aqueous sodium hydroxide solution. The influence of mechanical stirring by means of small gas bubbles (ca. 0.01 ml in volume) on mass transfer was examined in independent experiments. The results were described with the help of the penetration theory and in the case of bubble stirring with the help of a mathematical model based on this theory. S LAG-METAL reactions, especially those in steel-making processes, often occur under conditions where gas is evolved in the form of bubbles that break through the slag-metal interface. It is known that stirring by means of bubbles increases the mass transfer coefficient, but there has been very little quantitative work done in this field. Because of the difficulties that attach to experimental work at high temperatures this study was confined to model experiments at room temperature. EXPERIMENTAL APPARATUS The transport of iodine from an n-hexane layer into a weak sodium hydroxide solution was studied a) with stirring by means of bubbles and b) with mechanical stirring. The apparatus for the experiments with bubbles consisted of the cell, two Dreschel bottles filled with hexane in order to saturate the nitrogen flow, one flow meter, and a nitrogen gas cylinder fitted with a fine-regulating valve. Fig. 1 shows the cell consisting of a glass cylinder 33 cm in height with an overall diameter of 7.5 cm embedded in a copper flange. The flange is connected to a Plexiglas plate and to the gas inlet. The Plexiglas plate has holes of 0.2 mm diam bored into it which are spaced 1 cm from each other. For the experiments with mechanical stirring the bottom of the cell was sealed off by a Plexiglas plate. The upper layer was stirred by means of a glass stir-rer and the bottom layer with the help of a magnetic stirrer in a counter rotatory direction. Both stirrer speeds could be varied continuously. EXPERIMENTAL PROCEDURE Iodine dissolves in n-hexane producing a stable violet color thus enabling the iodine concentration in

Jan 1, 1970

By B. Surender Mohan

Mining lignite pollutes the environment and causes ecological damage if unattended. Being conscious of the importance of environmental resources for the well-being of the living system, the Neyveli Lignite Corporation (NLC) adopts the policy of environmental regeneration as the foundation on which productivity is built. NLC started investing on Eco Care and Environment Protection long ago and it continues. Early investment in environmental protection has resulted in steady growth of the Company along with a healthy environment. The future vision of NLC is to be in the vanguard among the contributors to the community, environment and the nation by developing and utilizing industrial and human resources to the optimum. Untiring efforts are being put in mines (NLC as a whole) to maintain and sustain the ecological balance arising due to continuous mining activity. NLC?s Environmental Management System is becoming a symbolic role model for many of the opencast mines in Southeast Asia. NLC has been bestowed with number of prestigious Environment and Sustainability awards in recognition of the mammoth contribution in maintaining a clean and green environment.

Aug 1, 2013

By Shane McDonald

Australia produces approximately 84 million tonnes of coal per annum from 30 longwalls in New South Wales and Queensland, operating at an average depth of around 300m. Industry trends and expectations place increasing emphasis on the reliability of these operations; for example, the current average face width is 245m and this is expected to increase to approximately 270m by 2010. In recent years, Beltana No.1 Mine has consistently been Australia?s highest longwall producer, with ROM output of 7.2Mt in YEJ2007. Strata management has become a key feature of the operation of Australia?s longwall mines, as a tool to manage variances in the geotechnical environment. This involves an understanding of the impacts of the geotechnical environment on ground behaviour and the implications for mine design, stability and associated support, interaction and horizon selection. The anticipated ground control impacts of these factors form the assumptions that drive the format of plans specifying both triggers and actions, with quantified, monitoring-focussed experience used to refine the plan in a continuous improvement (ie ?plan-do-check-act?) process. This paper summarises the Beltana No.1 Mine strata management methodology and experience to-date.

Jan 1, 2008

Three complete connector assemblies and ten separate contacts were submitted to a series of tests to establish the connector permissibility and compliance with the Bureau of Mines' research Contract H 0110423. Test Procedure TPC-0100 was coordinated, and the test plan approved by the Bureau as fully complying with the intent of the contract for the low voltage, medium voltage and high voltage A.C. connectors. The components and connector assemblies have been demonstrated in testing that they meet or exceed all the requirements of the test procedure.

Jan 1, 1972

By G. van Aswegen

Seismic monitoring became commonplace in the deep South African gold mines in the early 1990’s. The discipline has, to a large extent, developed beyond the ‘research’ stage, and a ‘Guide to Seismic Monitoring in Mines’ has been accepted by the Department of Minerals and Energy1. Although ongoing research is a requirement for the achievement of all the objectives of seismic monitoring in mines, sufficient knowledge exists to apply seismic monitoring for routine seismic hazard assessment as an aid to risk management. The design and management of seismic monitoring systems can be tested against requirements spelled out in the ‘Guide’. Assuming the seismic monitoring system performs as per requirement, the best practice for routine seismic hazard assessment in mines includes • Long term seismic hazard assessment: through back analysis of seismic data and correlation with numerical modelling output, reasonable tests for planned mine designs are possible. • Medium term seismic hazard assessment: o Spatial analysis through contouring of seismic strain related parameters, with superimposed contours or event plots of stress related parameters allow the delineation of potential instabilities in space. o Quantitative and statistical analyses of seismicity in smaller spatial units (usually encompassing production sites) allow the comparative seismic hazard rating of different areas/sites so that rock engineering input and risk management can be optimised • Short term seismic hazard assessment relies mainly on time history analyses of particular seismicity parameters. The temporal patterns are controlled by a combination of temporal and parameter filters, the optimisation of which determines the success rate.

Jan 1, 2003

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By B. K. Mishra

In order to maintain higher grinding efficiency in tumbling mills the mill interior and dynamics must be known. For this purpose, several different types of non-intrusive methods have been proposed and are being tried in the industry. We have made an effort to develop a diagnostic tool based on vibration signal. Here we discus results of our experiments pertaining to ball as well as SAG mill. In each case, a triaxial accelerometer was used to capture mechanical vibration generated due to the tumbling action of the charge. The vibration signal was transmitted to a remotely placed computer and the signals were analyzed by standard signal processing technique. In case of a ball mill (5m diameter), qualitative mill information could be obtained by correlating the vibration signal to feed rate and mill filling. An effort was also made to identify different motion characteristic of the charge by analyzing its vibration signal. In case of the SAG mill (10m diameter), liner wear was estimated by comparing the vibration signal emitting out of a freshly lined mill with that of a worn out mill.

Jan 1, 2011

By Keith S. McIntosh

The fire assay process for the quantitative recovery of platinum group elements (PGE?s) prior to subsequent analysis traditionally is a time-consuming process. Samples derive from various ore types and contain PGE?s at the ppm or ppb levels, making concentration of the elements mandatory before assaying. Traditionally sample turn-around times are of the order of 24 hours. The whole sequence of sample preparation, fire assay and subsequent analysis of PGE?s have been automated by Anglo Platinum. Some of the major challenges on the road to automation will be discussed and the novel solutions that were implemented. The engineered solution included robotic automation of the whole sequence, from sample preparation, up to the final element by element assay. The final system allowed for rapid (less than one hour) and accurate analysis of PGE?s even in streams containing very low levels, such as flotation tailing streams and drill core samples.

Jan 1, 2006

By R. D. Lindsay

"Pamour Porcupine Mines, Limited is involved in the mining, milling and primary refining of various gold, gold - copper and refractory gold ores. Pamour operates five mines in the Porcupine Mining District of Ontario, and two 2,550 t/d milling facilities.Both metallurgical facilities use conventional cyanidation technology including zinc cementation for precipitation of gold and silver from solution. The precipitation process, as applied to clarified leach solutions (less than 1 ppm suspended solids) at Pamour is called the Merrill - Crowe process. Precipitates from both milling operations are treated at Pamour's Area Refinery. Schumacher precipitates, unlike Pamour No. 1, require an ''Acid Treatment Stage"" prior to refining to remove the high contained copper. This is accomplished by leaching the precipitates initiallv with sulphuric acid to remove zinc and then with sulphuric acid and manganese dioxide to dissolve copper. Refining procedures after ''Acid Treatment"" are essentially the same for both precipitates.The following considerations highlight the basic principals applied to refining cyanidation precipitates at Pamour, including:"

Jan 1, 1986

By J. L. Gregg, J. L.

RECENTLY there has been considerable interest in the production and use of extra hard alloys composed primarily of tungsten and carbon. Dr. Hoyt's recent paper1 gives a good description of these alloys and describes their performance when used as tools. There are a number of these alloys on the market sold under various trade names, and it is the purpose of this paper to describe the results of an investigation of the structure of five of these alloys by means of microscopic and X-ray methods. The samples studied were in the form of small tools or wire-drawing dies, which were either purchased or supplied as samples. They were in some cases not supplied by the original makers but were furnished by the agents in this country, and we wish to call attention to the fact that they may not be truly representative of the materials supplied under the various trade names. No performance data are given and no inference as to the inferiority of one alloy as against any other is made. K. Schröter2 recently described methods for polishing alloys of this type for microscopic examination and has presented photomicrographs of several alloys. However, he did not identify their constituents or describe methods for their identification.

Jan 1, 1929

By Kang N. Zhong, Hui H. Luo, Yunan Phosphate Chemical Co., Yi H. Wei, Yao J. Li, Yu L. Wang

"The three kinds of phosphate ores (igneous, metasedimentary and sedimentary) found in China have great differences in flotation flowsheets and reagents suite because of their crystal structure and mineral composition. The igneous and metasedimentary apatites have good floatability with fatty acid as collector and waterglass, sodium hydroxide or sodium carbonate as conditioners. The sedimentary phosphate is very difficult to beneficiate by direct flotation because of their poor floatabilities and relatively high content of MgO and SiO2, even though the dolomite depressants are used sometimes.The differences in floatability of apatites in China are closely related to their differences in specific surface area. The amount of collector to float apatite increases with the specific surface area. Apatite with lower specific surface area showed good floatability at lower collector concentration. Apatite with a higher specific surface area needed a higher concentration of collector. The content of CO3 2- will affect the specific surface area of apatite by distortion of its crystal structure and consequently affect its floatability.Dolomite can be easily rejected from apatite in a weak acidic medium (pH=5), especially in phosphoric acid medium by reverse flotation. Quartz and siliceous gangue in sedimentary apatite can be removed by direct flotation using fatty acid or by reverse flotation using amine. Amine is not practically applied because sedimentary apatite in China is usually very fine and needs fine grinding, which always results in excessive, very fine, stable and non-flowable foam.Based on the floatability of phosphate ore in China, a two-stage flotation process, direct and reverse flotation (D+R), was developed to beneficiate sedimentary ore. For the Haikou phosphate ore containing 25.11% P2O5, 3.46% MgO and 16.5% SiO2, a concentrate containing 31.84% P2O5, 0.48% MgO and 14.8% SiO2 can be obtained through a continuous D+R test at a recovery of 89%."

Jan 1, 2003

By Daniel Saint Don, Jacques Dumouchel

QIT Madagascar Minerals (QMM)’s heavy mineral sand deposit located near the Village of Fort Dauphin, Madagascar was recently drilled using Boart Longyear Company’s Mini-Sonic drill. Continuous sand core samples were obtained to a depth of up to 30 meters for analysis and compared with the existing drilling data. Results were used as part of a validation process of the resource estimate, based on approximately 1,500 exploration holes drilled to date.

Jan 1, 2005

By S. Hardy

The paper describes state of the art non-linear analyses of the pile groups that were employed during the raising of the 133m high triumphal arch which forms the centre piece of the new Wembley stadium in North London. The deformation behaviour of these piles groups was critical during the lifting process, due to the slendemess of the arch structure. The issue was made more critical by the high profile nature of the project. The results of Class A (Lambe (1973)) predictions of the pile group movements are compared with observed displacements and rotations which were accurately measured on site. To illustrate the importance of soil non-linearity on pile group behaviour, comparison is also made with pile group analyses which assume a linear soil stiffness.

Jan 1, 2006

Remember, the good of the Institute is not limited to the technical papers. The acquaintance and good fellowship, the education and broadening effect of our meetings, can be made a real benefit for us all. Don't forget the meetings. The nest one will be at Denver, Feb. 26, 27 and 28. THE SECRETARY

Jan 1, 1922

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905

By S. Banisi, M. Poorkani

The Sarcheshmeh copper deposit contains 1 billion tones of ore averaging 0.7% copper and 0.025% molybdenum. It is located southeast of Iran and currently processes 41,000t/d. Molybdenite as a by-product is recovered in two separate stages. First, a bulk coppermolybdenum concentrate is produced and in the second stage these two are separated. The recovery of molybdenite in the first and second stages is 65% and 85-90%, respectively. The yearly production of molybdenite concentrate varies between 3500 and 4000 t. Sodium sulphide is used as the depressant of the copper and iron bearing minerals which due to a rather high consumption (17.7 kg/t) constitutes one of the major cost items of the plant (i.e., 58% of total reagents cost). A detailed laboratory scale study showed that replacing air with nitrogen could reduce the consumption of sodium sulphide (i.e., H2S or mineral origin). Nitrogen for the plant was supplied from an oxygen plant used for the smelter through a 1400 m long pipeline. The existence of the oxygen plant at the Sarcheshmeh complex was a key factor in the implementation and success of this project. After using nitrogen in the plant for a period of twenty one months, the consumption of sodium sulphide was reduced from 17.7 to 14.2 kg/t at constant metallurgy. The reduction was lower than expected which was mainly due to the type of sodium sulphide used and the lack of any automatic instrument to control the depressant (sodium sulphide) dosage. The latter in turn caused the operators to overuse sodium sulphide in order to reach and maintain the target metallurgy (i.e., higher molybdenite recovery along with lower copper content of the concentrate).

Jan 1, 2005

By Juliana Gutiérrez-Paredes

Keywords: Slag, chromium oxide, recovery, stainless steel Experimental and theoretical work was performed to estimate the effect of slag basicity and amount of reducing agents on the reduction of chromium oxide from the slag which interacted with molten steel at 1600°C. The slag system contained CaO, MgO, SiO2, CaF2 and Cr2O3 together with Fe-alloys (Fe-Si and Fe-Si-Mg). The CaF2 and MgO contents in the slags were 10 mass % each; Cr2O3 was 25%. The amount of the ferroalloys ranged from 12.5 to 50 g per 100 g of slag. The (CaO+MgO)/SiO2 ratio was held at 1 and 2. The Cr yield was determined using both Fe-alloys as reducing agents. Some estimations were made to determine the theoretical effect of temperature, slag basicity, (CaO+MgO)/SiO2, and amount of reducing agents in the slag on the chromium recovery. The FACT (Facility for the Analysis of Chemical Thermodynamics) computational package is used to determine the equilibrium between the slag and molten steel.

Jan 1, 2005

By O E. Jr Crenwelge

Frequency domain, single-charge vibration signatures are used to interpret the characteristics of explosive impulse excitation and ground vibration transmission. The effects of charge height, charge splitting, and different blasting agents are first discussed. Then the effects of rate of change with distance of overburden material properties and layer or surface geometries are illustrated.

Jan 1, 1988

By Camilla Favaretti, Benjamin Turner, Anne Lemnitzer

Pile foundations are extensively used in the construction of various types of superstructures, including tall buildings, bridges, freeways and offshore structures. A fully constrained tip embedment such as a rock-socket offers an attractive solution for achieving significant tip resistance and improving the load-carrying capability of the foundation element. In profiles with very soft surficial soil, rock-socketing often provides the only reliable source of axial and lateral resistance. In preparation of a large-scale testing program on rock-socketed piles at UC Irvine (UCI) geared towards studying the magnitude of shear amplification at the rock-soil boundary of pile foundations, a pre-test model-scale experiment was executed in the UCI Structural Laboratory. The objective of the model-scale experiment was to iterate and validate the test setup, study the influence of important boundary conditions, assess instrumentation techniques and sensor placement, and to gain preliminary insight into the small-scale specimen non- linearity. In addition, this model-scale study provides ample opportunity to compare lateral performance parameters with analytically predicted lateral load behavior using traditional soil resistance functions and limit state analyses and explore new techniques for the derivation of soil resistance functions. The pile specimen had a pile diameter (D) of 10 inches and a total pile length of 125 inches. The pile was embedded in a 40 inch simulated rock socket overlain by 52 inch of medium dense sand (DR~50%). The pile extended 32 inches above the soil surface, where cyclic lateral loading was applied. The pile was installed in a laminar metal frame box with inside dimensions of 39 inches in width (W), 73 inches in length (L) and 86.1 inches in height (H) as shown in Figure 1. During testing, the box was restrained using a rigid bracing system consisting of concrete reaction blocks, wooden braces and steel girders.

Jan 1, 2018

By R. A. Lord, H. M. Prichard

efficiency is discussed from both experimental and

Apr 1, 1994