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By F. M. Doyle, Robert G. Robins, E. Peters

Stability diagrams for the Cu-S-H2O system have been widely applied over many years. Stability diagrams for aqueous systems generally, have been generated by computer, but with the programs for Potential-pH diagrams in particular, a common routine leads to error in multi-element systems. In this paper these errors, and some misinterpretation of diagrams are considered. In most of the published diagrams for the Cu-S-H2O system there has been no account of the sulfide complexes of copper. Here, the free energies of formation for the various species in the system have been re-evaluated for consistency, and some diagrams for the Cu-S-H2O system ( generated with the program DIASTAB Vers.5 ) are presented.

Jan 1, 1993

By B. E. Dindsale, P. B. Altringer, R. H. Lien

The Bureau cf Mines, U.S. Department of the Intericr, is investigating biolcgical and chemical deccntaminaticn of cyanide- containing leachates and residues. Biolcgical cyanide cxidaticn, using bacteria isolated from a precious metals tailings pond, destroyed >85 pct of the cyanide in several prccessing solutions containing up tc 280 ppm CN. Reaction time varied from about 4.5 hr in a trickling reactor using quartz as a bacterial substrate to 2 mo in unagitated, covered flasks. Chemical techniques were used to destroy the remaining complexed cyanide down to 1 ppm. Exploratory tests were also conducted using spent ore from heap leach operations as the bacterial substrate to determine if biological cyanide oxidation could be used to destroy the residual cyanide in spent heaps.

Jan 1, 1991

By Ken J. Fair, Vicken H. Aprahamian, Gus Van Weert

A consortium of Canadian mining companies, engineering firms and the Ontario Government has supported Hydrochem's efforts in the last year to design and cost a 10 tpd NITROX PROCESS® demonstration plant. A 5 kg per hour mini plant was installed at the Hydrochem facilities in Brampton, Ontario. This paper describes design testwork on Dickenson Mines arsenopyrite concentrate and application of the findings to the demonstration plant flowsheet. The control of nitrates in discard solids and stack gases is discussed in detail. Nitric acid oxidation of arsenopyrite results in significant ele- mental sulphur formation, enough for it to be detrimental to sub- sequent cyanidation. Flowsheet variations aimed at dealing with this process characteristic are discussed and testwork results on one option (hot liming) are described.

Jan 1, 1988

By M. Yekeler

The critical surface tension of wetting values (Ye) of realgar (AsS), talc [Mg3si401o (OH) 2]' stibnite (Sb2S3), and sulfur (S) were determined by flotation in the absence of conventional flotation collectors as 38.7, 38.0, 35.5, and 30.0 dyne/cm, respectively. The surface tensions of flotation media were arranged by methanol. Separation of binary mixtures of these minerals was performed exploiting their Ye differences-which form the basis of the "ganuna flotation process". One step flotation test showed that sulfur floats preferentially from its mixtures with realgar and stibnite at recoveries of 73.6 and 70.7 % and grades of 81.7 and 91.2 %, respectively. The separation of stibnite from realgar gave a recovery of 4.1 % and a grade of 41.2 % for stibnite, indicate that a minimal Ye difference of 3.6±0.2 dyne/cm is essential for such separation when conventional flotation reagents are not used. This paper presents data and describes the approach employed in these separations.

Jan 1, 1994

The Bagdad mill, built in 1977, was de-signed for a mill capacity of 36,300 tpd. An ABC (Autogenous Mill-Ball Mill-Crusher) grinding circuit was chosen. The original mill contained three completely independent grinding circuits, each containing one 9.75 m diameter by 3.96 m long fixed speed autogenous mill, one 4.72 m diameter by 6.71 m long ball mill and one 2.13 m diameter short-head cone crusher. Total installed power per grinding circuit was 8,464 kw with 5,966 kw in the autogenous mill, 2,237 kw in the ball mill and 261 kw in the crusher. (See FIGURE I--Major Equipment Flow Diagram.) The autogenous mills were designed to be able to operate semi-autogenously but were never converted to SAG. As a result of this design, only about 4,100 kw of the designed power is utilized in the autogenous mills. The grinding circuits are closed with 2.44 m by 6.10 m double deck vibrating screens. Screen oversize is returned, by a series of conveyors, underneath the mill coarse ore stockpile to feed the crushers. Variable speed belts feed the crushers and control power draw. Crusher product reports directly to the tail end of the autogenous mill feed belt. (See FIGURE 2--Typical Crusher Feed and Product Size Distributions.) Tramp iron in the autogenous mill-crusher circuit is handled in a unique way. A magnetic sensor detects the metal. This closes a gate which directs the crusher feed onto a separate belt which bypasses the crusher and returns the material to the autogenous mill feed belt.

Jan 1, 1992

By J. R. Batista, J. C. Young

Leachates from gold heap-leaching mines may contain selenium concentrations as high as 2 mg/L. Previous studies report satisfactory selenium adsorption by activated alumina from relatively "clean" drinking waters. However, the findings of these studies cannot be directly applied to the treatment of mine leachate where other ions compete for the alumina adsorption sites. This study evaluated the adsorption of selenium from a mine leachate to develop design parameters for a full-scale activated alumina process. The study revealed that 68% of the selenium in the leachate could be removed by alumina at pH levels greater than 5.0. At pH levels less than 4, silica was poorly adsorbed by alumina, and selenium adsorption was improved. Silica adversely affected the selenium adsorption capacity.

Jan 1, 1998

By K. J. Sollman

With an ongoing concern for safety and health in the workplace, NYCO® requested three medical evaluations be undertaken to study possible health hazards of wollastonite. Two of the evaluations were conducted by the National Institute of Occupational Safety and Health (NIOSH). One was in 1976 (Ref. 1), and the second in 1982 (Ref. 2). The aim of the two studies was to answer the following two questions: 1. Do wollastonite workers exhibit more respiratory abnormalities than workers not exposed to wollastonite? 2. Is there a relationship between prevalence of respiratory abnormalities and accumulated expo-sure time to wollastonite?

Jan 1, 1988

By Jeff Hussey

Since 1955, Gaspe Mines has produced 150 Mt (165 million st) of ore averaging 0.9% copper. The ore was mined from two open pits and from underground workings. In 1994, four exploration drill holes discovered a buried porphyry/skarn copper-molybdenum (Cu-Mo) deposit at depths of between 1,000 and 1,700 m (3,280 and 5,580 ft) below the top of Porphyry Mountain. The mineralization and alteration associated with the Porphyry Mountain quartz monzonite does not outcrop. Prior to 1997, about 19,500 m (64,000 ft) of drilling in 12 drill holes had outlined 200 Mt (220 million st) grading 0.73% Cu and 0.08% Mo. Mineralization occurs as veins and disseminations of chalcopyrite and molybdenite.

Jan 1, 1998

By Matthew E. Fowler, Jean Habimana, Roy F. Cook

The West Side CSO Tunnel, Pump Station & Pipeline Project is currently beginning construction along the downtown waterfront of Portland, Oregon. This4.3 meter diameter, 5,500 meter-long soft ground tunnel will be driven along the westbank of the Willamette River adjacent to buildings and utilities and several major pile-supported bridges. High groundwater pressure, extended lengths of gravel to cobble-size alluvium, and the need to control ground loss and surface settlements were key considerations in the selection of slurry tunnel boring machines for the project This paper presents an overview of the numerical modeling that was performed during design to estimate the strains and additional loads in the pile-supported structures and to assess the efficiency of proposed mitigation measures.

Jan 1, 2003

By Charles N. Alpers, Jane M. Hammarstrom, Robert R. II Seal, Nora K. Foley

Geoenvironmental models are compilations of geologic, geochemical, and hydrologic information that describe both the pre- and post-mining environmental signatures of mineral deposits. The environmental behavior of seafloor massive sulfide deposits varies according to deposit type. This study has divided massive sulfide deposits into six categories: (1) Noranda-type, (2) Kuroko-type, (3) Cyprus- type, (4) Bathurst-type, (5) Besshi-type, and (6) sedimentary-exhalative deposits. In addition to Fe and Al, the heavy metals most commonly associated with drainage from these deposits are Cu, Zn, Cd, Pb, and As. Metal ratios of mine drainage and natural background waters tend to reflect the primary character of the ores. Variations in pyrite and pyrrhotite contents are reflected in lower pH values associated with pyrite-rich deposit types.

Jan 1, 2000

By K. M. Belingheri, M. E. Smith

Pinson Mining Co. operates a conventional mill and two heap leach operations in north-central Nevada. The latest of these heap leach operations, the Preble project, is a low-grade, low-tonnage property made profitable through several innovative capital reduction techniques. Rapid return on investment was a prime factor in design. To facilitate this, fast-track design and construction techniques were employed. The project is a seasonal 1.5 kt/d (1 700 stpd) crush/agglomerate heap leach plant using both clay and plastic leach pads. Construction and startup were achieved through cooperative arrangements between local contractors and in-house construction personnel, with few items put out to bid. An interactive approach to design minimized lost time and construction costs.

Jan 1, 1987

By J. H. Tylczak, R. Blickensderfer, D. J. Singleton

As part of its research on wear of mining and mineral processing equipment, the US Bureau of Mines evaluated the erosion-corrosion characteristics of 12 alloys in phosphoric acid waste water. Tests were conducted on 2- and 5-cm-diam specimen8 in 12- and 60-cm-diam ball mills by grinding phosphate rock in gypsum pond water with an initial pH of 1.6. For comparison, grinding tests also were conducted in tap water. Static corrosion tests in gypsum pond water also were carried out. For all alloys tested, the wear by erosion-corrosion was greater than the sum of erosion plus static corrosion. A low-alloy, high-carbon steel and a high-manganese, nitrided stainless steel were the most cost-effective materials

Jan 1, 1987

By M. Li, J. D. Miller

It has been discovered that water insoluble alcoholic solutions of alkyl hydroxamic acids serve as selective collectors for the flotation of phosphate mineral resources (Miller et al., 2000). The effectiveness of the new collector chemistry has been demonstrated by the results from single stage bench scale flotation experiments for feed material from plants in Florida, North Carolina, and Utah. In the best case, from experiments with low grade (5% P20,) coarse feed (16 x 35 mesh), a single stage phosphate recovery of 95% was achieved with a concentrate grade of 31% P20,. Such a separation efficiency could not be achieved using the traditional fatty acid/fuel oil collectors as is evident from a comparison of the respective grade/recovery curves.

Jan 1, 2002

By G. H. Jardine

Mine planning and production scheduling in surface mines are basically iterative processes which are ideally suited to the use of computer-based techniques. Both processes are truly three-dimensional and lend themselves to the application of 3-D interactive graphics. Until recently, this has applied the need for the costly, dedicated graphics screens and mid range minicomputers. However, ongoing advances in processor chip design led to the emergence of inexpensive and powerful 5 to 10 Mips desktop work- stations. These workstations have the processing power to support rapid, high resolution, 3-dimensional graphics. By combining these workstations with powerful 3-D CAD software and, with a suite of comprehensive mine planning and scheduling applications, Mincom has developed a most cost effective solution to modern mine planning challenges.

Jan 1, 1989

By Hugo J. Garcia, M. C. Fuerstenau, D. M. Lupan, J. L. Hendrix

Biodegradation of cyanide by microorganisms isolated from solids previously exposed to cyanide has been investigated. The anaerobic cyanide biodegradation showed good, short-term removal of cyanide in the presence of nutrients (medium A). This system retained metabolic activity at cyanide concentrations up to 300 ppm at pH 10.5. Microscopic examination of stained specimens revealed that the bacteria were Gram-negative, rod-shaped bacilli. Strains capable of cyanide decomposition were identified as Pseudomonas and Alcaligenes. The kinetics of biodegradation were found to be first order with respect to cyanide concentration, and the overall reaction rate constant is k = 0.102 day-1. Studies with Na14CN showed that 17 % of 14C transformation went into the cells, 18 % into carbonate and 47 % into bicarbonate.

Jan 1, 1995

By J. L. Gent

Compressed air distribution networks are essential for powering equipment in many mines even though some mines are replacing them with electrical power for hydraulic drills. Compressed air can be costly especially if the system is poorly designed and maintained. This paper outlines a technique for proper compressed air system design that will help mine managers reduce compressed air power costs; an important topic in today's highly competitive international minerals market. Compressed air system design is complex. It requires specifying: 1) air quantity and pressure in all branches of a large network, 2) proper location and types of valves and fittings, 3) the network solution that determines compressor requirements, 4) optimal hose and pipe, diameters, 5) receiver and compressor accessories, and 6) required capital and operating costs.

Jan 1, 1989

By E. Yuksel

Noted as one of the 20 major economies of the world, Turkey is a semi-arid plateau between the Eurasian and the African continents. With its surface area of 780 thousand sq km, it supports a population of 70 million people. While the mining history of Turkey can be traced back as far as 7 000 B.C., mining currently generates only 2% of Turkey’s gross national product. Turkey has 77 of the 90 principal minerals that are mined world-wide. Currently, some 5 000 mine occurrences including copper, lead, zinc, iron, gold-silver, chromite, sepiolite, mercury, and coal deposits, soda ash, marble, zeolite, feldspar, magnesite deposits, as well as the world’s largest known borate deposits, have been discovered and partially explored.

Jan 1, 2004

By B. Bringhurst, J. J. McClelland

A filter consisting of a synthetic fibrous material has been determined to be a viable alternative to the wire mesh panels currently used in irrigated filter dust collection systems. An extensive laboratory investigation of the material showed that it removed a higher percentage of both respirable coal and quartz dust from the air entering a collector than did the flat and pleated wire mesh panel designs. This improvement in dust collection efficiency reduced the amount of coal and quartz dust discharged from the collector exhaust by approximately 44%. Since continued exposure to excessive levels (>5%) of respirable quartz dust presents a severe health hazard, this alternative filter medium could be of use to those mines required to comply with more stringent dust standards due to quartz.

Jan 1, 1992

By V. Perdikatsis

The aim of this paper is the study of the pollution of soils in greenhouses because of the use of pesticides. The degree of pollution was studied in relation with the mineralogical and pedologic properties of the soil. The study was con-ducted in the region of Kountoura, Palaiochora, situated in the south of the prefecture of Hania/Greece. Several samples of soil, originated from 4 greenhouses were analyzed. 5 pesticides with organic drastic compounds were chosen for analytical determination using GC-MS from 18 which were applied in total during the period of sampling. It was concluded that the adsorption of pesticides in the soil of greenhouses is connected with the percentage of the clay fraction and the content of organic carbon.

Jan 1, 2006

By Kiran B. Chaudhuri

The Kivcet process is technologically the most advanced of the new lead smelting processes which have been developed over the past decade construction of the first commercial scale Kivcet lead smelter which has been designed by KHD Humboldt Wedag for Sociedad Complejo Metalurgico de Karachipampa is at present nearing completion in Bolivia. Some of the measures taken to minimise emission of harmful elements as well as methods employed to minimise energy consumption in the design of the smelter, are presented. Results of recent testwork which have added to the flexibility of the process are summarised.

Jan 1, 1982