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By J. A. Finch

Solvent-coated air bubbles in the Air-Assisted Solvent Extraction (AASX) process achieve the dual role of high solvent specific surface area and ease of phase separation. The thickness of the solvent film is of fundamental interest but difficult to measure directly in the process itself. As an approach interferometry (in the UV-vis region) was used to measure the time dependent thickness of a film formed by blowing an air bubble in kerosene-based solvents. The film was stabilized by the presence of 1.5 ppm silicone oil, as employed in AASX. The film appears to comprise two layers; an outer "free" layer of almost constant thickness and an inner "bound" layer which decreased in thickness with time. The bound layer is considered relevant to AASX. For a 20 mm diameter bubble blown in LIX/kerosene solvent the initial thickness was ~ 3 um which decreased over 10 minutes to a final rupture thickness of 500 nm. The bound layer thickness and time to rupture decreased with decreasing bubble size. Correspondence to prior indirect estimates of solvent layer thickness is examined.

Jan 1, 2006

By A. G. Matyas, B. Wasmund, R. C. Francki, K. M. Donaldson

"The construction of large. high-power electric furnaces has been an important factor in the growth of electric smelting technology . New developments in the design and operation of electric furnaces have been spurred by the escalating cost of electric power and increasingly stringent environmental constraints. Key areasofprogress include the application of high voltage to enhance furnace productivity; the installation of novel furnace cooling elements and robust binding systems to extend furnace life; development of process schemes to reduce power consumption by preheating and prereduction of the charge; and environmental control improvements for handling fine dusty feedstocks, and for furnace sealing.This paper reviews these developments and outlines a systematic approach for their application in the custom design of new or retrofit electric furnace facilities.IntroductionThe use of electric smelting furnaces has continued to progress during the last decade. Electric furnaces offer high throughput capacity and productivity. In addition, they produce minimum environmental impact, as the furnaces can be readily sealed, and only a small quantity of off-gas is generated. Electric furnaces present the most favourable choice of smelting technology where high process temperatures in excess of about l400°C are required.Their application is burdened by the escalating cost of electric power, hence it is important to seek new opportunities through further technological development. This paper reviews recent developments in the design and operation of high-power electric smelting furnaces, in the following areas:"

Jan 1, 1993

By X. B. Wang, Z. Q. Guo

Slagging coal gasification process became a highlight of coal chemical industry in China during the last decade. Refractory lining's life of slagging gasifiers is one of the most critical factors for a cost-effective operation. The paper introduces current status of coal gasification in China, lining structure of slagging gasifiers and performance of refractory lining. It also summarizes the major factors impacting on refractory wear in slagging coal gasifiers in four Chinese chemical plants, based on ten years of industrial experience. The utilizability is discussed in terms of cost-effectiveness of high chromia refractories and possibility of the alternatives.

Jan 1, 2004

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By A. Carbonari

In order to gain competitiveness and compete at a global level, construction companies should improve their efficiency. The problem is even more relevant in the construction field, whose work processes find it hard to evolve towards new automated methods and techniques in the management field. For that reason, this paper suggests how construction companies could apply new technologies to implement automated management of environmental hazards. Based on a survey regarding the environmental risks presently experienced in construction sites, noise and dust were considered two of the main hazards. So in this paper a networked system for real time remote monitoring of the spatial distribution of dust in construction sites was developed. Such a system would relieve builders from the commitment of on-site surveys, allowing for a continuous monitoring of the site conditions and of the real exposure of each worker and pass-by to the pollutants generated by construction works. The main system requirements considered are: easy to deploy, reliable, as accurate as needed to be able to send real-time warnings and store a good estimation of the real exposure to which involved people have been subject to. So far the research produced a prototypical hardware for dust monitoring made up of wireless sensors which can be easily deployed on site. The sensors were calibrated by means of laboratory tests, where their measurements were compared with those collected by means of highly accurate instruments, which were taken as a reference. Thanks to these experiments, calibration curves for the sensors were worked out, showing also the measurement range of the sensors.

Aug 1, 2013

By H. J. Glass, J. G. L. Bekkers

"In order to determine the feasibility of a hydraulic ore hoisting installation, the optimal operating conditions were calculated for applying such a system at the Detour Lake Mine of Placer Dome Ltd. Next, a financial analysis was conducted in order to estimate the cost per tonne for hydraulic hoisting of the ore. Subsequently, the cost per tonne was compared with the hoisting costs associated with a new borehole hoist. Installing a hydraulic ore hoist at Detour Lake Mine was found to be feasible with considerably lower costs per tonne of ore. The applied research method appears to be very functional and can be used to do similar research for other mining operations. IntroductionThe principle of hydraulic ore hoisting is well known, yet hardly accepted in hard rock mining. Application of the system would result in a smaller diameter shaft requirement and a flexible, easily expandable system. However, underground ore size reduction might be necessary and practical experience with the system is limited. Following recent innovations in the field of pumping hardware, e.g. new GeHo and Siemag Transplan equipment, hydraulic ore hoisting should be seriously considered for certain mining operations. As a case study, a design was made for the development of the newly found QK-Zone at Placer Dome Ltd.’s Detour Lake Mine. Hydraulic ore hoisting has been compared with conventional skip hoisting by establishing the optimal operating conditions and pumping equipment requirements for similar capacities at a selected mining operation. Generally accepted equations for slurry transport were used to predict the variation of pressure and power requirements as a function of hourly production and pipeline diameter. These data are used to select suitable equipment and estimate cost figures in order to make a financial assessment."

Jan 1, 1998

By Rodrigo Serna, Nora Schreithofer, Zoltan Javor, Kari Heiskanen

"Mineral floatability is a function of mineral properties such as size, liberation, shape, surface composition, reagent coverage on the surface, level of oxidation on the surface, etc.; pulp chemistry: Eh, pH, temperature, DO, reagent type, etc. and hydrodynamic conditions: turbulence, gas dispersion, D32, etc. The biggest challenge with predicting the floatability of an ore is finding a measurement method that would take into account the effect of all of the variables on the floatability of the minerals. The particle-bubble attachment time measurement is considered as an alternative way to predict the floatability of minerals instead of using expensive and time consuming flotation tests because it takes into considerations both surface chemistry and hydrodynamic parameters present in the froth flotation. The existing particle-bubble attachment time method is suitable for studying some significant flotation variables such as pH, temperature, particle size, reagent type and concentration. Nevertheless, measuring the attachment time as a function of collector coverage or surface oxidation is much more challenging. This paper introduces a new induction timer designed to measure the effect of galvanic interaction on the attachment time of particles. The new setup employs an array of needles to create 6 bubbles with the average size of 2.1 mm. Imaging system is used to set the initial distance between the particle bed and the array of bubbles. The attached particles are collected and sent for further analysis. One of the main benefits of the new experimental setup is that the attached particles can be physically separated from the unattached particles therefore many of the particle properties can be analysed and evaluated.INTRODUCTIONSchumann (1942), and Tomlinson and Fleming (1963) proposed that the flotation rate constant is dependent on four probabilities: particle-bubble collision (PC), particle-bubble attachment (PA), particlebubble aggregate stability in turbulent environment (PE), and particle-bubble aggregate stability in froth phase (PF). Any change in any of these probabilities will affect the overall flotation rate constant. All of the above-introduced probabilities are influenced by stream- variables and mechanical variables but their extent of influence vary. The stream variables are particle properties that have been shown to affect flotation rate constant such as size, shape, liberation, mineralogical composition, reagent surface coverage, surface oxidation, etc. The mechanical variables are the direct and indirect properties of the flotation unit affecting flotation rate constant such as cell and impeller geometry, air rate, impeller speed, air holdup, bubble size, residence time, hydrodynamics, froth depth, etc. For instance, the probability of collision is affected by many mechanical variables (bubble size, hydrodynamics, bubbles holdup etc.) but only one stream variable (particle size) has a major effect on it. On the other hand the probability of attachment is affected by much more stream variables: particle size, shape, liberation, surface composition, particle surface oxidation and collector coverage, Eh, pH, etc."

Jan 1, 2016

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

By G. A. Davidson, P. G. Williams

"New developments in centrifugal slurry pump technology are discussed in relation to their importance for improving pump operation and reliability.Experimental data obtained by measuring the velocity of liquid flows in a slurry pump casing using Laser Doppler Velocimetry are presented. This demonstrates the importance of selecting pumps with the proper hydraulic design to provide optimum efficiency, maximum part life and minimum operating cost.The paper also discusses the use of new wear resistant materials, such as ceramic/metal composites, which can significantly improve the life of parts exposed to abrasive media. The results of laboratory attrition tests are presented. IntroductionCentrifugal slurry pumps are of primary importance for the hydro transport of abrasive and corrosive media in the mineral processing industry. As for all process equipment, slurry pumps must be carefully selected and operated to provide optimal performance. To achieve this, it is necessary to select equipment which will provide efficient and reliable operation for the specific service conditions and incorporates the best materials available to obtain maximum parts life.Abrasive wear of liquid end components is the most important aspect that distinguishes the design and application of slurry pumps from other types of pumps. It is therefore necessary to have a fundamental understanding of the mechanical interaction between pump components and the media being handled, as this will impact significantly on hydraulic design, mechanical reliability and selection of wear resistant materials. Recent advances in computational approaches'» have greatly improved the prediction of wear rates in pump casings by facilitating the solution of complex equations which describe the wear mechanisms mathematically. In conjunction with this, new experimental techniques allow researchers to measure flow fields in pump casings using non-invasive devices such as Laser Doppler velocimeters."

Jan 1, 1992

By D. Mraz

"Under high pressure in a deep potash mine, the salt rock behaves in accordance with the concept of a generalized, perfectly plastic substance. The paper presents the evidence of this behaviour and engineering concepts f or room-and-pillar design. IntroductionThe mining and refining facilities at International Minerals &. Chemical Corporation (Canada) Limited are located near Esterhaz y at the southeastern edge of the Saskatchewan evaporites. Ore extraction began in 1962 and at the present time the annual mining capacity is in excess of eleven million tons of potash ore.A generalized geological section is shown in Figure I. The mining horizon is overlay in by 100 feet of rock salt followed by a thin bed of competent dry shale. The strata in the next 1,500 feet are generally competent and locally water bearing. The Blairmore formation contains strata of water-bearing unconsolidated sand. Below the mining horizon, rock salt is interbedded with anhydrite bands.The 8-foot mining bed is distinguished mainly by grade and clay content, as there is no definite bed boundary. The chief mineral s are halite, sylvite and, in some cases, carnallite, with up to 2 per cent disseminated clay. The ore is coarse grained, with crystals averaging one-half to three-quarters inch across.The major mining problem is related to the fact that the Dawson Bay formation, overlying the evaporites, contains areas and channels that are highly porous and permeable and are filled with unsaturated brine under high pressure. Consequently, all mining areas, with no exception, must be so designed that the overburden salt stratum remain s competently supported for the duration of the mine .This paper outlines a successful engineering method of determining the stability of the pillar s and designing a stable room -and-pillar mining system."

Jan 1, 1980

By Michel David

"The usual complaint of mines is that grade does not match exploration expectations. Quite often, more tons are mined than expected but at a lower grade. This can be seen as dilution. Geostatistics can help predict which dilution can be expected both in terms of grade and tonnage for different mining methods.The usual vocabulary of geostatistics speaks of block distribution; block variance, size effect, information effect, all terms which say very little to the practitioner. In f act, all this can be rephrased in terms of dilution .In this paper, the following is presented - an example which shows how reserves change with the size of selection units and number of samples taken, and tables which show the dilution that are bound to happen when dealing with the commonly encountered log-normal distribution. Finally, the paper shows how grade tonnage computations should be made in the case of an arbitrary distribution. IntroductionGeostatistics progresses more and more rapidly if one judge s by the number and quality of papers published in Mathematical Geology or at APCOM meetings. More and more case studies describing successful applications are published (David et al., 1986)(Kwa and Mousset-Jones, 1987). It is estimated that more than 270/0 of the gold mines around the world use geostatistics. There is still, however, a lot of resistance from the remaining 73%. Geostatistics has more formulae and equations than it needs to reach year 2000. We will be well into the third millenium before all the models available now are actually used. The progress may come in the form of finding better ways to present known statistical results and getting away from the jargon of geostatisticians. One example may be in trying to explain how we can answer the most common plea of the mining industry: production grade is not what was expected in the feasibility study."

Jan 1, 1988

By Godfrey W. McDonald, Dennis E. Fredrickson

"Commercial coal mining has been recorded in Nova Scotia since 1863 and during this period an estimated 60,000,000 short tons of mine discard containing 10 1030% coal has been accumulated, Approximately 70% of these dumps are in the Cape Breton region and most are owned by the Cape Breton Development Corporation (CBDC), formerly DEVCO.The explosion of oil produced energy costs which created an increase in thermal coal demand as well as the desire to rehabilitate abandoned mine dumps encouraged coal reclamation. CBDC was receptive to a proposal from the Selminco Joint Venture and encouraged the building of the Princess Recovery Plant (1980) and The Summit Plant (1982).The mine dump contains scrap, waste rocks, coal and substantial quantities of fine shale. The scrap and oversize are removed and the remaining material slurried with water to a density of 1.45. The slurry is cycloned to separate the saleable thermal coal from the rejects which are returned to designated areas of the dump for contouring and revegetation.BackgroundThe recorded coal production in Nova Scotia from 1863 to 1980 was 390,000,000 short tons. This extraction was associated with an estimated 60,000,000 short tons of discarded material. This mining discard and coal washing plant reject are located in numerous, varying sized dumps throughout the mining areas. Approximately 70% of these dumps are in the Sydney coal field region of Nova Scotia. The coal content of these dumps varies from 10 to 30% coal with an average of 18%.Energy CostsThe explosion o f energy costs in the mid-1970s greatly increased the sale price of thermal coal which made recovery of coal from some of the dumps economical. The environmental benefit of these operations will be the rehabilitation of the dumps upon cessation of the coal reclamation operation."

Jan 1, 1983

By M. Mahfoud

The effect of grain refinement on the tensile and fatigue crack propagation behavior of sand cast magnesium alloy AM60B has been investigated in the present study, C2Cl6 in the amount of 0,3% was used to grain refine the melt, The fracture toughness tests were conducted in laboratory air at room temperature (25°C) using a sine-wave cyclic frequency of 20Hz and a load ratio of R = 0,1, The response in the Paris's regime and the critical stress range were determined, Preliminary findings have shown that C2Cl6 has a significant effect on both the tensile properties and fatigue crack propagation of the alloy tested, Grain refinement increased both the yield and ultimate tensile strength by more than 46%, and decreased the crack growth rate from 2,7 to 1,4 MPa Vm , However, the grain size seems to have a smaller effect on threshold stress intensity factor range. The fracture surfaces of specimens were examined optically and under the scanning electron microscope (SEM) to determine the relationship between grain size and fatigue properties.

Jan 1, 2005

By Torsten Zeller

Due to the increasing worldwide demand for raw materials and the resulting rise in commodity prices more expensive processing that is able to utilize complex ores becomes economically viable. This and increasing ecological awareness is why the interest in recycling and urban mining is steadily growing in Germany. In addition to that; landfills do also contain elements, which were not targeted over the period, when they were being accumulated. Examples are rare earths, indium, gallium, cadmium, arsenic, selenium and tellurium. Also copper, zinc and lead, the target components of ancient mining, can be obtained due to more effective processing and smelting technologies. Funding by the German Federal Ministry for Education and Research, entitled "r³ ? Strategic Metals and Minerals ? Innovative Technologies for Resource Efficiency" also indicates the high level of strategic interest. It is against this background that the research project "Exploitation of the Raw Material Potential of Mining and Metallurgical Tips in Respect of Sustainability as Exemplified in the West Harz Mountains (ROBEHA)" has been implemented. A major concern of this project is the possible transfer of results to landfills in other areas. Therefore the development of an expert system based on the innovative processing methods and a method manual for urban mining are the central components of the investigation. This will provide an important contribution to the cost optimization of ensuing urban mining projects. To ensure the success of landfill mining projects it is necessary to record the composition and quality of the deposits accurately. Also the environmental impact caused by landfill mining and changes in the natural and cultural landscape will be considered in a multicriteria evaluation method. Depending on their origin the tips are divided into the categories mining, processing, and smelting. The content of a landfill and thus the economic potential in terms of urban mining is dependent on the type and composition of the deposits (host rock, gangue, and ore mineral), the available processing and smelting technology, and the target components at the time of mining. Zinc, for example, was not been processed until the 19th century, when it gained attention as being material of economic importance. After such knowledge about a landfill is obtained the decision for further investigations can be made. For a total of 158 landfills in the Harz Mountains, both the volume and the approximate contents of copper, zinc, and lead has been estimated for the different types of tips within past research projects. Based on the prices of the London Metal Exchange (LME) and a euro/dollar exchange rate of 0.76 (as of 03/05/2012) and assuming a minimum density of ? ? 1.5 t/m³ a average value of 1.6 billion ? in copper, zinc, and lead can be obtained. Although only these three metals are considered in this first estimate, it demonstrates the potential of landfill mining and the need for further research. KEYWORDS Urban Mining,

Aug 1, 2013

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

By B. Arsenault

Aluminum coatings can provide galvanic cathodic protection for several metals and alloys, In order to be a suitable protective solution on structural components, the mechanical integrity of the component must be preserved, In particular, fatigue properties are a challenge for thermal-spray protective coatings on mechanical structures, To address the issue of the fatigue integrity of 7075 aluminum alloy with an arc-sprayed protective coating, different surface preparations prior to arc spraying were considered, In the present work, a feasibility study was performed using laser ablation as a surface-preparation technique before or during arc spraying of coatings, This was collaborative effort between the LERMPS laboratory in France, the National Research Council Canada and the Royal Military College of Canada, Both fatigue and adhesive properties of aluminum coatings were evaluated in relation to substrate-surface-preparation techniques including laser ablation (Protal® process), grit blasting and shot peening. Results indicate that a combination of key conditions, including the use of nitrogen as the arc spray gas, shot peening, and proper laser energy density for ablation, provide high fatigue resistance of metallic coated 7075 alloy substrates. Specimens prepared under these conditions show a similar fatigue resistance to uncoated substrates.

Jan 1, 2005

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

For developing new technologies, it is important to characterize the microstructure of materials with high spatial resolution at the nanoscale. To achieve high resolution, field emission scanning electron microscopes (FE-SEM) were developed. These microscopes allow working at low accelerating voltage, below 5 kV, to take advantage of the reduction of the interaction volume with accelerating voltage. Furthermore, their higher gun brightness compared to conventional thermo-electronic emitters, allow a probe size at the nanoscale. At low accelerating voltage, the emission volume of backscatter and secondary electron (SE) of the type II signals approach that of SEI signals. However, it is not enough to reach the highest resolution. A magnetic field above the sample improves the spatial resolution by collecting mostly high-resolution signals. In addition, the energy-filtration of the electron signals allows selecting the type of contrast detected: topographic, compositional, or crystallographic. The development of these new technologies permits to extend the imaging capabilities of the SEM towards new nanoscale applications.

Jan 1, 2014

By J. W. Senn

A magnesium alloy modeled after commercial alloy WE54 was thermomechanically processed and characterized to understand the mechanisms by which its texture can be randomized, as reported by Ball and Prangnell [1]. Samples were deformed in plane strain compression to prescribed strain levels at temperatures high enough to prevent cracking and then recrystallized. The deformation texture is very similar to that observed after plane strain compression (e.g., rolling) of other Mg alloys, such as common AZ31. However, the texture can radically evolve during recrystallization. Annealing above the precipitate solvus temperature results in a nearly random recrystallization texture where the initially strong basal texture is completely eliminated. Annealing below the solvus temperature produces a recrystallized texture similar to conventional Mg alloys, i.e., a weakened basal texture. If this same material is then annealed above the solvus to promote grain growth, a randomized texture evolves, which is similar that of samples simply recrystallized above the solvus. It is hypothesized that a sort of preferred growth mechanism, whereby grains with random orientation grow faster than those with the original basal texture, contributes significantly to the texture randomization observed in wrought magnesium alloys containing rare earth elements.

Jan 1, 2006

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016