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By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By H. M. Lewis

The current status of the international zinc market is summarized, and a supply /demand outlook is presented for the next five years. A number of technical problems facing the industry are outlined. Introduction ZINC has sometimes been called the unknown metal. Considering that on a world basis it ranks third among non-ferrous metals in production and consumption, zinc retains a certain modesty. It has no distinctive colour like copper, lacks the low density of aluminum or magnesium and is not always easy to identify as a product. The 'spangle' of galvanized steel is probably zinc's most distinguishing feature. The purpose of this article is to develop an over-all review of zinc. Starting with the current position of the metal, the major factors that will shape its future will be described so that an assessment of the outlook for zinc can be made.

Jan 1, 1978

By S. Averill, B. Schreiner, V. Sopuck

The La Ronge. Kisseynew, Glennie Lake and Flin Flon domains. the main focu for gold exploration in the southeast part of the Saskatchewan Shield, were subject to continental glacial ice advances from the northeast during the Quaternary. Based on forty-four auger hole along with surficial mapping, the general Quaternary stratigraphy in this area is observed to be composed of a lower till unit , an overlying stratified unit of glaciofluvial sand and gravel and/or a glaciolacustrine silt-clay unit. an upper till. and an upper tratified unit. The lower till is commonly found throughout the geological domains except where it has been eroded in glaciofluvial or fluvial channels. Glacial Lake Agassiz fo rmerly covered most of these prospective domains. The lacustrine deposits associated with the lake impede surficial geochemical surveys including soil. lake sediment. and biogeochemical surveys. The approximate extent of clay cover can be predicted from beach elevations. For instance. in the Waddy Lake area. clay i not known to occur above about 1,400 feet (425 m) elevation. Exploration techniques are hampered by clay in at least one third of the volcanic belt. Thi s influence is indicated by the fact that nearly all gold prospect found to date are located above 1,400 feet (425 m) while the area of clay cover is vi rtually unexplored. The upper till i related to a minor ice readvance. This till is the medium often sampled during soil surveys in the area . lts value as a geochemical ampling medium is dependent on the extent of erosional contact with bedrock highs on the lower till. Those areas which are relatively free of lacustrine and fluvial deposits are those where surface geochemical methods work best. In the Waddy Lake volcanic belt approximately 25-50% of the area may be suitable for surficial surveys. The area of the Star Lake prospect occurs above the 1,500 foot (460 m) elevation and was not covered by Lake Agas iz. The effectivene of till sampling as a surface sampling medium was tested in those areas above the clay level. Till orientat ion surveys were carried out at the Star Lake property and the Tower Lake prospect (Waddy Lake area) within the La Ronge Domain . Gold grain counts and analy es of heavy mineral concent rate from 7 kg surface ti ll samples were used to delineate dispersion trains down-ice from mineralization. In addition, the clay fraction and a 30 g (-80 mesh) subsample from the same till sample, were analyzed for gold . In the Star Lake area, ice direction is subparallel to the strike of several narrow northeast trending auriferous structures. arrow dispersion trains down-ice from known

Jan 1, 1986

By T. W. Wlodek

"AbstractThe results of research into the fatigue properties of SAE 1080 carbon steel and nickel-chromium-molylbdenum steel for mining drill rods are analysed and described in detail.The effect of water corrosion on the fatigue strength of drill rods of these two steels in the as-rolled condition has ,been investigated and the beneficial influence of shot-peening on their dry and water-corrosion fatigue strengths determined by employing the method developed previously (1).Eight S-N curves for as-rolled and shot-peened mining drill rods under both dry and water corrosion conditions have been derived and their shape and relative position are discussed. The main features relating to field performance of the drill rods are analysed.Purpose of Research and Outline of ProgrammeDRILLING holes in rock and ore by means of drill rods attached to a pneumatic drill is a basic procedure required in mining operations. Detonation of explosives placed in these holes is at present the only practical method of breaking down the rock and ore.A drilling rod is supported by its bit end in the drilled rock. Its shank end, fixed in the drilling machine, transmits impact energy to the cutting edges of the bit. On the field performance of the drill rod depend a number of basic mining operations such as sinking, drifting, and stoping. The drill rod is there-fore regarded as one of the most important tools used in the mining industry."

Jan 1, 1952

By L. R. Plitt

A series of experiments were carried out in an effort to develop a universally applicable mathematical model of the hydrocyclone classifier. The design and operating variables studied were: cyclone diameter and height, the inlet, vortex finder and apex diameters, the feed pressure and the solids content of the feed slurry. The model consists of four basic equations which express the cut size ( dso), volumetric split between overflow and underflow, volumetric throughput, and sharpness of separation in terms of the operating and design variables. Although empirical, the model is nevertheless in general agreement with fundamentally derived models. The model clearly 1•eveals the effect of the major variables on the operation of a hydrocyclone. Because of its broad data base and the inclusion of all the major variables, the model may be used without experimental data to predict the operation of cyclones over a wide range of different operating conditions. With operating data, the equations may be modified to serve as an operational model.

Jan 1, 1976

By Dennis Hoffmann

"Abstract - Banded iron formation rocks associated with massive sulfide lenses in the Broken Hill Pb-Zn-Cu-Ag deposit in the Namaqualand Metamorphic Complex, South Africa , were investigated with respect to the geochemistry of manganiferous silicate-rich bands. Two common varieties of these are: amphibole- and garnet-rich iron formation bands. The results reveal that the former are enriched in Fe, Mg, Cu, Co and S. The garnet-rich bands are enriched in Mn, Ca, P, Pb and Ba with significant detrital contamination of Ti, Al, Zr, Cr, Y, V, Ni and Nd.The silicate-rich bands have compositions, in terms of, Si/Al, Si/Fe, Fe/Mn, La/Ce and Co/Zn, comparable to submarine chemical sediments which precipitated from hydrothermal fluids. The garnet­ and amphibole-rich bands are interpreted as ""evolved"" and ""immature"" hydrothermal sediments, respectively. The latter resulted from rapid precipitation after exhalation, whereas the former had a longer residence within sea water. The silicate-rich bands both exhibit increasing Mn/(Mn+ Fe) fractions, which are consistent with a variation expected from proximal to distal depositional settings. The prevalence of garnet-rich bands over amphibole-rich bands is interpreted as the result of injection of hydrothermal fluids from a single vent situated along the northwest margin of the Broken Hill deposit."

Jan 1, 1994

By Alfred W. G. Wilson

THE state of development of its iron and steel industries serves as a 1eading index to the general condition of a nation's business affairs. In this paper, the authors present an economic study of the progress of this group of industries in Canada for the decade 1927-1936. The statistical data and most of the tables which accompany this article have been com-piled by John Casey, Statistician, Bureau of Mines; the text and some of the computations have been prepared by the seni0r author. The principal source of statistical information has been the publications of the Dominion Bureau of Statistics; where other sources have been consulted, they are noted in the text. All weights are given in short tons. Records for the years 1913 and 1918 are also presented in the group of tables dealing with iron ore and pig iron; they will serve as a basis for comparison with nearly normal years in the two decades prior to 1927-36, which included the abnorma1 years of the Great War. GENERAL REVIEW At the beginning of the decade under review, this group of industries had returned to almost normal production, as determined by pre-war conditions. Iron ore consumption showed a steady increase between 1927 and 1930; a marked decline began in 1930 and reached its culmination in 1932, when the recorded consumption of ore was 293,353 to11s, about 16 per cent of the average consumption during the first four years of the decade; the last four years of the decade show a gradual increase in consumption; the amount of ore used in 1936 was still slightly below the amount used ten years before, in 1927 (see Table 1, top).

Jan 1, 1938

By C. M. Offenhauer

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.

Jan 1, 1949

By Norman Marr

Introduction In Canada, the mining industry and water-power development are intimately associated in that mining, which ranks second among the country's primary industries, depends principally upon hydro-electric energy for its large power requirements. On the whole, the Dominion has been very favourably endowed with water-power resources; generally speaking it is a well-watered country with numerous rivers and lakes located in are as where the topography favours water-power development. Precipitation, the raw material of water power, varies from an annual fall of more than l00 inches on the Pacific coast to about 12 inches in sections of the Prairies and the Northwest Territories; in Ontario and Quebec the annual average is 24 to 40 inches and in Nova Scotia about 45 inches. In its descent to the sea, the resulting run-off, much of it from considerable altitudes, creates sources of potential energy at every rapid and fall along the country's many streams and rivers. Many of the innumerable lakes in the Dominion provide storage basins for the regulation of stream flow, thus enhancing the potential power of available sites. While water-power resources are fairly well distributed across the Dominion, as is shown on the accompanying map of Canada showing power sites (Figure 1), it is particularly fortunate that those areas which are lacking in indigenous fuels have been compensated in large degree for this scarcity by being favoured with a high proportion of the total potential water power. This has an important bearing on the mining industry in that extensive mining operations can be economically carried out in the great Canadian Shield, which is lacking in commercial coal deposits but is rich in water-power resources. This Precambrian formation, which forms a wide belt around Hudson bay and in which many metalliferous ores are found, was 'subject to severe glaciation in a recent geological period, so that its river systems are comparatively young and are characterized by numerous lakes joined by short reaches of fast water, rapids, and falls which offer frequent opportunities for power development. The western Cordilleran region, which also is important in mining, has abundant water power. The accompanying geological map (Figure 2), prepared by the Geological Survey of Canada, shows the great extent of the Precambrian and Cordilleran regions and may be compared with the map of water-power sites to show the high incidence of water-power resources in these potential mining areas in which important mineral discoveries have already been made.

Jan 1, 1949

By F. W. Tregarthen

"This paper gives a brief description of the methods used to form and implement the present planned maintenance program. The system is designed to assist plant personnel in their task of controlling a large work-force and maintaining the many and varied types of equipment used in a mining and concentrator operation. The types of reports and methods used in scheduling and work-loading are described. General built-in flexibility is derived from computer assistance to the Central Planning Group."

Jan 1, 1971

By Gabriel G. Walton

Conventional numerical modelling tools for analyses of underground excavations are well suited for modelling elastic behaviour and yield response of geomaterials with very simple constitutive behaviour. Non-dilatant elastic and perfectly plastic behaviour is most commonly used for preliminary analyses in the absence of the data required to consider more complex behaviours such as strainweakening and dilation. For truly brittle models, this deficiency is more acute. Current state of practice allows only for reliable estimation of the volume of failure, but not for any prediction of displacement. In fact, there is no consensus in rock engineering regarding the most accurate approach or most suitable tool to model the magnitude of the plastic deformation that strain-weakening or brittle rocks experience at tunnel boundaries, particularly when support is incorporated into these models. This problem is largely a function of a poor understanding of how inelastic dilation occurs in different types of rockmasses, the rate controls on strength loss and volume change during yield, and the complexities of rock-support interaction in yielding conditions.

Jun 1, 2012

By P. D. Kondos, J. R. Goode

Given the global inventory of low grade and refractory gold deposits, processes that could turn these challenged deposits into mines are of considerable interest. Such gold deposits have low value and potentially high operating costs and so they pose special challenges for the mining engineer and metallurgist. Conventionally, refractory gold ores have been processed by whole ore pressure oxidation and roasting, or flotation followed by roasting, pressure oxidation or bio-oxidation of the concentrate. Halide-based processes have recently been developed that might be applied to concentrates. Low grade refractory gold ores have been processed using heap bio-oxidation followed by cyanide heap leaching or milling. Other processes are emerging. Barrick has completed an inventory of emerging technologies (1). A summary of the current status of these developments will be presented with the view that, with additional development, some of these technologies or a combination thereof may unlock the value of these deposits.

Jan 1, 2005

By J. Walker, G. E. Kim

Since May of 2000, Mogas Industries, in partnership with F.W. Gartner Thermal Spraying Co. and using the services of Perpetual Technologies, has invested time, energy, and resources towards developing novel ball valves for high-pressure acid-leach (HPAL) service. In addition to developing new valve designs, an aggressive coatings development effort has been undertaken to improve the protective quality of the coatings so as to enhance the performance and extend the life of valves in severe HPAL conditions. In 2001, Mogas Industries qualified and applied a nanostructured titanium oxide (n-TiO2) coating for gold and nickel/cobalt HPAL services. The n-TiO2 coating provided dramatically superior protection against abrasive and erosive wear, fared very well against high-pressure autoclave corrosion testing, and has performed well in HPAL service.

Jan 1, 2004

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By J. H. Morrish

"The delivered price of any mineral is the determining factor in converting untapped resources into economic resources. Transporting the minerals from the mine to the market plays a significant part in the total package. The expansion of the Western minerals industry in the last ten years has been paralleled by improved transportation systems to reduce cost, increase accessibility of resources and get the minerals to market in the shortest time possible. A review is made of developments, such as unit trains, complex multi-modal systems and containerized transport, over the last ten years, with specific movement outlined. The total transportation package of land transport, port and terminal facilities, and water transport, where needed, is stressed. As the volume of minerals movement expands, increasingly sophisticated and integrated transportation systems will have to be utilized. The development of solids pipelines and other possibilities is outlined."

Jan 1, 1973

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By J D. McDonald

This paper outlines the function of the Safety and Compensation Division of the Mining Association of British Columbia. After a general discussion of safety and the safety program now being followed in B.C., the author goes on to describe the wide-ranging aspects of compensation payments and company assessment rates. Special attention is also given to the problem of silicosis in mining operations. In appendices to the paper, the experience rating plan of the mining industry is compared to that recently adopted for the construction industry. Introduction The Mining Association of British Columbia consists of fifty-five member companies, including virtually all the producing mines as well as the larger exploration, contracting and development companies. On completion of an extensive study of safety and compensation in the mining industry, the Mining Association of British Columbia instituted a Safety and Compensation Division in 1954. The director of the Safety and Compensation Division reports to the Executive Committee of the Association. There are two main functions of this Division. First is the prevenion of accidents by encouraging

Jan 1, 1965

By L. V. Chugaev, Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

"Pressure oxidation (POX) is one of the most common and reliable methods of processing gold-bearing sulfide concentrates. However, when processing concentrates that contain natural carbonaceous matter, substantial gold losses occur due to autoclave preg-robbing. The latter involves formation of gold chloride complexes under typical POX conditions (high temperatures, high acidity and high ORP) and subsequent sorption of these complexes by carbonaceous matter. Naturally, chloride ion plays a significant role in the process of autoclave preg-robbing; its concentration in POX solution has a well-marked effect on subsequent gold recovery during cyanidation of POX residue. The previous research done by SRC Hydrometallurgy showed that autoclave preg-robbing of gold could be significantly inhibited by the addition of mercury(II) compounds to POX slurry. The positive effect of mercury(II) was well pronounced both at high (>20 mg/L) and low (<5 mg/L) Cl concentrations in POX solution. The successful bench-scale laboratory testing was followed by pilot plant trials at Ore Test Facility in Blagoveshchensk, Russia. The present paper provides the results of these trials. The bench-scale testing results were verified; the optimum oxidizing parameters and reagent dosage were specified. The behavior of mercury (II) at POX pilot plant was found to be in good consistency with industrial practice described in the literature.INTRODUCTION Pressure oxidation (POX) is one of the most common, reliable, and commercially proven methods of processing gold-bearing sulfide ores and concentrates. However, when processing double refractory materials that contain natural carbonaceous matter, POX technology advantages are compromised by autoclave preg-robbing of gold. The latter occurs when natural organic carbon and soluble halides are both present in autoclave feed. Strongly oxidizing conditions of POX (high temperature, oxidation-reduction potential or ORP, and acidity) favor formation of gold-halide (mostly, gold-chloride) complexes, which tend to bond with carbonaceous matter. The exact nature and mechanism of this bonding is unknown, but as the result of this, cyanide is unable to leach gold from POX residue and the precious metal is lost to the tails (Axenov et al., 2014; Dimov, Chryssoulis, & Sodhi, 2003; Fomenko, Zaytsev, Pleshkov, Chugaev, & Shneerson, 2013)."

Jan 1, 2017