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By F. D. Forgeron

"ONE OF THE FIRST DOCUMENTED APPLICATIONS of soil geochemistry in the Canadian Shield was that carried out by Chisholm in the Kenora district in 1949. This survey proved successful in outlining sulphide-associated gold veins utilizing cold-extractable metals. Since then, mining companies, government agencies - both provincial and federal - and universities have conducted soil investigations. Some of the results are documented in publications, others are on open file in provincial and federal mines departments and, unfortunately, many other investigations with both successful and unsuccessful results are buried in company files or have been discarded. This paper deals with soils within the scope of chemical studies of overburden in the Canadian Shield. The subject is a broad one and some definition is required. The soil investigations discussed herein are those aimed at the testing of specific targets more or less in the source area. This definition distinguishes soil investigations from other overburden studies which commonly monitor metal accumulations at some substantial distance from the metal source. Naturally this distinction is relative, because in many instances there is overlap."

Jan 1, 1971

By F. H. Edmunds

Introduction This paper, it is hoped, will serve as an introduction to further work upon the origin of the soils and to a more complete interpretation of the geology of Saskatchewan from a study of the soils of the Province. The great difficulty that is encountered in mapping the structure of the prairie regions of the west must be evident to all who have made the attempt. The rarity of good exposures, due to the extensive coverings of glacial drift, is the greatest obstacle, making it difficult to determine the exact stratigraphical position of such exposures as may be found. In many cases palæontological evidence is lacking, or, if available, our present knowledge of the stratigraphy is insufficient to justify division of the formations into horizons; and until many of these formations have been subjected to petrographic investigation, little can be done in using lithological differences as an aid to the correlation of the usually sparse outcrops met with in the Province. Topography may be of the utmost value as an indication of geological structure when considered in conjunction with other evidence. It does not necessarily follow that, because an area in Saskatchewan has resemblances in surface configuration to an area of oil-producing land in Texas, there is sufficient justification for sinking money in wells without further investigation. Such - investigation should include the study of available soil maps.

Jan 1, 1929

By D. R. Murray

"A promising long-term solution to uranium tailings reclamation has been the establishment of vegetation directly on the waste material. The soil profiles of areas vegetated for 0, 3, 8 and 10years are characterized as to the extent of soil development . The characteristics are compared with the visually interpreted soil profile. Organic matter content is presently the best analytical judge of soil development. Vegetation procedures have produced a build-up of organic matter in the top 10cm of tailings where natural microbial populations flourish. The CN ratio is high and the profile depth shallow, suggesting the need for additional fertilizer applications.IntroductionThe reduction of surface erosion and improved aesthetics of uranium tailings has been accomplished by the establishment of a vegetative cover. In 1971 research concentrated on developing methods of plant establishment at minimal cost and soil amendments on uranium tailings in Elliot Lake , Ontario. One process of stabilization used on a large scale was direct seeding of grasses and legumes into the tailings which had received only limestone and fertilizer treatments. Fertilizer additions were made for varying lengths of time in subsequent years to maintain the established cover.Maintenance-free vegetation would be possible once a soil profile developed with sufficient nutrient recycle and plant regeneration capabilities(1). Tailings vegetated in 1971, 1973 and 1978 that had received either 3 or 5 years of maintenance fertilizers were examined for soil development profiles. The extent of soil development and the relative effect of time and fertilizer would provide direction on reaching the goal of a self-sustaining cover.This paper is an abridgment of Division Report MRP /MRL 81-126 of the same title(2)."

Jan 1, 1984

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

"Geological investigation in the Appalachian region of Canada began more than 150 years ago. The distribution of rock formations, and their ages and regional structure are today reasonably well known in most parts of the region to 1-or 2-mile scale. Most Newfoundland geology is known only to 4-mile scale. About 200 earth scientists carry out research in the region, of whom about 25 per cent are government employees, 50 per cent university staff and graduate students, and 25 per cent industry employees.Increased activity is needed toward both regional analyses and problem studies through the efforts of multi-disciplinary teams. The ultimate objectives of earth science must be the discovery and development of mineral re•-sources and the use and conservation of natural material in the environment, all for the benefit of the local in-habitants. To accomplish this, the scientific community must carry out an array of research projects ranging from the technical products of geological, geophysical and geochemical surveys through to the research products de-signed to renew theories and hypotheses bearing on natural processes. Some scientific sub-objectives are listed.Recommended is the increase and broadening of communication among Appalachian scientists, specifically those resident in the Atlantic Provinces. It is proposed that an Appalachian Division of the Geological Association of Canada be formed to provide a forum for discussion of Appalachian topics. In addition, a committee or council of university, industry and government earth scientists should be formed to examine the state of the science in the region, to identify programs of investigation and individual projects of research, and to recommend methods of approach. If the committee succeeds and the scientific community acts upon the recommendations, the quantity, quality and pertinence of research will increase, and earth science will better serve Appalachian society."

Jan 1, 1970

By M. O. Makwarela, M. W. Erwee, K. Bisaka

"Energy efficiency in mining and minerals processing forms part of Mintek’s long-term research strategy which includes a specific programme designed at overcoming the challenges faced by the South African pyrometallurgy industry.The electric smelting industry is currently severely constrained by the global economic downturn as well as by the availability and increasing cost of electricity. Efficient utilisation of electricity through energy recovery systems and improved smelting process flowsheets can significantly contribute towards creating sustainable operations.Apart from efficient engineering design and solid process control, smelting of either cold or hot pre-reduced ores has been shown to decrease furnace electricity consumption by more than 40%. Various methods of solid-state reduction tests have been carried out at Mintek in order to select the most appropriate process option in the context of the South African industry. This paper summarises a subset of the results obtained, specifically on pre-reduction tests done on South African chromite and manganese ore pellets.In this set of tests, it was found that the use of an organic binder, together with B2O3 as flux, promotes manganese ore pre-reduction, but retards the pre-reduction of chromite. By pre-reducing the manganese ore feed, significant cost savings can be achieved in subsequent smelting processes and there is potential to minimise manganese losses as a result of fuming, due to possible lower operating temperatures."

Jan 1, 2016

By Jayesh B. Patel, Zhongyun Fan, Hu-Tian Li

"Melt conditioned direct-chill (MC-DC) casting is a novel technology which combines vertical direct-chill (DC) casting with a high shear device directly immersed in the sump for in situ microstructural control. In this paper, the solidification mechanism of DC casting under varying conditions is discussed. The temperature profiles in the sump were measured under the steady state casting conditions by using sacrificing thermocouples. Detailed comparisons of the derived thermal condition are made. The individual role of grain refiner additions, natural thermosolutal convection and forced convection in the sump and the interplay of these factors in determining the solidification structures of DC cast billets are discussed. The MC-DC casting technology can be used to control microstructural constituents and casting defects in DC cast billets/ingots by in situ manipulating of the thermal and fluid flow conditions.INTRODUCTION Direct-chill (DC) casting of aluminium, has been the essential commercial process for producing feedstock suitable for subsequent processing, such as extrusion, rolling or forging. Fine and equiaxed grain structures in the as-cast billets/ingots are required to enable a fine and uniform distribution of second phase particles and microporosity. This leads to higher productivity, more cost-effective homogenisation and more efficient downstream thermomechanical processing. The addition of chemical inoculants has been the standard industrial operation prior to casting for grain refinement of Al alloys. However, it has been established that less than 1% of the grain refiner particles added actually act as heterogeneous nuclei to refine the grain structures, showing a very low grain refining efficiency (Greer, Bunn, Tronche, Evans, & Bristow, 2000). Moreover, the remaining particles from the grain refiner addition in the final casting may cause surface defects during downstream processing. A major issue of the metallurgical quality of large sized ingots/billets is the non-uniformity of microstructures even with chemical grain refiner additions. This is due to the fact that the grain structure formed in the different zones of the billet depends on the local chemical composition and local cooling rate. The local cooling rate can vary from 0.4~1 K/s at the centre of the billet to around 10–20 K/s at its surface zone (Nadella, Eskin, Du, & Katgerman, 2008). The large thermal gradient along radial direction between billet surface and interior of the melt during conventional DC casting induces thermal stress and cold cracking even with grain refiner addition. Therefore the control of casting defects, such as macrosegregation, porosity, cold/hot cracking and distortion of the billets/slabs, etc., is still challenging in industry, causing high scrap rate of DC cast ingots/billets even with grain refiner addition."

Jan 1, 2018

By H. Assadi, S. Reutzel, D. M. Herlach

Intermetallics exhibit unique solidification behaviour due to their chemical longrange order. This includes, for instance, generally slow solidification kinetics, and in some cases, an anomalous partitioning behaviour. In the present work the electromagnetic levitation technique - complemented by theoretical modelling - is used to explore various aspects of this behaviour, as observed in solidification of B2 phase in undercooled melts of the Ni-Al system. Moreover, a phase-field model is developed and used to illustrate the effect of chemical order on the solidification kinetics of a B2 phase in a model system. The phase-field model provides an additional basis for the simulation of solidification microstructures in intermetallic forming systems. Both experimental studies and theoretical work signify the role of chemical order in solidification of intermetallics.

Jan 1, 2006

By Xueyuan Nie, Xuezhi Zhang, Henry Hu, Shen Xinwei, Jimi Tjong, Li Fang

With the demand for weight reduction in vehicles and airplanes, researchers have shown great interested in casting wrought aluminum alloy 7075 because of its potential advantages such as high strength-to-density ratio and stress-reduction capabilities. It is therefore essential to conduct a fundamental investigation on solidification behavior and grain microstructure of alloy 7075. In this study, a commercially-available wrought aluminum alloy 7075 was used to study the solidification behavior of alloy 7075. A thermal analysis was performed based on the cooling curve and its corresponding first and second derivative curves. The nucleation of the primary a-Al phase and eutectic phases were analyzed. The comparison between the microstructures of the wrought and cast 7075 alloys shows that coarse microstructure and porosity are present in the cast alloy. The techniques for grain refinement in casting, such as the addition of the nucleating particles and applied pressure, should be employed to reduce the dendrite arm spacing and the porosity.

Jan 1, 2015

By C. Matthews, A. Vo

"Australia is one of the world’s leading exporters of bulk commodities and the extensive use of sampling equipment is key to the successful management of each mining operation. At the process plant, without a full understanding of the feed, product and tails, it is impossible to fully optimise the performance of the plant, such that the metallurgical balance is often open to error. At the port, a statistically correct, bias free and compliant sampling system is crucial to ensuring exported minerals are reflective of their true value and to avoid penalties. Over the last decade, as a result of the iron ore boom, there has been high demand for reliable, representative and standard compliant solids sample systems in Australia. This paper reviews several solids sampling applications at Australian mine sites, the challenges and experience gained and how the implementation of reliable representative sampling systems has provided better understanding of plant process performance, improved plant control and overall benefits to the operations.INTRODUCTION Mining is the primary contributor to the Australian economy with Australia ranking in the top 4 in economic resources for 21 primary industrial minerals in 2016 (Britt, et al., 2017). Australia is one of the world leaders in the export of the majority of its commodities including gold, copper and iron ore (Britt, et al., 2017). Therefore, a suitable and standard compliant sampling system is essential for evaluating plant performance and content verification. At the mine and at the port, the larger iron ore miners in Australia have developed stockpile models to predict the grade of their ore down to individual blocks of the stockpile. This allows the miner to create the right blend of material for sale to their customers and ensures they are not underselling their product or at risk of penalties for impurities or low grade. As an example, the average difference between the benchmark 62% Fe and low grade 58% Fe fines at the time of this report averaged US $30/tonne according to the Metal Bulletin Iron Ore Index. At a shipload of 180kt this would be a variation of US $5.4M. Whilst this is an extreme example, it highlights the economic importance of producing the correct grade product and a recognised representative sample of said product."

Jan 1, 2019

By C. Matthews, A. Vo

Australia is one of the world’s leading exporters of bulk commodities and the extensive use of sampling equipment is key to the successful management of each mining operation. At the process plant, without a full understanding of the feed, product and tails, it is impossible to fully optimise the performance of the plant, such that the metallurgical balance is often open to error. At the port, a statistically correct, bias free and compliant sampling system is crucial to ensuring exported minerals are reflective of their true value and to avoid penalties. Over the last decade, as a result of the iron ore boom, there has been high demand for reliable, representative and standard compliant solids sample systems in Australia. This paper reviews several solids sampling applications at Australian mine sites, the challenges and experience gained and how the implementation of reliable representative sampling systems has provided better understanding of plant process performance, improved plant control and overall benefits to the operations. INTRODUCTION Mining is the primary contributor to the Australian economy with Australia ranking in the top 4 in economic resources for 21 primary industrial minerals in 2016 (Britt, et al., 2017). Australia is one of the world leaders in the export of the majority of its commodities including gold, copper and iron ore (Britt, et al., 2017). Therefore, a suitable and standard compliant sampling system is essential for evaluating plant performance and content verification. At the mine and at the port, the larger iron ore miners in Australia have developed stockpile models to predict the grade of their ore down to individual blocks of the stockpile. This allows the miner to create the right blend of material for sale to their customers and ensures they are not underselling their product or at risk of penalties for impurities or low grade. As an example, the average difference between the benchmark 62% Fe and low grade 58% Fe fines at the time of this report averaged US $20/tonne according to the Metal Bulletin Iron Ore Index (Fastmarkets MB, 2019). At a shipload of 180kt this would be a variation of US $3.6M. Whilst this is an extreme example, it highlights the economic importance of producing the correct grade product and a recognised representative sample of said product.

Jan 1, 2019

By T. Crivits

"Phase equilibria in the ‘Cu2O’-‘Fe2O3’-SiO2 system, the base slag system in copper production, were recently determined. However, the addition of MgO, commonly present in the slag, drastically changes the phase equilibria in this system. The present study focuses on the phase equilibria in the ‘Cu2O’-‘Fe2O3’-MgO-SiO2 system in equilibrium with metallic copper.Recently, an experimental procedure has been developed that resolved a number of experimental difficulties. This procedure has been successfully applied to characterise several complex industrial copper slags. It includes a high-temperature equilibration followed by rapid quenching and electron probe X-ray micro-analysis (EPMA). The methodology was adapted to the present system and used to determine the liquidus at SiO2 saturation and in contact with high-MgO phases in between 1100 and 1250 °C in Cu2Orich slags.The results indicate a maximum solubility of MgO in the system at 1200 °C of 5 wt%. The boundary line between tridymite and spinel lies 3-4 wt% closer to the SiO2 apex for every 2 wt% MgO added. These new data on the high-copper slags are important for optimisation of the direct-to blister"

Jan 1, 2014

By S. Power Warren

Introduction It is generally conceded by flotation men that the condition at the surface of a particle of mineral or gangue is the most important factor controlling its behaviour in a flotation cell. Much research work has been devoted to the study of the forces that are active at the surface of the particle and of the effect of the surrounding solution upon these forces. Study of the relationship between mineral or gangue particles and gas bubbles indicates that, in the main at least, flotation is a physical phenomenon. The important factor, that of mineral-gas-bubble attachment, is unquestionably physical; however, modifications may be effected by chemical means, whereby the nature either of the surface of the particle or of the surrounding solution may be changed. For example, the coating of lead sulphide that forms on lead-carbonate ore particles when sodium sulphide is added greatly aids the flotation of the carbonate particles. Without going into the question as to why, under certain surface conditions, mineral particles will attach themselves to gas bubbles whereas under other conditions they will remain unaffected, it may be stated that there are three general conditions in a flotation pulp which control the attachment of the particle and the gas bubble.

Jan 1, 1933

By X. Zhou

"Hydrogen induced failure and degradation in structural metals, namely hydrogen embrittlement, has been a long-standing industrial problem for more than one century and remains unsolved. Despite the proposal of numerous models, no consensus has been reached, and considerable discrepancies in experimental observations and theoretical calculations exist. One aspect that is central to the understanding of hydrogen embrittlement is the interaction between hydrogen and grain boundaries. In this study, we investigated the influence of several solute elements (i.e., Cr, Mo and Nb) on hydrogen segregation at the representative 9 grain boundary using first-principles calculations. Our results showed that the presence of Mo and Nb can reduce the tendency of hydrogen segregation at grain boundaries, while meanwhile enhance the grain boundary strength. This indicates that Mo and Nb are salutary elements that can be used to increase the material’s resistance to hydrogen embrittlement, providing new insights in designing hydrogen embrittlement resistant Ni alloys. INTRODUCTION Hydrogen embrittlement (HE), a phenomenon of hydrogen triggering premature failures in structural metals, has been a headache for industries ever since its first discovery one century ago (Johnson, 1874; Zhou, Marchand, McDowell, Zhu, & Song, 2016; Zhou, Ouyang, Curtin, & Song, 2016). It is well accepted that the segregation of hydrogen at microstructures such as grain boundaries (GBs) plays a key role in determining the occurrence and severity of HE. GBs are two-dimensional defects where significant local lattice distortion exist, which leads to large free volume and thus locations for hydrogen trapping and segregation. Numerous works have clarified GBs as the energetically preferable places for hydrogen segregation. For instance, Geng et al. demonstrated the preferential segregation of hydrogen at the S5(120) GB in several metals, and suggested a decohesion-type of HE in light of Rice-Wang thermodynamic theory (Geng, Freeman, & Olson, 2001). Birnbaum et al. illustrated that complete intergranular crack of Ni GBs can be induced by hydrogen segregation when the hydrogen concentration is sufficiently high, evidencing the significant role of hydrogen accumulation on GB weakening (Lassila & Birnbaum, 1987). Yamaguchi et al. demonstrated strong segregation hydrogen also occurs at S3 GBs in alpha-iron, showing that local hydrogen clustering (i.e., multiple hydrogen atoms, up to six, per unit cell) can be trapped at the S3 GB (Yamaguchi, Kameda, Ebihara, Itakura, & Kaburaki, 2012)."

Jan 1, 2017

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By U. Troncoso

Mantoverde is a heap leach-SX-EW operation that was commissioned in December 1995 at a production rate of 42,130 ton of copper per year and 5.4 million ton of ore per year. Copper production has been steadily increased to reach 62,000 ton in 2005. The forecast copper production for 2006 is 60,300 ton for an ore treatment rate of 9.5 million ton. A first dump leach operation was started in 1999 at a production rate of 1,922 ton of copper. A second dump leach operation was started in early 2002 at a production rate of 2,805 ton of copper. Dump leach production will be increased over time to as much as 24,000 ton of copper. Several improvements in the heap leach process have been implemented to cope with the higher ore throughput and copper production. However, the solvent extraction plant has remained unchanged which has resulted in a lower availability of raffinate solution and, as a consequence, in longer leach cycles. Different studies have been undertaken in order to optimize the solution management system at Mantoverde, including column test work aimed to reduce the leach cycle and solvent extraction plant modifications aimed to increase the raffinate solution availability. The test work program and the economical evaluations carried out, as well as the conclusions and recommendations obtained, are discussed in this paper.

Jan 1, 2007

By T. Fliß

The protection of natural resources is of essential importance in times of rapidly increasing populations and resulting shortage of agricultural land. Soil and groundwater resources play a central role for the production of food or feed of any kind. The intensive agricultural and environmentally friendly use of these resources must ensure sufficient income and sustainability of life for future generations. Mining projects often represent a particularly deep intervention into ecosystems due to their size as well as the most expensive treatment processes. Conventional mines comprising of shafts and developed mining fields require the stockpiling of waste rock and in particular to potash mining, the discharge of brines from raw salt processing. In contrast, mining operations based on the solution mining method can be operated without major environmental impacts and lower security risks. While the solution mining for the production of rock salt finds application since more than 500 years, exist a procedure to produce potash using solution mining only since the 1980's. For solution mining drill holes are used to exploit the potash, launched from the surface into the deposit. The exploitation of the raw material occurs by the dissolution of the potash injecting solvents and creating so-called brine caverns. Currently, a number of mining projects in Carnallite deposits by the solution mining method are in progress around the world. Often these projects are located in sensitive ecosystems. K-UTEC project and support actual a solution mining operation of a Carnallite deposit for a Chinese customer in South-East Asia. This work comprises a comprehensive geological and geomechanical modeling as well as stability analyses. Furthermore the cavern design and brine field layout as well as the planning of the brine processing and the plant design. The present paper introduces this project as a case study. The application of a special solution mining procedure and processing design ensures an emission-free mining operation (Zero Disposal Plant). The emission-free operation is achieved by utilizing the full extent of the caverns to dispose the liquid solutions from processing. The presentation of principal salt processing and technical equipment will be rounded by information about the geology of the deposit. Since the deposit includes a number of sensitive minerals, such as Tachyhydrite and Bischofite the presentation comprise a lot of interesting items with special view at the brine field operation. K-UTEC designed and delivered a special blanket measuring system and a well cement according the request of the customer. K-UTEC, a research and engineering company with more than 60 years of experience in the sector of potash and rock salt mining, developed the world's first solution mining operation for Carnallite in Germany more than 30 years ago. In recent times K-UTEC served in different solution mining projects worldwide, with special view at the environmental impact, as well as the optimal utilization of the deposits.

Aug 1, 2013

By H. Lorenzen, D. Buyze

"Magnesium-bearing salts occur in the Zechstein Basin in the north eastern part of the Netherlands at a depth of 1500m to 2500 m.Exploration results justified the exploitation of these salts by means of solution mining for the production of refractory grade magnesium- oxide. This paper discusses design criteria, operation parameters, and methods used for magnesium chloride solution mining by Noordelijke Zoutwinning B. V. (NOZO), an operating company of Billiton International Metals B. V.A unique variation of widely used solution mining techniques has been developed for mining the complex Veendam salt deposit. NOZO extracts salt through deviated wells with a set of parallel, suspended tubings. Cavern fluid pressure is maintained close to that of overburden rock. These special design features provide an answer for the complex characteristics of the minerals, halite, carnallite, bischofite and kieserite, from which a solution rich in magnesium is generated. Dissolution chemistry and rock mechanical behaviour of these salts are unlike those of rock salt. Throughout a few years, NOZO demonstrated adequate process control while they continue improving the operation.IntroductionBilliton, a wholly owned company of the Royal Dutch /Shell Group of Companies, is active in metal exploration, mining, processing, and trading, mainly in the non-ferrous sector.Since 1972 Billiton has been active with solution mining magnesium salts in the northeastern part of the Netherlands, in the Province of Groningen, near the city of Veendam . Solution mining techniques were developed in conjunction with the ""Koninklijke/Shell Laboratorium Amsterdam"" (KSLA) and the ""Koninklijke/Shell Exploration and Production Laboratorium"" (KSEPL), Rijswijk. The company's objective is to produce magnesia sinter (MgO) from magnesium-chloride brine (MgClz) and de-carbonated dolomite (CaO.MgO). The magnesia produced serves as base material for the manufacturing of refractory bricks, used for furnace linings in the steel industry."

Jan 1, 1986

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978