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By R. A. Metz, George S. Barnett

The Equis and El Roble projects are located in the Cordillera Occidental of Colombia. The Equis vein deposits have sulfide ore reserves of 95,955 mt (105,770 st) grading 8.51 g/mt (0.248 oz/st) gold and 12.4 g/mt (0.36 oz/st) silver with 0.94 % copper, 1.10% lead and 11.06% zinc. Ore reserves at El Roble are estimated as 1.1 Mmt (1.21 million st) grading 4.89 % copper and 3.39 g/mt (0.099 oz/st) gold. Geologically possible reserves at Equis may total 1.6 Mmt (1.76 million st). El Roble has the potential to contain several tens of millions of metric tons. Exploration included diamond drilling, trenching, channel sampling, rock and soil geochemistry, geophysics and tunneling. Erratic high grade samples affect the weighting of channel and drill core samples. Secondary reconcentration of gold is also a factor. Sample maps and graphs show the distribution of values to be highly variable. Geostatistical treatment of some of these data gave important guidelines for parameters such as sampling densities, drill hole spacing and confidence limits.

Jan 1, 1992

In 1991, environmental issues related to coal mining continued to be an integral part of managing a cost-effective operation. Environmental regulations and their implementation can create considerable cost burdens on operating mines. Environmental responsibilities require management decisions to be made on a whole systems approach that is comprehensive in costs and consequences. Most of the regulatory activity in 1991 that affected coal was related to reauthorization or revision of several pieces of legislation. Issues related to the reauthorization of the Clean Water Act, the Resource Recovery and Conservation Act (RCRA) and Abandoned Mine Land. Clear Water Act considerations will encompass discharge standards, wetlands issues and proposals to regulate ground water quality at the federal level. Discussion regarding RCRA includes efforts to expand regulatory authority into the area of coal mine waste. That is currently regulated by the Office of Surface Mining (OSM). Another RCRA consideration will be the disposal of coal combustion byproducts. Abandoned Mine Land reauthorization continues the Abandoned Mine Land tax on coal operators. This tax has been in effect since 1977. Regulatory revisions were also proposed by the Department of Interior on valid existing rights, subsidence, federal coal leasing programs and OSM's troubled Applicant Violator System. Industry officials have been critical of the revisions. A federal appeals court found that evidence supported claims by Whitney Benefits, Inc. that the passage of the Surface Mining Control and Reclamation Act (SMCRA) deprived the owner of full economic use of its property. Before SMCRA's passage, Whitney established an operating agreement with Peter Kiewit Sons Co. to mine coal.

Jan 1, 1992

By Walter G. Steblez

The countries of Eastern Europe are former members of the Council for Mutual Economic Assistance (CMEA). Geographically, they are located in Central Europe (Poland, Hungary, Czechoslovakia) and Southeastern Europe, largely in the Balkans (Yugoslavia*, Bulgaria, Romania and Albania*). It is important to remember that all of the countries of Eastern Europe had central planning imposed on them by the Soviet Union during the years following World War II. "Stalinist" policy for industrial development had three important tenets: • central economic planning, or a nonmarket-based command economy with administratively set prices; • economic priorities that stressed the development of heavy industries such as mining, metallurgy (steel) and heavy machine building; and • self-sufficiency at all costs, which was aimed at abolishing reliance on the world capitalist market, or reducing it to a minimum. Essentially, the system of industrialization that was used in the Soviet Union in the 1930s and 1940s was imposed on Eastern Europe. Organic market economic development in Eastern Europe ceased during this period. The flaws of this experiment became apparent when mineral processing facilities were set up in many areas of Eastern Europe that did not have reliable resources. Poland, Hungary and Romania are good examples of this situation. The Soviet Union became the principal supplier of iron ore and other minerals and mineral fuels, not only to these countries but to the Bloc as a whole.

Jan 1, 1992

By G. Folmo

Allis Mineral Systems' GRATE-CAR agglomeration/induration/reduction process is currently being operated to process ilmenite at Tinfos Titan & Iron KS in Tyssedal, Norway. In this process, balled ilmenite concentrate is fed to a traveling grate where pellets are dried and preheated, using fully oxidized kiln exhaust gas. Hot preheated, semi-indurated pellets are fed directly to a ported kiln where reduction of the ilmenite's iron oxide fraction occurs in the presence of lump coal. The reduced pellet sand coal char are discharged from the kiln to an indirect rotary drum cooler. Cooled pellets and char are screened and magnetically separated prior to their further processing in a downstream smelting operation. The pellets are melted and the titanium dioxide and iron are separated. Operation commenced in late 1986.

Jan 1, 1992

By R. Kramer

The Process Mineralogy review arrived too late to appear in the May issue. The Process Mineralogy Committee scheduled programs with both SME and The Metallurgical Society. At the 1991 SME Annual Meeting in Denver, CO the committee sponsored five sessions containing 31 papers. Four process mineralogy sessions were sponsored at the 1992 annual TMS meeting in San Diego, CA. Process mineralogy is used to understand and evaluate mineral behaviors during mineral beneficiation, phase reactions during metallurgy, recoveries and reactions of precious metals during processing and mineral and phase behaviors with respect to environmental problems. The most recent refinement in mineralogical studies with respect to mineral beneficiation has been the wider use of image analysis and combined materials balancing techniques of image analysis data. Image analyzers that can perform analysis with respect to mineral beneficiation are expensive. They are used only for solving major processing problems. Nevertheless, the methodology of analysis continues to be refined. Much better data are collected, and methods of evaluating the data continue to improve. One interesting development involves modifying the ultrasound unit used in medical studies to perform a three-dimensional analysis of ore particles.

Jan 1, 1992

By J. Mark Richardson

Steady-state flowsheet simulators for mineral processing plants have evolved to a current high level of utility and accuracy. Reliable, general-purpose, semi-empirical models now exist in nearly all unit operations categories particularly in the areas of comminution and classification. .These models, installed as user-selectable functions within the integrated frame- work of flowsheet balance-solver software systems, can be strung together to represent any plant configuration. In addition, CAD-like graphics, data reconciliation and model parameterization functions have become standard features of the current generation of integrated plant simulators. These advances have given engineers the capability to investigate many different plant scenarios while requiring a minimum of actual plant testwork. This paper describes a methodology and an integrated software package which are being successfully applied in a number of operating plants worldwide to predict plant performance under changing conditions. Those conditions which can be changed include effect-of ore type, feed size, water addition rates, equipment geometries and flowsheet modifications. By using data from actual plant optimization exercises in real mills, the paper illustrates and out- lines a technique which includes plant data collection, ore breakage testing, flowsheet simulation, model-fitting (parameterization), data adjustment and model experimentation. Brief descriptions of some unit operations models, such as autogenous mills and cyclones, are provided as examples of the current state of such models. Ore breakage testing and its relation to certain models is also discussed. Computer- generated size-distribution graphs, along with tabular data generated by the simulator, round out the presentation and serve to demonstrate the real- ism and accuracy of the models. The paper concludes with a partial list of cases where this technology has been successfully applied.

Jan 1, 1992

By Herbert E. Allen, Andrew F. Kingery, Spyros P. Pavlou

This paper examines and compares the role that chemical speciation plays in the environmental aquatic toxicity of two metals - copper and arsenic. Copper is shown to have well-understood chemical speciation equilibria, but poorly known species toxicities. Arsenic presents the opposite case, with unpredictable speciation in aquatic systems, but is relatively easy to evaluate toxicologically. Speciation is not currently incorporated into Water Quality Standards. This can have a major impact on the cost of environmental containment and cleanup.

Jan 1, 1992

By E. D. Sehnke

The refractory materials industry provides the largest commercial market for nonmetallurgical grade bauxite. Refractory grade bauxite is prepared from bauxites having low iron, titania, and alkali content by calcining at temperatures near 1,650° C. Although there are substantial bauxite reserves in the world, premium grade bauxite ores suitable for use in refractory applications are limited to only a few specific sources, primarily in Guyana and the People's Republic of China. Consumption of bauxite for refractory use is closely associated with the production and consumption of primary metals, in particular iron and steel. Barring major disruptions within the principal producer nations, sufficient supplies of refractory bauxite will be available to meet world demand well into the next century, and raw material costs will continue to determine the availability of markets for bauxite-based refractory products.

Jan 1, 1992

By John L. Watson, Suren Mishra

Many of the wastes produced by modern steel plants are pulps or sludges containing significant concentrations of iron and displaying some ferromagnetic characteristics. These waste materials are often suited to treatment by magnetic cycloning to produce a high solids content underflow and a clean water overflow. Alternatively in the classification mode, the magnetic cyclone can produce a high iron underflow product for recycling by discarding fine non-magnetic material to the overflow. Results for the treatment of a variety of steel plant wastes in 5.0cm, 2.5cm and 1.25cm diameter cyclones, operating with and without an applied magnetic field, are presented. It is demonstrated that the magnetic cyclone increases solids recovery to the underflow product, especially at finer particle sizes and for higher solids content feed pulps.

Jan 1, 1992

By A. F. Edwards

The Main Pass sulphur and oil deposit is located at Main Pass Block 299 in the Gulf of Mexico, 30 miles east of Venice, Louisiana, in 210 feet of water. The deposit was discovered by Freeport-McMoRan and its joint venture partners, IMC Fertilizer and Homestake Mining, in late 1988-early 1989. The sulphur deposit contains 67 million long tons of recoverable sulphur. The sulphur occurs in bio-epigenetic limestone replacing anhydrite caprock on top of a salt diapir. Recoverable reserves of 39.4 million barrels of oil and 9.1 billion cubic feet of gas are also contained in the limestone caprock and in supracap sandstone stringers.

Jan 1, 1992

By Ronald S. Conti, Harry Dobroski

Re1iabl e monitoring a1ong an underground mine belt line is of great concern because of combustibles, electrical apparatus, and friction. Belt entries are strategically located where a fire can have rapid and disastrous consequences. This paper reviews conventional distributed temperature sensing systems based on resistive, thermistor, and thermocouple effects. These are shown to provide limited benefits. A new system tested by the U.S. Bureau of Mines based on fiber optics and time domain reflectrometry, promises much better temperature and spatial resolution, faster response, inexpensive cable, longer distance, and comprehensive data analysis. Test results in a small, controlled, in-mine fire are given.

Jan 1, 1992

By M. S. Celik

Beneficiation of boron minerals by flotation with well defined systems has been very little investigated in the literature. The difficulty arises from the fact that boron minerals cover a spectrum of solubilities. Colemanite, a calcium containing relatively insoluble boron mineral, and borax, a highly soluble boron mineral have been used to exemplify the flotation of boron minerals. The floatability of both minerals using sodium dodecylsulfonate and dodecylamine hydrochloride exhibits considerable differences in their response to flotation. This has been ascribed to variations in the solubilities 0f boron minerals and the presence of the cations in the lattice structure. Flotation tests along with zeta potential measurements are used to elucidate the mechanisms involved in the flotation of boron minerals.

Jan 1, 1992

By C. P. Mangelsdorf, Richard A. Allwes

At the request of the U.S. Department of Labor, Mine Safety and Health Administration (MSHA), the U.S. Bureau of Mines evaluated the suitability of using tri-sets for protecting mine personnel in roof-fall prone areas. A steel-set arch provided by MSHA served as a basis for evaluating the performance of the tri- set. All tests and analyses were conducted according to the arch canopy test and design procedures developed by the Bureau. Theoretical resistance functions were established for the steel-set arch and tri-set and were representative of their experimental behavior. The resistance functions were used to determine the energy absorption capacity of the structures and to predict their dynamic response to impact loading. The dynamic tests demonstrated that the arch canopy design procedure is appropriate for tri -sets and yields conservative designs for both steel-set arches and tri-sets. As a result of this work, it is recommended that tri-sets may be considered for protection against roof falls, provided that the arch canopy design procedure is utilized for each application and that the principles underlying the design procedure are understood.

Jan 1, 1992

By C. E. Jordan

The Bureau of Mines investigated a simultaneous elutriation and flotation technique for separating polyethylene terephthalate (PET) from polyvinylchloride (PVC). The Tuscaloosa Research Center, through a cooperative agreement with a recycling company, devised an elutriation-flotation method for beneficiating the mixed heavy plastics portion of municipal solid wastes which is composed of polystyrene (PS), PET, and PVC. A sodium carbonate brine was used to remove the lighter PS from the heavier PET and PVC. Over 98 pct of the PS was recovered in a high purity PS concentrate containing 99.7 pct PS, The remaining PET and PVC mixture was washed to remove the brine salts that would be harmful to the flotation process. The clean PET and PVC mixture was conditioned in a solution of 45 g/t gelatine and floated in a short (l-m) column flotation cell in an upward flow of water. In a single flotation step, over 75 pct of the PET was recovered in a high purity product containing 99.8 pct PET. The bubbles attached to the PET lowered the effective density of the PET-bubble agglomerate and allowed successful separation of these agglomerates from the PVC plastic pieces. This method separated two-thirds of the mixed plastics fraction into high purity PS and PET products suitable for recycling and left only one-third of the plastics in the mixed plastics product.

Jan 1, 1992

By Joseph J. Wojcik

INTRODUCTION A great deal more is involved in a sampling effort directed at a placer deposit than physically capturing a quantity of representative material and extracting the desired component. The distribution and dimensions of the sample sites must be chosen after consideration has been given to the type of deposit and the concentrating mechanism. Interpretation of the sampling results is likewise an extremely important part of the sampling program. SAMPLE SPACING The interpretation begins with the selection and design of the sampling program. A decision regarding genesis of the deposits and their geometry must be made in order to select a suitable technique and sampling pattern. Deposits differing genetically will have differing distributions and degrees of concentration.

Jan 1, 1992

By R. R. Oder, R. J. Gray

We report measurements of the effects of rank, type, and grade of coal on grinding energy and grinding media consumption in a Pitt Mill. The rank of coal has a greater effect on grinding energy than does coal type. The effect of coal grade on grinding energy depends upon the relative grindability of the mineral matter and of the hydrocarbon components of the coal. The mineral matter is primarily responsible for abrasive media wear in a Pitt Mill. The widely recognized HGI test for coal breakage may yield misleading results, particularly for multiple-banded bright and dull coal where the screening procedure used in sample preparation favors the testing of the hardest coal fraction. The work reported here indicates that the Pitt Mill, which grinds the whole coal in a single stage and which yields easily interpreted results, is an excellent candidate for testing coal pulverization characteristics including energy requirements and equipment wear. The measurements of the effects of coal characteristics on grinding energy and on media consumption have been used to estimate the cost of fine grinding in a Pitt Mill. The results, based on a conceptual level evaluation of grinding at the rate of 1 TPH, show that there are trade-offs possible between the cost of energy and cost of media consumption which involve choice of grinding media size. The use of fine-size grinding media to lower grinding energy and to increase throughput can be deceptive because the total cost of grinding must consider both energy and media consumption.

Jan 1, 1992

By G. L. Mowrey

One critical element of the US Bureau of Mimes computer- assisted mining research program is the development of a reliable coal interface detection (CID) system. Several promising CID concepts currently being investigated by the Bureau include natural gamma radiation (NGR), vibration and passive infrared. To help establish which CID sensor technologies need to be developed for a given seam, coal and adjacent rock samples (immediate roof and floor) are being collected from selected major coal seams in the US and are being analyzed in terms of NGR and other geophysical measurements. This paper provides a brief overview of the Bureau's work in these CID areas.

Jan 1, 1992

By Hans G. Machel

In low-temperature diagenetic environments (0 c T c 60 - 80°C), elemental sulfur forms by six common processes: via (1) inorganic oxidation of H2S by molecular oxygen, (2) inorganic oxidation of H2S by ferric iron compounds, (3) polysulfide disproportion- ation; and via the microbial metabolic actions of (4) colorless sulfur bacteria, (5) colored sulfur bacteria, and (6) some types of thiobacilli. Economically viable deposits of native sulfur usually are formed by only one process: inorganic oxidation of H2S by molecular oxygen. The amount of elemental sulfur is also limited by three common processes that destroy it in low- temperature diagenetic environments: bacterial reduction, bacterial oxidation, and inorganic oxidation. In high-temperature diagenetic environments (80 - 10o°C c T c 150 - 200°C), particularly in sour gas reservoirs, there are seven common processes forming elemental sulfur: (1) SOdH2S reaction, (2) H2S- hydrocarbon reaction, (3) polysulfide disproportionation, (4) catalytic H2S decomposition, (5) C02-H2S reaction, (6) chlorinification, and (7) exsolution of physically dissolved elemental sulfur. Natural processes that destroy or remove elemental sulfur in such settings are hydrocarbon sulfurization, polysulfide formation, and advection. In most sour gas reservoirs, relatively small quantities of elemental sulfur occur as a free phase (solid or liquid). However, elemental sulfur often precipitates in copious amounts from the reservoir fluids via exsolution and polysulfide disproportionation during production of sour gas reservoirs. By extension, elemental sulfur may precipitate from reservoir fluids in relatively large quantities upon uplift and erosion of deep sour gas reservoirs, or from advection of sulfurous fluids into shallower settings via faults or other high-permeability pathways.

Jan 1, 1992

By Zvonimir Jam?ek

In Rudarski Institut Ljubljana (RIL), i.e. Ljubljana Mining Institute, we have developed CADRIL, a smaller CAD package which purpose is to overcome the difficulties by introducing Computer Aided Design in our mines. Program CADRIL is a graphics shell for several computer applications in mining. With the basic version of CADRIL all 2D working maps for daily use can be produced. Inserting different program blocks into CADRIL we get versions MAPRIL, TAHRIL, SECRIL and so on. The main purpose of all versions is graphics design. The main and most innovative feature of CADRIL is the screen four-word command menu. Not having pull-down or tablet menus is the speciality of this program. CADRIL contains 500 achievable commands. Each of them can be composed by choosing two to four expressions stored and shown in a specific four- column menu, sorted as objects functions, parameters and modes. Thus all commands are immediately accessible. As a result of its plainness and adaptability to the present working methods of mining engineers, CADRIL quickly attained a good reputation in our mines.

Jan 1, 1992

By C. A. Roberts

What are the benefits and limitations of financial analysis software as a decision making tool in the mining industry? Traditionally, the assumptions and simplifications imposed by complex and uncertain information have been viewed as the main obstacle to reaching an optimum decision. Recently, however, phenomena such as corporate culture and power structure have received increasing attention as significant influences on organizational decision making processes. Studies of these phenomena have suggested an alternative way of understanding decision making processes and an alternative view of the role played by computer analysis in such processes. This paper presents these two views of decision making, and examines what each implies about the role of financial analysis software as a decision making tool in the mining industry.

Jan 1, 1992